Perovskite-derived structure modulation in the iron sulfate family
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We report the first example of a perovskite sulfate [Na3(H2O)]Fe(SO4)3. Further structure modulation, by dimensional reduction or ligand extension, has resulted in two related layered perovskite-like compounds Na6Fe(SO4)4 and Na12Fe3(SO4)6F8. Taken together, these results open up a more general strategy for the future design of more complex perovskite-related materials.
Lan , Y , Yan , Q , Zhang , X , Yao , W , Wang , C , Lee , C-S , Lightfoot , P & Tang , Y 2022 , ' Perovskite-derived structure modulation in the iron sulfate family ' , Chemical Communications , vol. 58 , no. 50 , pp. 7074-7077 . https://doi.org/10.1039/d2cc02242g
Copyright © 2022 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/D2CC02242G
DescriptionFunding: Authors acknowledge support from Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality (China). The authors acknowledge support from the National Natural Science Foundation of China (52125105, 22005329, 51972329, 52061160484), the Shenzhen Science and Technology Planning Project (JCYJ20190807172001755, JCYJ20210324101016039, JCYJ20210324101203009), and the Science and Technology Planning Project of Guangdong Province (2019A1515110975, 2021A1515010184, 2019TX05L389).
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