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dc.contributor.authorAitken, R Alan
dc.contributor.authorSmith, Melanja H
dc.contributor.authorWilson, Heather S
dc.date.accessioned2017-03-14T00:32:51Z
dc.date.available2017-03-14T00:32:51Z
dc.date.issued2016-06-05
dc.identifier.citationAitken , R A , Smith , M H & Wilson , H S 2016 , ' Variable temperature 1 H and 13 C NMR study of restricted rotation in N,N -bis(2-hydroxyethyl)acetamide ' , Journal of Molecular Structure , vol. 1113 , pp. 171-173 . https://doi.org/10.1016/j.molstruc.2016.02.030en
dc.identifier.issn0022-2860
dc.identifier.otherPURE: 240872862
dc.identifier.otherPURE UUID: 1e0e926f-12d8-4d01-8cd0-e2ad8a1461da
dc.identifier.otherScopus: 84959010868
dc.identifier.otherORCID: /0000-0001-6959-5311/work/34857570
dc.identifier.otherWOS: 000373544300020
dc.identifier.urihttp://hdl.handle.net/10023/10461
dc.description.abstractN,N-bis(2-hydroxyethyl)acetamide shows restricted rotation about the amide bond in both 1H and 13C NMR spectra rendering the two hydroxyethyl groups non-equivalent. A variable temperature study in CD3SOCD3 allowed estimation of the free energy barrier to rotation as 75.6 ± 0.2 kJ mol–1. Previously published data in CDCl3 appears to be erroneous.
dc.format.extent3
dc.language.isoeng
dc.relation.ispartofJournal of Molecular Structureen
dc.rightsCopyright © 2016 Elsevier B.V. All rights reserved. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://dx.doi.org/10.1016/j.molstruc.2016.02.030en
dc.subjectVariable temperature NMRen
dc.subjectRestricted rotationen
dc.subjectAmide bonden
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleVariable temperature 1H and 13C NMR study of restricted rotation in N,N-bis(2-hydroxyethyl)acetamideen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1016/j.molstruc.2016.02.030
dc.description.statusPeer revieweden
dc.date.embargoedUntil2017-03-13
dc.identifier.urlhttp://www.sciencedirect.com/science/article/pii/S0022286016301247#appd001en


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