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Selective NaOH-catalysed hydration of aromatic nitriles to amides

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dc.contributor.authorSchmid, Thibault
dc.contributor.authorGomez Herrera, Alberto
dc.contributor.authorSongis, Olivier
dc.contributor.authorSneddon , Deborah
dc.contributor.authorRévolte , Antoine
dc.contributor.authorNahra, Fady
dc.contributor.authorCazin, Catherine S.J.
dc.date.accessioned2016-03-18T00:01:16Z
dc.date.available2016-03-18T00:01:16Z
dc.date.issued2015-05-01
dc.identifier.citationSchmid , T , Gomez Herrera , A , Songis , O , Sneddon , D , Révolte , A , Nahra , F & Cazin , C S J 2015 , ' Selective NaOH-catalysed hydration of aromatic nitriles to amides ' , Catalysis Science & Technology , vol. 5 , no. 5 , pp. 2865-2868 . https://doi.org/10.1039/C5CY00313Jen
dc.identifier.issn2044-4753
dc.identifier.otherPURE: 175341936
dc.identifier.otherPURE UUID: 9f172d0d-2535-47e7-938f-19b062156235
dc.identifier.otherScopus: 84929493339
dc.identifier.otherWOS: 000353641800036
dc.identifier.urihttps://hdl.handle.net/10023/8434
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC)en
dc.description.abstractThe selective synthesis of aromatic and heteroaromatic amides through base-catalysed hydration of nitriles was achieved using inexpensive and commercially available NaOH as the only catalyst. A wide range of nitriles was selectively converted to their corresponding amides. Kinetic studies show that the double hydration of nitriles towards undesirable carboxylic acids is negligible under our reaction conditions.
dc.language.isoeng
dc.relation.ispartofCatalysis Science & Technologyen
dc.rightsCopyright 2015 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C5CY00313J.en
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleSelective NaOH-catalysed hydration of aromatic nitriles to amidesen
dc.typeJournal articleen
dc.contributor.sponsorThe Royal Societyen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C5CY00313J
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-03-18
dc.identifier.urlhttp://www.rsc.org/suppdata/c5/cy/c5cy00313j/c5cy00313j1.pdfen
dc.identifier.grantnumberUF100691en


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