Now showing items 1-10 of 1080
Flash vacuum pyrolysis of α-acyl-o-methoxybenzylidenetriphenylphosphoranes to give 2-substituted benzofurans
(ARKAT, 2000) - Journal article,
The title stabilised ylides, readily prepared in one step from acid chlorides, are converted upon FVP at 850 °C into 2-substituted benzofurans. When the acyl group is aromatic it appears unchanged as the 2- substituent in ...
The X-ray structure of 4-aminobenzyl alcohol (4-aminophenylmethanol)
(2018-11-02) - Journal article,
A second polymorph of 4-aminobenzyl alcohol [orthorhombic, a = 8.95051(15), b = 5.8248(1), c = 12.1645(2) Å, space group Pna21] shows a "herringbone" structure with stacks of hydrogen-bonded molecules when viewed down the b-axis.
Yeast three-hybrid screen identifies TgBRADIN/GRA24 as a negative regulator of Toxoplasma gondii bradyzoite differentiation
(2015-03-19) - Journal article,
Differentiation of the protozoan parasite Toxoplasma gondii into its latent bradyzoite stage is a key event in the parasite’s life cycle. Compound 2 is an imidazopyridine that was previously shown to inhibit the parasite ...
50-1: Invited paper: Recent advances in measuring and understanding the influence of molecular alignment on the light extraction efficiency of OLEDs
(2017) - Journal item,
We review recent progress in controlling the alignment of the transition dipole moment of electroluminescent molecules to maximize the light extraction efficiency in OLEDs. Particular focus devoted to ways of measuring ...
All-cis 1,2,3,4,5,6-hexafluorocyclohexane is a facially polarised cyclohexane
(2015-04) - Journal article,
The highest-energy stereoisomer of 1,2,3,4,5,6-hexafluorocyclohexane, in which all of the fluorines are ‘up’, is prepared in a 12-step protocol. The molecule adopts a classic chair conformation with alternate C–F bonds ...
Mechanistic study of Ru-NHC-catalyzed hydrodefluorination of fluoropyridines : the influence of the NHC on the regioselectivity of C–F activation and chemoselectivity of C–F versus C–H bond cleavage
(2015-02-06) - Journal article,
We describe a combined experimental and computational study into the scope, regioselectivity, and mechanism of the catalytic hydrodefluorination (HDF) of fluoropyridines, C5F5?xHxN (x = 0?2), at two Ru(NHC)(PPh3)2(CO)H2 ...
Fractionation and DOSY NMR as analytical tools : from model polymers to a technical lignin
(2017-11-30) - Journal article,
One key challenge hindering the valorization of lignin is its structural complexity. Artificial lignin-like materials provide a stepping stone between the simplicity of model compounds and the complexity of lignin. Here, ...
Correlation of dielectric, electrical and magnetic properties near the magnetic phase transition temperature of cobalt zinc ferrite
(2017-01-07) - Journal article,
Multiferroic composite structures, i.e., composites of magnetostrictive and piezoelectric materials can be envisioned towards the goal of achieving strong room-temperature ME coupling for real practical device applications. ...
A biocatalytic approach towards the stereoselective synthesis of protected inositols
(2017-02-01) - Journal article,
A biocatalytic flow system utilising Trypanosoma brucei L-myo-inositol 1-phosphate synthase has been developed to prepare significant quantities of L-myo-inositol 1-phosphate. Using this highly valuable biochemical, we ...
Welcome to JPhys Energy
(2018-11-20) - Journal item,
JPhys Energy is an innovative new open access journal that aims to set the agenda in identifying and publishing the most impactful work in emerging and cutting-edge areas of energy-related research. An interdisciplinary ...