Now showing items 1-2 of 2

    • The gold(I)-catalysed protodecarboxylation mechanism 

      Dupuy, Stephanie; Crawford, Luke; Buehl, Michael; Nolan, Steven Patrick (2015-02-16) - Journal article
      A mechanistic study of the gold-catalysed protodecarboxylation is described. Each reaction step has been investigated experimentally and computationally. More specifically, the activation parameters for the decarboxylation ...
    • Mechanistic studies on quinolinate phosphoribosyltransferase 

      Catton, Gemma Rachel (University of St Andrews, 2008-06) - Thesis
      Quinolinate phosphoribosyltransferase (QPRTase, EC 2.4.2.19) is an intriguing enzyme which appears to catalyse two distinct chemical reactions; transfer of a phosphoribosyl moiety from 5-phosphoribosyl-1-pyrophosphate to ...