Now showing items 1-7 of 7
First charge-transfer complexes between tetrathiafulvalene and 1,2,5-chalcogenadiazole derivatives : design, synthesis, crystal structures, electronic and electrical properties
(2012-12-31) - Journal article
The first charge-transfer complexes of tetrathiafulvalene (1) with 1,2,5-chalcogenadiazole derivatives, i.e. with [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazole (2) and 3,4-dicyano-1,2,5-telluradiazole (3), were designed, ...
Interactions of trivalent lanthanide cations with a new hexadentate di-Schiff base : new lanthanide(III) complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)
(2010) - Journal article
The novel lanthanide(III) complexes [Ln(NO3)(2)L](NO3)center dot 3MeOH (Ln = La 1, Pr 2) and [Ln(NO3)(3)L](NO3)center dot 2MeOH (Ln = Gd 3, Yb 4), where L = (NE,N'E)-2,2'-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethy ...
How Not to Discover a New Reagent. The Evolution and Chemistry of Woollins' Reagent
(2012-05) - Journal article
The pathways in research can be complex. This review provides a personal account of the winding scientific and funding road that led to Woollins' reagent. The synthesis and applications of Woollins' reagent are summarised.
Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s
(2012-07-25) - Journal article
The reaction of sodium alkoxides [(RONa)-O-1, R-1 = CH3, CH3CH2, (CH3)(2)CH and CH3CH2CH2] with 2,4-diphenyl-1,3-diselenadiphosphetane-2,4-diselenide [PhP(Se)(mu-Se)](2) (Woollins' reagent, WR) gave the non-symmetric sodium ...
Phosphorus–tellurium heterocycles and their lighter chalcogen analogues : from small rings to macrocycles
(University of St Andrews, 2014-12-01) - Thesis
The research on phosphorus-chalcogen compounds enjoys a long tradition in the field of inorganic chemistry, which has led to applications such as strike-anywhere matches, precursors for metal chalcogenide thin films and ...
Theoretical and experimental investigation of anticancer activities of an acyclic and symmetrical compartmental Schiff base ligand and its Co(ii), Cu(ii) and Zn(ii) complexes
(2018-10-17) - Journal article
A compartmental Schiff base ligand, 2,2′-((((((2-hydroxypropane-1,3-diyl)bis(oxy))bis(2,1-phenylene))bis(methylene))bis(azanylylidene))bis(methanylylidene))bis(4-bromophenol) (H3LBr) and its complexes with cobalt(ii), ...
Planar P6E6 (E = Se, S) macrocycles incorporating P2N2 scaffolds
(2012-05) - Journal article
Oxidation of alkali metal derivatives of the dianions [E((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)E](2-) (E = S, Se) with I-2 produces 15-membered macrocycles in which a planar P6E6 motif is stabilised by perpendicular ...