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Title: Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocycles
Authors: Martin, Anthony
Chartoire, Anthony Raymond Georges
Slawin, Alexandra Martha Zoya
Nolan, Steven Patrick
Keywords: C-H functionalization
Direct arylation
Heterocycles
N-heterocyclic
Carbenes
Palladium
QD Chemistry
Issue Date: 27-Sep-2012
Citation: Martin , A , Chartoire , A R G , Slawin , A M Z & Nolan , S P 2012 , ' Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocycles ' Beilstein Journal of Organic Chemistry , vol 8 , pp. 1637-1643 .
Abstract: The use of [Pd(NHC)(cinnamyl)Cl] precatalysts in the direct arylation of heterocycles has been investigated. Among four different precatalysts, [Pd(SIPr)(cinnamyl)Cl] proved to be the most efficient promoter of the reaction. The C–H functionalization of sulfuror nitrogen-containing heterocycles has been achieved at low catalyst loadings. These catalyst charges range from 0.1 to 0.01 mol % palladium.
Version: Publisher PDF
Status: Peer reviewed
URI: http://hdl.handle.net/10023/3257
DOI: http://dx.doi.org/10.3762/bjoc.8.187
ISSN: 1860-5397
Type: Journal article
Rights: © 2012 Martin et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)
Appears in Collections:Chemistry Research
University of St Andrews Research



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