Now showing items 1-3 of 3
Synthesis, adsorption and catalysis of large pore metal phosphonates
(University of St Andrews, 2010-06) - Thesis,
The synthesis and properties of metal phosphonates prepared using piperazine-based bisphosphonic acids have been investigated. The ligands N,N’-piperazinebis(methylenephosphonic acid) (H₄L), and the 2-methyl (H₄L-Me) and ...
Synthesis, characterisation and adsorption properties of metal-organic frameworks and the structural response to functionalisation and temperature
(University of St Andrews, 2012-07) - Thesis,
The synthesis of a scandium aluminium methylphosphonate ScAl₃(CH₃PO₃)₆ isostructural to the aluminium methylphosphonate AlMePO-α and with permanent microporosity is reported here for the first time. Structural characterisation ...
Synthesis and properties of scandium carboxylate metal-organic frameworks
(University of St Andrews, 2015-06-24) - Thesis,
This work investigated the synthesis, characterisation and properties of known and novel scandium carboxylate Metal-organic Frameworks (MOFs). The first part reports the performance of these Sc-MOFs as Lewis acid catalysts. ...