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dc.contributor.authorShearan, Stephen J.I.
dc.contributor.authorStock, Norbert
dc.contributor.authorEmmerling, Franziska
dc.contributor.authorDemel, Jan
dc.contributor.authorWright, Paul A.
dc.contributor.authorDemadis, Konstantinos D.
dc.contributor.authorVassaki, Maria
dc.contributor.authorCostantino, Ferdinando
dc.contributor.authorVivani, Riccardo
dc.contributor.authorSallard, Sébastien
dc.contributor.authorRuiz Salcedo, Inés
dc.contributor.authorCabeza, Aurelio
dc.contributor.authorTaddei, Marco
dc.date.accessioned2019-05-27T10:30:05Z
dc.date.available2019-05-27T10:30:05Z
dc.date.issued2019-05-24
dc.identifier.citationShearan , S J I , Stock , N , Emmerling , F , Demel , J , Wright , P A , Demadis , K D , Vassaki , M , Costantino , F , Vivani , R , Sallard , S , Ruiz Salcedo , I , Cabeza , A & Taddei , M 2019 , ' New directions in metal phosphonate and phosphinate chemistry ' , Crystals , vol. 9 , no. 5 , 270 . https://doi.org/10.3390/cryst9050270en
dc.identifier.issn2073-4352
dc.identifier.otherPURE: 259098197
dc.identifier.otherPURE UUID: 32eb210f-5834-432a-97d0-436b003dd47d
dc.identifier.otherBibtex: urn:6be475dd15e04889d8bbb874ff507c1e
dc.identifier.otherScopus: 85067818949
dc.identifier.otherWOS: 000472674400046
dc.identifier.otherORCID: /0000-0002-4243-9957/work/62668312
dc.identifier.urihttp://hdl.handle.net/10023/17764
dc.descriptionM.T is supported by funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement No 663830.en
dc.description.abstractIn September 2018, the First European Workshop on Metal Phosphonates Chemistry brought together some prominent researchers in the field of metal phosphonates and phosphinates with the aim of discussing past and current research efforts and identifying future directions. The scope of this perspective article is to provide a critical overview of the topics discussed during the workshop, which are divided into two main areas: synthesis and characterisation, and applications. In terms of synthetic methods, there has been a push towards cleaner and more efficient approaches. This has led to the introduction of high-throughput synthesis and mechanochemical synthesis. The recent success of metal–organic frameworks has also promoted renewed interest in the synthesis of porous metal phosphonates and phosphinates. Regarding characterisation, the main advances are the development of electron diffraction as a tool for crystal structure determination and the deployment of in situ characterisation techniques, which have allowed for a better understanding of reaction pathways. In terms of applications, metal phosphonates have been found to be suitable materials for several purposes: they have been employed as heterogeneous catalysts for the synthesis of fine chemicals, as solid sorbents for gas separation, notably CO2 capture, as materials for electrochemical devices, such as fuel cells and rechargeable batteries, and as matrices for drug delivery.
dc.language.isoeng
dc.relation.ispartofCrystalsen
dc.rightsCopyright ©2019 by the authors. Licensee MDPI, Basel, Switzerland. This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).en
dc.subjectMetal phosphonates and phosphinatesen
dc.subjectLayered materialsen
dc.subjectMetal–organic frameworksen
dc.subjectSynthesisen
dc.subjectX-ray and electron diffractionen
dc.subjectIn situ characterisationen
dc.subjectHeterogenous catalysisen
dc.subjectGas sorption/separationen
dc.subjectProton conductionen
dc.subjectRechargeable batteriesen
dc.subjectDrug deliveryen
dc.subjectQD Chemistryen
dc.subjectT-NDASen
dc.subject.lccQDen
dc.titleNew directions in metal phosphonate and phosphinate chemistryen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3390/cryst9050270
dc.description.statusPeer revieweden


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