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dc.contributor.authorLi, Cheng-Peng
dc.contributor.authorZhou, Hang
dc.contributor.authorChen, Jing
dc.contributor.authorWang, Jia-Jun
dc.contributor.authorDu, Miao
dc.contributor.authorZhou, Wuzong
dc.identifier.citationLi , C-P , Zhou , H , Chen , J , Wang , J-J , Du , M & Zhou , W 2020 , ' A highly efficient coordination polymer for selective trapping and sensing of perrhenate/pertechnetate ' , ACS Applied Materials & Interfaces , vol. 12 , no. 13 , pp. 15246-15254 .
dc.identifier.otherPURE: 267091897
dc.identifier.otherPURE UUID: 399de14a-8cc1-41bf-9d66-50b1d47bb7c5
dc.identifier.otherRIS: urn:70BCDA64424B218A4EABFF69C9EE77E7
dc.identifier.otherORCID: /0000-0001-9752-7076/work/71221163
dc.identifier.otherScopus: 85082779485
dc.identifier.otherWOS: 000526566900060
dc.descriptionThis work was financially supported by the National Natural Science Foundation of China (21771139), Tianjin Natural Science Foundation (17JCYBJC22800), and the Program for Innovative Research Team in University of Tianjin (TD13-5074).en
dc.description.abstractA porous cationic Ag(I) coordination polymer, [Ag(1,2,4,5-p4b)](SbF6) (TJNU-302) with the ligand 1,2,4,5-p4b (1,2,4,5-tetra(pyridin-4-yl)benzene), is reported that shows high sorption capacity (211 mg g–1) and distribution coefficient Kd (5.8 × 105 mL g–1) as well as outstanding selectivity in 500 times excess of CO32– or PO43– anion for perrhenate removal. TJNU-302 can act as a crystalline turn-off sensor for perrhenate upon UV radiation. In this way, a test paper strip for sensing ReO4– could be produced. In water solution, TJNU-302 shows an efficient fluorescence quenching response to ReO4– ion, with the highest quenching percentage (86%) among all reported ReO4– sensors. These results could be elucidated by the bonding properties of single-crystal structures of TJNU-302 before and after perrhenate sorption, as well as density functional theory (DFT) calculations.
dc.relation.ispartofACS Applied Materials & Interfacesen
dc.rightsCopyright © 2020 American Chemical Society. This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at
dc.subjectCoordination polymersen
dc.subjectAnion exchangeen
dc.subjectFluorescence sensoren
dc.subjectTest paperen
dc.subjectQD Chemistryen
dc.titleA highly efficient coordination polymer for selective trapping and sensing of perrhenate/pertechnetateen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.description.statusPeer revieweden

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