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2009ActaCrystE65_m1522.pdf327.72 kBAdobe PDFView/Open
Title: Tris(ethylenediamine)zinc(II) hexafluoridosilicate
Authors: Li, Yang
Shi, Qi
Slawin, Alexandra M. Z.
Woollins, J. Derek
Dong, Jinxiang
Keywords: Crystal
QD Chemistry
Issue Date: Dec-2009
Citation: Li , Y , Shi , Q , Slawin , A M Z , Woollins , J D & Dong , J 2009 , ' Tris(ethylenediamine)zinc(II) hexafluoridosilicate ' Acta Crystallographica. Section E, Structure reports online , vol 65 , no. 12 , pp. M1522-U277 .
Abstract: The title compound, [Zn(C2H8N2)(3)](SiF6), was synthesized ionothermally using choline chloride-imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octahedral geometry. The Zn-II ion is coordinated by six N atoms from three ethylenediamine molecules. The crystal structure displays weak hydrogen bonding between [SiF6](2-) anions and the ethylenediamine NH hydrogen atoms.
Version: Publisher PDF
Status: Peer reviewed
URI: http://hdl.handle.net/10023/1777
DOI: http://dx.doi.org/10.1107/S1600536809045693
ISSN: 1600-5368
Type: Journal article
Rights: This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0 ), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Appears in Collections:University of St Andrews Research
Chemistry Research



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