Chemistry: Recent submissions
Now showing items 441-445 of 897
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The bonding, synthesis and electrochemistry of some iron-sulphur-nitrosyl compounds
(University of St Andrews, 1990) - ThesisSalts of the bls(µ-thiosulphato-S)-bis(dinitrosylferrate)(2-) anion, [Fe₂(S₂o₃)₂(NO)₄]²- can be prepared by the reaction of iron(ll)/thiosulphate mixtures with nitrite ion. The crystal structure of {(Ph₃P)₂N}₂[ Fe₂(S₂0₃)₂(NO)₄] ... -
Aspects of the chemistry of iron-nitrosyls
(University of St Andrews, 1985) - ThesisThe work described in this thesis is a study of iron-sulphur-nitrosyls and related compounds. Chapter One is an introduction to the work presented. Chapter one is introduction to the work presented. Chapter Two is concerned ... -
Ferrocenylketones and the stabilisation of their thio analogues
(University of St Andrews, 1991) - ThesisAn effective method for the stabilization of otherwise unstable thiones is their complexation to M(CO)₅ (M= Cr, Mo, W). This complexation led to a very stable material of composition C₂₂H₁₄CrFeO₅S, whose crystals are ... -
Free radical rearrangements of cyclohexa-2,5-diene derivatives and strained polycyclic compounds
(University of St Andrews, 1995) - ThesisEsters of cyclohexa-2,5-diene-l-carboxylic acid were investigated to study the transfer of the labile bisallylic hydrogens (C-4) to give the cyclohexadienyl radical and then the subsequent decarboxylative stage to give R ... -
An experimental and theoretical study of free radical addition to fluoro ethylenes
(University of St Andrews, 1973) - Thesis