Show simple item record

Files in this item

Item metadata

dc.contributor.authorMgaya, James E.
dc.contributor.authorBartlett, Stuart A.
dc.contributor.authorMubofu, Egid B.
dc.contributor.authorMgani, Quintino A.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorPogorzelec, Peter
dc.contributor.authorCole-Hamilton, David J.
dc.date.accessioned2017-01-27T00:32:25Z
dc.date.available2017-01-27T00:32:25Z
dc.date.issued2016-02-18
dc.identifier.citationMgaya , J E , Bartlett , S A , Mubofu , E B , Mgani , Q A , Slawin , A M Z , Pogorzelec , P & Cole-Hamilton , D J 2016 , ' Synthesis of bifunctional monomers by the palladium-catalyzed carbonylation of cardanol and its derivatives ' ChemCatChem , vol 8 , no. 4 , pp. 751-757 . DOI: 10.1002/cctc.201501110en
dc.identifier.issn1867-3880
dc.identifier.otherPURE: 234872877
dc.identifier.otherPURE UUID: d916d0c4-febe-4a52-8b7c-b7594043f6be
dc.identifier.urihttp://hdl.handle.net/10023/10184
dc.descriptionThe authors thank the Royal Society Leverhulme Africa Program for funding this project.en
dc.description.abstractA 1,2-bis(di-tert-butylphosphinomethyl)benzene-modified palladium catalyst has been used to synthesize bifunctional monomers of different chain lengths from cardanol. Short-chain derivatives of cardanol, such as (E)-3-(dodec-8-enyl)phenol; HOPhC12-ene, (E)-3-(undec-8-enyl)phenol; HOPhC11-ene, (E)-3-(dec-8-enyl)phenol; HOPhC10-ene, and 3-(non-8-enyl)phenol; HOPhC9-ene, were synthesized by the metathesis of cardanol with symmetrical internal alkenes. These derivatives were methoxycarbonylated to produce monomers with different chain lengths such as methyl-16-(3-hydroxyphenyl)hexadecanoate; HOPhC15COOMe, methyl-13-(3-hydroxyphenyl)tridecanoate; HOPhC12COOMe, methyl-12-(3-hydroxyphenyl)dodecanoate; HOPhC11COOMe, methyl-11-(3-hydroxyphenyl)undecanoate; HOPhC10COOMe, and methyl-10-(3-hydroxyphenyl)decanoate; HOPhC9COOMe, respectively. Polymerization of the synthesized monomers produced oligomers that consist of up to seven monomer units as confirmed by MALDI-TOF-MS. Lactone formation was also observed in some cases under polymerization conditions.en
dc.format.extent7en
dc.language.isoeng
dc.relation.ispartofChemCatChemen
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/cctc.201501110en
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/cctc.201501110en
dc.subjectLactonesen
dc.subjectOligomerizationen
dc.subjectPalladiumen
dc.subjectPolymerizationen
dc.subjectRenewable resourcesen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleSynthesis of bifunctional monomers by the palladium-catalyzed carbonylation of cardanol and its derivativesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doihttp://dx.doi.org/10.1002/cctc.201501110
dc.description.statusPeer revieweden
dc.date.embargoedUntil26-01-20


The following license files are associated with this item:

This item appears in the following Collection(s)

Show simple item record