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Regression analysis of properties of [Au(IPr)(CHR2)] complexes

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dc.contributor.authorVeenboer, Rik
dc.contributor.authorAzofra, Luis
dc.contributor.authorGasperini, Danila
dc.contributor.authorCollado, Alba
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorCavallo, Luigi
dc.contributor.authorNolan, Steven
dc.date.accessioned2020-05-06T23:32:12Z
dc.date.available2020-05-06T23:32:12Z
dc.date.issued2019-06-14
dc.identifier.citationVeenboer , R , Azofra , L , Gasperini , D , Collado , A , Cordes , D B , Slawin , A M Z , Cavallo , L & Nolan , S 2019 , ' Regression analysis of properties of [Au(IPr)(CHR 2 )] complexes ' , Dalton Transactions , vol. 48 , no. 22 , pp. 7693-7703 . https://doi.org/10.1039/C9DT00841Aen
dc.identifier.issn1477-9226
dc.identifier.otherPURE: 258978420
dc.identifier.otherPURE UUID: 7ee4ba62-babf-4be4-b37d-a5c83acf139c
dc.identifier.otherScopus: 85066850530
dc.identifier.otherWOS: 000470709700023
dc.identifier.otherORCID: /0000-0002-9527-6418/work/62668369
dc.identifier.otherORCID: /0000-0002-5366-9168/work/62668386
dc.identifier.urihttps://hdl.handle.net/10023/19891
dc.descriptionThe European Research Council (ERC) and the Engineering and Physical Sciences Research Council (EPSRC), UK, are gratefully acknowledged for their support. L.C., and S.P.N. thank the King Abdullah University of Science and Technology (KAUST) and Kind Saud University (KSU) for support.en
dc.description.abstractNew [Au(IPr)(CHR2)] complexes have been synthesised through protonolysis reactions of [Au(IPr)(OH)] with moderately acidic substrates, CH2R2. An array of spectroscopic (IR and NMR), structural (X-ray), electronic (DFT) and experimental (reactivity) parameters was collected to quantify the variation in stereoelectronic properties of these new and previously reported [Au(IPr)(CHR2)] complexes. Variation of the R substituents on the carbanion ligands (CHR2–) was found to have a crucial impact on parameters characterising the resulting gold complexes. A regression analysis of both experimental and modelled parameters, guided by network analysis techniques, produced linear models that supported trends within the [Au(IPr)(CHR2)] complexes.
dc.language.isoeng
dc.relation.ispartofDalton Transactionsen
dc.rightsCopyright © 2019 The Author(s). This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C9DT00841Aen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleRegression analysis of properties of [Au(IPr)(CHR2)] complexesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doihttps://doi.org/10.1039/C9DT00841A
dc.description.statusPeer revieweden
dc.date.embargoedUntil2020-05-07


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