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An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine

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dc.contributor.authorSurgenor, Brian Andrew
dc.contributor.authorTaylor, Laurence John
dc.contributor.authorNordheider, Andreas
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorAthukorala Arachchige, Kasun Sankalpa
dc.contributor.authorWoollins, John Derek
dc.contributor.authorKilian, Petr
dc.date.accessioned2017-01-05T00:32:29Z
dc.date.available2017-01-05T00:32:29Z
dc.date.issued2016
dc.identifier240325958
dc.identifieredb95df9-9f5c-44c1-a44c-fb1b142321d2
dc.identifier84961371983
dc.identifier000368941700098
dc.identifier.citationSurgenor , B A , Taylor , L J , Nordheider , A , Slawin , A M Z , Athukorala Arachchige , K S , Woollins , J D & Kilian , P 2016 , ' An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine ' , RSC Advances , vol. 7 , pp. 5973-5976 . https://doi.org/10.1039/C5RA27594Fen
dc.identifier.issn2046-2069
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861518
dc.identifier.otherORCID: /0000-0001-6379-3026/work/58285397
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779167
dc.identifier.urihttps://hdl.handle.net/10023/10042
dc.descriptionThis work was financially supported by the Engineering and Physical Sciences Research Council (EPSRC) and by COST action (grant CM1302, SIPs).en
dc.description.abstractA new synthetic route to FcPH2 and FcPCl2 (Fc = Ferrocenyl) is presented. This method avoids the challenging monolithiation of ferrocene, as well as any tedious purification steps. All reactions are high yielding and easily conducted on a relatively large scale, using economical and commercially available synthetic precursors.
dc.format.extent476804
dc.format.extent466095
dc.language.isoeng
dc.relation.ispartofRSC Advancesen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleAn efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphineen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doi10.1039/C5RA27594F
dc.description.statusPeer revieweden
dc.date.embargoedUntil2017-01-04


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