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| Title: | Di-mu-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)] |
| Authors: | Slawin, Alexandra M. Z.
Waddell, Paul G.
Woollins, J. Derek |
| Keywords: | QD Chemistry |
| Issue Date: | May-2010 |
| Citation: | Slawin , A M Z , Waddell , P G & Woollins , J D 2010 , ' Di-mu-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)] ' Acta Crystallographica. Section E, Structure reports online , vol 66 , no. 5 , pp. M499-U317 . |
| Abstract: | The title compound, [Pd2Cl4(C8H11O2P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd center dot center dot center dot Pd distance of 3.4662 (17) angstrom. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd-P bond length is ca 0.04 angstrom shorter than those in mononuclear PdCl2(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl- compared to a single-bonded Cl- atom. |
| Version: | Publisher PDF |
| Status: | Peer reviewed |
| URI: | http://hdl.handle.net/10023/1774 |
| DOI: | http://dx.doi.org/10.1107/S1600536810012055 |
| ISSN: | 1600-5368 |
| Type: | Journal article |
| Rights: | This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0 ), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
| Appears in Collections: | University of St Andrews Research
Chemistry Research
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