Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR
Abstract
Pulsed electron paramagnetic resonance (EPR) spectroscopy is gaining increasing importance as a complementary biophysical technique in structural biology. Here, we describe the synthesis, optimisation, and EPR titration studies of a spin-labelled terpyridine Zn(II) complex serving as a small-molecule model system for tuneable dimerisation.
Citation
Ackermann , K , Giannoulis , A , Cordes , D B , Slawin , A M Z & Bode , B E 2015 , ' Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR ' , Chemical Communications , vol. 51 , no. 25 , pp. 5257-5260 . https://doi.org/10.1039/C4CC08656B
Publication
Chemical Communications
Status
Peer reviewed
ISSN
1359-7345Type
Journal article
Rights
© 2015 The Authors. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/)
Description
AG acknowledges a postgraduate fellowship by the EPSRC funded doctoral training centre ‘integrated magnetic resonance’. BEB is grateful for an EaStCHEM Hirst Academic Fellowship by the School of Chemistry, St Andrews, and funding from the People Programme (Marie Curie Actions) of the European Union’s Seventh Framework Programme (REA 334496).Collections
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