Browsing University of St Andrews Research by Title
Now showing items 1-20 of 9755
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1,1'-Diethyl-4,4'-bipyridine-1,1'-diium bis(1,1,3,3-tetracyano-2- ethoxypropenide) : multiple C-H⋯N hydrogen bonds form a complex sheet structure
(2014-03-01) - Journal articleIn the title salt, C14H18N22+·2C9H5N4O−, the 1,1′-diethyl-4,4′-bipyridine-1,1′-diium dication lies across a centre of inversion in the space group P21/c. In the 1,1,3,3-tetracyano-2-ethoxypropenide anion, the two independent ... -
1,2,5-Selenadiazolo[3,4-b]pyrazines : synthesis from 3,4-Diamino-1,2,5-selenadiazole and Generation of Persistent Radical Anions
(2015-09) - Journal articleSynthesis of 3,4-disubstituted and fused 1,2,5-selenadiazolo[3,4-b]pyrazines via previously unknown 3,4-diamino-1,2,5-selenadiazole has been achieved in moderate to high yields. The compounds synthesized were characterized ... -
1,2-Bis(2-bromobenzyl)diselane
(2010-10) - Journal articleIn the title compound, C14H12Br2Se2, the Se-Se bond length [2.3034 (9) angstrom] is similar to those in diphenyl diselenide [2.3066 (7) and 2.3073 (10) angstrom] and shorter than that in 1,8-diselenonaphthalene [2.0879 (8) ... -
1,4-Oxazine
(2013) - Journal articleThe fundamental heterocyclic compound 1,4-oxazine has been generated using FVP. It is the first parent heterocycle among all the possible isomeric oxazines, thiazines and their heavier atom analogues to be characterised ... -
1,5,6-Triphenyl-8-oxa-7-selena-6-phosphabicyclo[3.2.1]octane-6-selone
(2008-01) - Journal articleThe structure of the title compound, C23H21OPSe2, consists of fused puckered five- and six-membered rings, PSeC2O and C5O, respectively, with a C2O bridgehead. The C5O ring adopts a chair conformation, whilst the C2PSeO ... -
1-(3-Phenylpropyl)urea
(2009-10) - Journal articleIn the crystal of the title compound, C10H14N2O, double supramolecular layers of PhCH2CH2CH2NHC(O)NH2 are formed parallel to the bc plane by intermolecular N-H center dot center dot center dot O hydrogen bonding, with ... -
1-(Benzo[d]thiazol-2-yl)-3-phenylureas as dual inhibitors of casein kinase 1 and ABAD enzymes for treatment of neurodegenerative disorders
(2018) - Journal articleSeveral neurodegenerative disorders including Alzheimer’s disease (AD) have been connected with deregulation of casein kinase 1 (CK1) activity. Inhibition of CK1 therefore presents a potential therapeutic strategy against ... -
A 1.9 Earth radius rocky planet and the discovery of a non-transiting planet in the Kepler-20 system
(2016-11-11) - Journal articleKepler-20 is a solar-type star (V = 12.5) hosting a compact system of five transiting planets, all packed within the orbital distance of Mercury in our own Solar System. A transition from rocky to gaseous planets with a ... -
1.9 µm waveguide laser fabricated by ultrafast laser inscription in Tm:Lu2O3 ceramic
(2017-06-26) - Journal articleThe ultrafast laser inscription technique has been used to fabricate channel waveguides in Tm3+-doped Lu2O3 ceramic gain medium for the first time to our knowledge. Laser operation has been demonstrated using a monolithic ... -
1/3 magnetization plateau and frustrated ferrimagnetism in a sodium iron phosphite
(2016-04-01) - Journal articleThe sodium-iron phosphite NaFe3(HPO3)2(H2PO3)6 is studied by ac-magnetic susceptibility, pulsed-field magnetization, specific heat, and high-frequency electron spin resonance (HF-ESR) measurements combined with Mössbauer ... -
13C-1H coupling constants as a conformational tool for structural assignment of quinic and octulosonic Acid
(2018-11) - Journal articleA complete set of NMR coupling constants (1JC-H, 2JC-H, 3JC-H, and 3JH-H) were calculated for the eight stereoisomers of quinic acid, at the B3LYP/6-311G(d,p)/PCM(methanol) level of theory. The Fermi contact term of the ... -
The 13th data release of the Sloan Digital Sky Survey : first spectroscopic data from the SDSS-IV Survey MApping Nearby Galaxies at Apache Point Observatory
(2017-12) - Journal articleThe fourth generation of the Sloan Digital Sky Survey (SDSS-IV) began observations in July 2014. It pursues three core programs: APOGEE-2,MaNGA, and eBOSS. In addition, eBOSS contains two major subprograms: TDSS and SPIDERS. ... -
150,000-year palaeoclimate record from northern Ethiopia supports early, multiple dispersals of modern humans from Africa
(2018-01-18) - Journal articleClimatic change is widely acknowledged to have played a role in the dispersal of modern humans out of Africa, but the timing is contentious. Genetic evidence links dispersal to climatic change ~60,000 years ago, despite ... -
16S rRNA gene metabarcoding and TEM reveals different ecological strategies within the genus Neogloboquadrina (planktonic foraminifer)
(2018-01-29) - Journal articleUncovering the complexities of trophic and metabolic interactions among microorganisms is essential for the understanding of marine biogeochemical cycling and modelling climate-driven ecosystem shifts. High-throughput DNA ... -
17O solid-state NMR spectroscopy of A2B2O7 oxides : quantitative isotopic enrichment and spectral acquisition?
(2018-02-14) - Journal articleThe potential of 17O NMR spectroscopy for the investigation of A2B2O7 ceramic oxides important in the encapsulation of radioactive waste, is demonstrated, with post-synthetic enrichment by exchange with 17O2 gas. For ... -
17ß-Estradiol protects against the effects of a high fat diet on cardiac glucose, lipid and nitric oxide metabolism in rats
(2017-05-05) - Journal articleThe aim of this study was to investigate the in vivo effects of estradiol (E2) on myocardial metabolism and inducible nitric oxide synthase (iNOS) expression/activity in obese rats. Male Wistar rats were fed with a normal ... -
2 μm solid-state laser mode-locked by single-layer graphene
(2013-01-07) - Journal articleWe report a 2 μm ultrafast solid-state Tm : Lu2O3 laser, mode-locked by single-layer graphene, generating transform-limited similar to 410 fs pulses, with a spectral width similar to 11.1 nm at 2067 nm. The maximum average ... -
2,2 '-o-Phenylenediacetonitrile
(2009-11) - Journal articleIn the title compound, NCCH2C6H4CH2CN, the bond lengths and angles are within normal ranges. The benzene ring makes dihedral angles of 4.94 (8) and 77.04 (8)degrees with the C-C-C-N mean planes. Weak non-conventional C-H ... -
2,4,5-Triphenyl-1,3,2-dioxaphospholan-2-one
(2011-07) - Journal articleThe dioxaphospholane ring in the title compound, C20H17O3P, adopts an envelope conformation about one of the ring carbons. The benzene rings of the compound do not form face-to-face pi-pi interactions, instead weak C-H ... -
2-(4-Fluorophenyl)-3-methyl-1H-indole
(2011-07) - Journal articleThe indole N-H hydrogen in the title compound, C15H12FN, does not display classical hydrogen bonding. Rather it forms an interaction with the pi system of an adjacent indole, resulting in weakly interacting chains along ...