Centre of Magnetic Resonance (CMR)
The Centre of Magnetic Resonance joins research groups from the three Grade 5 schools of Physics, Chemistry and Biology in St Andrews and research groups in Dundee, all working in the fields of liquid- or solid-state Nuclear Magnetic Resonance (NMR), Dynamic Nuclear Polarization (DNP), Electron Paramagnetic Resonance (EPR), Muon Spin Rotation (mSR), or Computational Magnetic Resonance. The aim of the CMR is to provide a platform for an exchange of ideas, to stimulate discussion, and to strengthen cooperations, research, and grant applications.
For more information please visit the Centre of Magnetic Resonance (CMR) home page.
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Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation (2016-04-21) - Journal articleA convenient synthesis route to 2,2’-binaphtho[1,8-de][1,3,2]di-thiaphosphinine (3) was found. Its stable radical cation 3•+ was accessed easily through one-electron oxidation with NOBF4.
Synthesis and properties of the heterospin (S1 = S2 = 1/2) radical-ion salt bis(mesitylene)molybdenum(I) [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazolidyl (2015-07-20) - Journal articleLow-temperature interaction of [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazole (1) with MoMes2 (Mes = mesitylene / 1,3,5-trimethylbenzene) in tetrahydrofuran gave the heterospin (S1 = S2 = 1/2) radical-ion salt [MoMes2]+– ...
Photochemically induced dynamic nuclear polarization observed by solid-state NMR in a uniformly 13C-isotope labeled photosynthetic reaction center (2015-10-29) - Journal articleA sample of solubilized and quinone-depleted reaction centers (RC) from the purple bacterium Rhodobacter (R.) sphaeroides wild-type (WT) has been prepared entirely 13C and 15N isotope labelled at all positions of the protein ...
Understanding the structure directing action of copper-polyamine complexes in the direct synthesis of Cu-SAPO-34 and Cu-SAPO-18 catalysts for the selective catalytic reduction of NO with NH3 (2015-10-01) - Journal articleCu2+ cations complexed by linear polyamines have been studied as structure-directing agents (SDAs) for the direct synthesis of copper-containing microporous silicoaluminophosphate (SAPO) materials. The complexing ligands ...
(2016-03-24) - Journal articlePulse electron paramagnetic resonance (EPR) is gaining increasing importance in structural biology. The PELDOR (pulsed electron-electron double resonance) method allows extracting distance information on the nanometer ...