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Regioselective bromination of 1,4-dimethoxy-2,3-dimethylbenzene and conversion into sulfur-functionalised benzoquinones

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dc.contributor.authorAitken, Robert Alan
dc.contributor.authorJethwa, Siddharth Janak
dc.contributor.authorRichardson, Neville Vincent
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.date.accessioned2017-02-28T00:32:44Z
dc.date.available2017-02-28T00:32:44Z
dc.date.issued2016-03-11
dc.identifier241226968
dc.identifier2f962e80-9d5f-40ea-8655-2be217adc2b2
dc.identifier85030259503
dc.identifier000372945300011
dc.identifier.citationAitken , R A , Jethwa , S J , Richardson , N V & Slawin , A M Z 2016 , ' Regioselective bromination of 1,4-dimethoxy-2,3-dimethylbenzene and conversion into sulfur-functionalised benzoquinones ' , Tetrahedron Letters , vol. 57 , no. 14 , pp. 1563-1566 . https://doi.org/10.1016/j.tetlet.2016.02.091en
dc.identifier.issn0040-4039
dc.identifier.otherORCID: /0000-0001-6959-5311/work/34857571
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861785
dc.identifier.urihttps://hdl.handle.net/10023/10376
dc.description.abstractThe NBS bromination of 1,4-dimethoxy-2,3-dimethylbenzene has been examined under a variety of conditions in both 1,1,1-trichloroethane and benzotrifluoride. Four different bromination products have been isolated including the previously unknown 1-bromo-4-bromomethyl-2,5-dimethoxy-3-methylbenzene whose single crystal X-ray structure is presented. The synthetically useful 2,3-bis(bromomethyl)-1,4-dimethoxybenzene is readily prepared using either solvent and it has been converted into new sulfur-containing quinone derivatives
dc.format.extent4
dc.format.extent293706
dc.language.isoeng
dc.relation.ispartofTetrahedron Lettersen
dc.subjectBrominationen
dc.subjectBenzotrifluorideen
dc.subjectSolvent effectsen
dc.subjectX-ray structuresen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleRegioselective bromination of 1,4-dimethoxy-2,3-dimethylbenzene and conversion into sulfur-functionalised benzoquinonesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1016/j.tetlet.2016.02.091
dc.description.statusPeer revieweden
dc.date.embargoedUntil2017-02-27
dc.identifier.urlhttp://www.sciencedirect.com/science/article/pii/S0040403916302003#appd002en


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