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dc.contributor.advisorFinch, Adrian Anthony
dc.contributor.advisorDonaldson, C. H.
dc.contributor.authorHunt, Emma J.
dc.coverage.spatialviii, 214, [7] p.en_US
dc.description.abstractUnderstanding crystallisation in magma chambers is a key challenge for igneous petrology. It is particularly important to understand the origins of layering in peralkaline rocks, e.g. the kakortokite (nepheline syenite), Ilímaussaq Complex, S. Greenland, as these are commonly associated with high value multi-element economic deposits. The kakortokite is a spectacular example of macrorhythmic (>5 m) layering. Each unit consists of three layers comprising arfvedsonite-rich (sodic-amphibole) black kakortokite at the base, grading into eudialyte-rich (sodic-zirconosilicate) red kakortokite, then alkali feldspar- and nepheline-rich white kakortokite. Each unit is numbered -19 to +17 relative to a characteristic well-developed horizon (Unit 0), however there is little consensus on their development. This project applies a multidisciplinary approach through field observations combined with petrography, crystal size distributions (CSDs), mineral and whole rock chemistries on Units 0, -8 to -11 and a phonolite/micro-nephelinolite (“hybrid”) sequence that crosscuts the layered kakortokite. Textures and compositions are laterally consistent across outcrop and indicators of current activity are rare. CSDs indicate in situ crystallisation with gravitational settling as a minor process. Chemical discontinuities occur across unit boundaries. The layering developed through large-scale processes under exceptionally quiescent conditions. The discontinuities reflect open-system behaviour; units were formed by an influx of volatile-rich magma that initiated crystallisation in a bottom layer. Nucleation was initially suppressed by high volatile element concentrations, which decreased to allow for crystallisation of arfvedsonite, followed by eudialyte, then alkali feldspar and nepheline to form each tripartite unit. The chemistry of the hybrid indicates mixing between a primitive (sub-alkaline) magma and kakortokite. Thus injections of magmas of varying compositions occurred, indicating a complex plumbing system below current exposure. The lessons learned at Ilímaussaq, which is extremely well exposed and preserved, are relevant to understanding magma chamber dynamics in the more common instances of pervasively altered peralkaline rocks.en_US
dc.publisherUniversity of St Andrewsen
dc.subjectIlímaussaq Complexen_US
dc.subjectNepheline syeniteen_US
dc.subjectRare earth elementsen_US
dc.subjectEconomic geologyen_US
dc.subjectMacrorhythmic layeringen_US
dc.subjectOscillatory crystallisationen_US
dc.subjectVolatile activitiesen_US
dc.subjectCrystal size distributionsen_US
dc.subjectIgneous texturesen_US
dc.subjectIn situ crystallisationen_US
dc.subject.lcshNepheline syeniteen_US
dc.subject.lcshIgneous rocksen_US
dc.titleMagma chamber dynamics in the peralkaline magmas of the Kakortokite Series, South Greenlanden_US
dc.contributor.sponsorNatural Environment Research Council (NERC)en_US
dc.type.qualificationnamePhD Doctor of Philosophyen_US
dc.publisher.institutionThe University of St Andrewsen_US

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