The influence of cation doping on the electronic properties of Sr₃Ru₂O₇
Abstract
Sr₃Ru₂O₇ is a quasi-two-dimensional metal and has a paramagnetic ground state that
is heavily renormalised by electron-electron correlations and magnetic exchange
interactions. Inextricably linked to this renormalisation is the metamagnetism of
Sr₃Ru₂O₇ - a rapid rise in uniform magnetisation over a narrow range of applied
magnetic field. Knowledge of the zero-field physics is essential to any description of
the metamagnetism. Light may be shed on the enigmatic ground state of Sr₃Ru₂O₇ by
doping the crystal lattice with foreign cations: this is the primary purpose of the
original research referred to in this thesis, in which studies of some of the electronic
properties of crystals of cation-doped Sr₃Ru₂O₇ are reported. Single crystals of
Sr₃(Ru[subscript(1-x)]Ti[subscript(x)])₂O₇ and Sr₃(Ru[subscript(1-x)]Cr[subscript(x)])₂O₇ have been synthesised in an image furnace and
some of the properties of these crystals have been measured. Evidence that indicates
the emergence of a spin density wave as a function of Ti-doping in Sr₃(Ru[subscript(1-x)]Ti[subscript(x)])₂O₇ is
presented. Time-dependent magnetic irreversibility has been observed in samples of
Sr₃(Ru[subscript(1-x)]Cr[subscript(x)])₂O₇, thus hinting at the involvement of the RKKY mechanism in these
materials. Regarding cation doping out of the conducting RuO₂ planes, samples of
(Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ have been grown and investigated. Both the Sommerfeld coefficient
and the Fermi liquid A coefficient of (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ are found to decrease as a
function of y (0 ≤ y ≤ 0.02); these observations point towards a reduction in the
thermodynamic mass of the Landau quasiparticles. Results from magnetoresistance
and magnetisation measurements indicate that the metamagnetism of the (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ series probably cannot be explained by a rigid band-shift model. Also,
some aspects of these data imply that the metamagnetism cannot be fully accounted
for by a spin fluctuation extension to the Ginzburg-Landau theory of uniform
magnetisation.
Type
Thesis, PhD Doctor of Philosophy
Collections
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.