A reactive nitrone-based organogel that self-assembles from its constituents in chloroform
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The reversible reaction of an aldehyde with a hydroxylamine affords a nitrone which is capable of forming a stiff gel with chloroform at concentrations as low as 0.20 wt% (6 mM). The gelator forms dynamically from its constituents and the gel assembly can be degraded in a controlled manner through a recognition-mediated reaction that targets the nitrone component of the gel network.
Richards , J & Philp , D 2016 , ' A reactive nitrone-based organogel that self-assembles from its constituents in chloroform ' Chemical Communications , vol 52 , no. 28 , pp. 4995-4998 . DOI: 10.1039/C6CC01259K
Copyright 2016 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C6CC01259K
DescriptionThe authors thank the EPSRC for funding (DTA studentship to JER, EP/K503162/1)
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