Research@StAndrews
 
The University of St Andrews

Research@StAndrews:FullText >
University of St Andrews Research >
University of St Andrews Research >
University of St Andrews Research >

Please use this identifier to cite or link to this item: http://hdl.handle.net/10023/1774
This item has been viewed 1 times in the last year. View Statistics

Files in This Item:

File Description SizeFormat
ActaCrystE66_5_m499.pdf323.82 kBAdobe PDFView/Open
Title: Di-mu-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)]
Authors: Slawin, Alexandra M. Z.
Waddell, Paul G.
Woollins, J. Derek
Keywords: QD Chemistry
Issue Date: May-2010
Citation: Slawin , A M Z , Waddell , P G & Woollins , J D 2010 , ' Di-mu-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)] ' Acta Crystallographica. Section E, Structure reports online , vol 66 , no. 5 , pp. M499-U317 .
Abstract: The title compound, [Pd2Cl4(C8H11O2P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd center dot center dot center dot Pd distance of 3.4662 (17) angstrom. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd-P bond length is ca 0.04 angstrom shorter than those in mononuclear PdCl2(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl- compared to a single-bonded Cl- atom.
Version: Publisher PDF
Status: Peer reviewed
URI: http://hdl.handle.net/10023/1774
DOI: http://dx.doi.org/10.1107/S1600536810012055
ISSN: 1600-5368
Type: Journal article
Rights: This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0 ), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Appears in Collections:University of St Andrews Research
Chemistry Research



This item is protected by original copyright

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

 

DSpace Software Copyright © 2002-2012  Duraspace - Feedback
For help contact: Digital-Repository@st-andrews.ac.uk | Copyright for this page belongs to St Andrews University Library | Terms and Conditions (Cookies)