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| Title: | Tris(ethylenediamine)zinc(II) hexafluoridosilicate |
| Authors: | Li, Yang
Shi, Qi
Slawin, Alexandra M. Z.
Woollins, J. Derek
Dong, Jinxiang |
| Keywords: | Crystal
QD Chemistry |
| Issue Date: | Dec-2009 |
| Citation: | Li , Y , Shi , Q , Slawin , A M Z , Woollins , J D & Dong , J 2009 , ' Tris(ethylenediamine)zinc(II) hexafluoridosilicate ' Acta Crystallographica. Section E, Structure reports online , vol 65 , no. 12 , pp. M1522-U277 . |
| Abstract: | The title compound, [Zn(C2H8N2)(3)](SiF6), was synthesized ionothermally using choline chloride-imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octahedral geometry. The Zn-II ion is coordinated by six N atoms from three ethylenediamine molecules. The crystal structure displays weak hydrogen bonding between [SiF6](2-) anions and the ethylenediamine NH hydrogen atoms. |
| Version: | Publisher PDF |
| Status: | Peer reviewed |
| URI: | http://hdl.handle.net/10023/1777 |
| DOI: | http://dx.doi.org/10.1107/S1600536809045693 |
| ISSN: | 1600-5368 |
| Type: | Journal article |
| Rights: | This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0 ), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
| Appears in Collections: | University of St Andrews Research
Chemistry Research
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