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Please use this identifier to cite or link to this item: http://hdl.handle.net/10023/689
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Jason Farrell thesis PhD.pdf8.3 MBAdobe PDFView/Open
Title: The influence of cation doping on the electronic properties of Sr₃Ru₂O₇
Authors: Farrell, Jason
Supervisors: Mackenzie, Andrew P.
Keywords: Sr₃Ru₂O₇
Ruthenate
Correlated electrons
Magnetism
Low temperature
Cryogenics
Crystal growth
Floating zone
Cation doping
Metamagnetism
Quantum criticality
Perovskite
Emergence
Complexity
Image furnace
Fermi liquid
Ginzburg Landau
Stoner model
Incongruent
Adiabatic demagnetisation
SQUID magnetometer
Continuous flow cryostat
Dilution refrigerator
Heat capacity
EDX
Electron probe
Issue Date: 27-Nov-2008
Abstract: Sr₃Ru₂O₇ is a quasi-two-dimensional metal and has a paramagnetic ground state that is heavily renormalised by electron-electron correlations and magnetic exchange interactions. Inextricably linked to this renormalisation is the metamagnetism of Sr₃Ru₂O₇ - a rapid rise in uniform magnetisation over a narrow range of applied magnetic field. Knowledge of the zero-field physics is essential to any description of the metamagnetism. Light may be shed on the enigmatic ground state of Sr₃Ru₂O₇ by doping the crystal lattice with foreign cations: this is the primary purpose of the original research referred to in this thesis, in which studies of some of the electronic properties of crystals of cation-doped Sr₃Ru₂O₇ are reported. Single crystals of Sr₃(Ru[subscript(1-x)]Ti[subscript(x)])₂O₇ and Sr₃(Ru[subscript(1-x)]Cr[subscript(x)])₂O₇ have been synthesised in an image furnace and some of the properties of these crystals have been measured. Evidence that indicates the emergence of a spin density wave as a function of Ti-doping in Sr₃(Ru[subscript(1-x)]Ti[subscript(x)])₂O₇ is presented. Time-dependent magnetic irreversibility has been observed in samples of Sr₃(Ru[subscript(1-x)]Cr[subscript(x)])₂O₇, thus hinting at the involvement of the RKKY mechanism in these materials. Regarding cation doping out of the conducting RuO₂ planes, samples of (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ have been grown and investigated. Both the Sommerfeld coefficient and the Fermi liquid A coefficient of (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ are found to decrease as a function of y (0 ≤ y ≤ 0.02); these observations point towards a reduction in the thermodynamic mass of the Landau quasiparticles. Results from magnetoresistance and magnetisation measurements indicate that the metamagnetism of the (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ series probably cannot be explained by a rigid band-shift model. Also, some aspects of these data imply that the metamagnetism cannot be fully accounted for by a spin fluctuation extension to the Ginzburg-Landau theory of uniform magnetisation.
URI: http://hdl.handle.net/10023/689
Type: Thesis
Publisher: University of St Andrews
Appears in Collections:Physics & Astronomy Theses



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