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| Title: | Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocycles |
| Authors: | Martin, Anthony
Chartoire, Anthony Raymond Georges
Slawin, Alexandra Martha Zoya
Nolan, Steven Patrick |
| Keywords: | C-H functionalization
Direct arylation
Heterocycles
N-heterocyclic
Carbenes
Palladium
QD Chemistry |
| Issue Date: | 27-Sep-2012 |
| Citation: | Martin , A , Chartoire , A R G , Slawin , A M Z & Nolan , S P 2012 , ' Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : Direct arylation of heterocycles ' Beilstein Journal of Organic Chemistry , vol 8 , pp. 1637-1643 . |
| Abstract: | The use of [Pd(NHC)(cinnamyl)Cl] precatalysts in the direct arylation of heterocycles has been investigated. Among four different precatalysts, [Pd(SIPr)(cinnamyl)Cl] proved to be the most efficient promoter of the reaction. The C–H functionalization of sulfuror nitrogen-containing heterocycles has been achieved at low catalyst loadings. These catalyst charges range from 0.1 to 0.01 mol % palladium. |
| Version: | Publisher PDF |
| Status: | Peer reviewed |
| URI: | http://hdl.handle.net/10023/3257 |
| DOI: | http://dx.doi.org/10.3762/bjoc.8.187 |
| ISSN: | 1860-5397 |
| Type: | Journal article |
| Rights: | © 2012 Martin et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc) |
| Appears in Collections: | Chemistry Research
University of St Andrews Research
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