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dc.contributor.authorVeenboer, Rik
dc.contributor.authorAzofra, Luis
dc.contributor.authorGasperini, Danila
dc.contributor.authorCollado, Alba
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorCavallo, Luigi
dc.contributor.authorNolan, Steven
dc.identifier.citationVeenboer , R , Azofra , L , Gasperini , D , Collado , A , Cordes , D B , Slawin , A M Z , Cavallo , L & Nolan , S 2019 , ' Regression analysis of properties of [Au(IPr)(CHR 2 )] complexes ' , Dalton Transactions , vol. 48 , no. 22 , pp. 7693-7703 .
dc.identifier.otherPURE: 258978420
dc.identifier.otherPURE UUID: 7ee4ba62-babf-4be4-b37d-a5c83acf139c
dc.identifier.otherScopus: 85066850530
dc.identifier.otherWOS: 000470709700023
dc.identifier.otherORCID: /0000-0002-9527-6418/work/62668369
dc.identifier.otherORCID: /0000-0002-5366-9168/work/62668386
dc.descriptionThe European Research Council (ERC) and the Engineering and Physical Sciences Research Council (EPSRC), UK, are gratefully acknowledged for their support. L.C., and S.P.N. thank the King Abdullah University of Science and Technology (KAUST) and Kind Saud University (KSU) for support.en
dc.description.abstractNew [Au(IPr)(CHR2)] complexes have been synthesised through protonolysis reactions of [Au(IPr)(OH)] with moderately acidic substrates, CH2R2. An array of spectroscopic (IR and NMR), structural (X-ray), electronic (DFT) and experimental (reactivity) parameters was collected to quantify the variation in stereoelectronic properties of these new and previously reported [Au(IPr)(CHR2)] complexes. Variation of the R substituents on the carbanion ligands (CHR2–) was found to have a crucial impact on parameters characterising the resulting gold complexes. A regression analysis of both experimental and modelled parameters, guided by network analysis techniques, produced linear models that supported trends within the [Au(IPr)(CHR2)] complexes.
dc.relation.ispartofDalton Transactionsen
dc.rightsCopyright © 2019 The Author(s). This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at
dc.subjectQD Chemistryen
dc.titleRegression analysis of properties of [Au(IPr)(CHR2)] complexesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.description.statusPeer revieweden

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