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Antioxidant properties of ethoxyquin and some of its oxidation products
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dc.contributor.advisor | Gunstone, F. D. | |
dc.contributor.author | Thorisson, Snorri | |
dc.coverage.spatial | 169 p. | en_US |
dc.date.accessioned | 2018-06-18T10:00:01Z | |
dc.date.available | 2018-06-18T10:00:01Z | |
dc.date.issued | 1988 | |
dc.identifier.uri | https://hdl.handle.net/10023/14172 | |
dc.description.abstract | Ethoxyquin (1,2-dihydro-6-ethoxy-2,2,4-trimethylquinoline (I)), ethoxyquin nitroxide (II), 2,6-dihydro-2,2,4-trimetbyl-6-quinolone (III) and l,2-dihydro-6-hydroxy-2,2,4-trimethylquinoline (IV) were prepared and purified in order to study their antioxidant properties in fish meal and/or oil. I (also commercally available) and III were equally effective in fish meal, but III and IV were better in oil than I and II. In AIBN initiated methyl linoleate autoxidation, the order of efficiency in terms of the stoichiometric factor (n), using BHT as a standard, was IV > I > BHT > II. On the other hand, III gave very little inhibition in this system. In fish meal and oil, I was converted to III and to a 1,8'-dimer (V). The same products were formed in tert-butoxy oxidation of I. The nitroxide (II) was also formed from I but this was only seen by ESR in various organic solvents. It is likely to play some role in the antioxidant mechanism of I. The 1,8'-dimer was isolated and found to have no antioxidant properties in oil. Another reaction product of 1,2,4-dimethyl-6-ethoxyquinoline was also prepared. It was found to show prooxidant effects in fish oil. | en_US |
dc.language.iso | en | en_US |
dc.publisher | University of St Andrews | |
dc.subject.lcc | QP752.F35T7 | |
dc.subject.lcsh | Fatty acids | en |
dc.title | Antioxidant properties of ethoxyquin and some of its oxidation products | en_US |
dc.type | Thesis | en_US |
dc.contributor.sponsor | International Association of Fish Meal Manufacturers | en_US |
dc.type.qualificationlevel | Doctoral | en_US |
dc.type.qualificationname | PhD Doctor of Philosophy | en_US |
dc.publisher.institution | The University of St Andrews | en_US |
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