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| Title: | Correlating Pt-P bond lengths and Pt-P coupling constants |
| Authors: | Waddell, Paul G.
Slawin, Alexandra M. Z.
Woollins, J. Derek |
| Keywords: | Nuclear-magnetic-resonance
X-ray-structure
Tertiary phosphine complexes
Transition-metal-complexes
Solid-state structures
Platinum(ii) complexes
Crystal-structures
Molecular-structure
Phosphorus ligands
Stacking compounds
QD Chemistry |
| Issue Date: | 16-Aug-2010 |
| Citation: | Waddell , P G , Slawin , A M Z & Woollins , J D 2010 , ' Correlating Pt-P bond lengths and Pt-P coupling constants ' Dalton Transactions , vol 39 , no. 37 , pp. 8620-8625 . |
| Abstract: | The X-ray structures of (5) cis-PtBr2(P(OMe)(3))(2), (6) cis-PtBr2(P(OMe)(2)Ph)(2), (7) cis-PtBr2(P(OMe)Ph-2)(2), (8) cis-PtBr2(PPh3)(2), (9) cis-PtI2(P(OMe)(3))(2), (10) cis-PtI2(P(OMe)(2)Ph)(2), (11) cis-PtI2(P(OMe)Ph-2)(2) and (12) cis-PtI2(PPh3)(2) are reported and compared with the previously reported chloride analogues. The magnitude of the J{Pt-P} varies linearly with the Pt-P bond length (l(Pt-P) = 2.421 - J/24255) for these 12 complexes. |
| Version: | Postprint |
| Status: | Peer reviewed |
| URI: | http://hdl.handle.net/10023/1980 |
| DOI: | http://dx.doi.org/10.1039/c003256e |
| ISSN: | 1477-9226 |
| Type: | Journal article |
| Rights: | This is the author's accepted version of this article. The published version (c)Royal Society of Chemistry is available from DOI: 10.1039/C003256E |
| Appears in Collections: | University of St Andrews Research
Chemistry Research
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