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| Title: | The role of silver additives in gold-mediated C-H functionalisation |
| Authors: | Patrick, Scott R.
Boogaerts, Ine I. F.
Gaillard, Sylvain
Slawin, Alexandra M. Z.
Nolan, Steven P. |
| Keywords: | C-H functionalisation
Gold catalyst
Halide abstraction
N-heterocyclic carbene
Silver salt
Substrate activation
N-Heterocyclic carbenes
Bond formation
Catalysis
Arylation
Complexes
Acid
QD Chemistry |
| Issue Date: | 1-Jul-2011 |
| Citation: | Patrick , S R , Boogaerts , I I F , Gaillard , S , Slawin , A M Z & Nolan , S P 2011 , ' The role of silver additives in gold-mediated C-H functionalisation ' Beilstein Journal of Organic Chemistry , vol 7 , pp. 892-896 . |
| Abstract: | The role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C-H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given. |
| Version: | Publisher PDF |
| Status: | Peer reviewed |
| URI: | http://hdl.handle.net/10023/3035 |
| DOI: | http://dx.doi.org/10.3762/bjoc.7.102 |
| ISSN: | 1860-5397 |
| Type: | Journal article |
| Rights: | © 2011 Patrick et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
| Appears in Collections: | University of St Andrews Research
Chemistry Research
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