Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation
Abstract
A convenient synthesis route to 2,2’-binaphtho[1,8-de][1,3,2]di-thiaphosphinine (3) was found. Its stable radical cation 3•+ was accessed easily through one-electron oxidation with NOBF4.
Citation
Kirst , C , Bode , B E , Cordes , D B , Nejman , P , Slawin , A M Z , Karaghiosoff , K & Woollins , J D 2016 , ' Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation ' , Dalton Transactions , vol. 45 , no. 15 , pp. 6348-6351 . https://doi.org/10.1039/C6DT00304D
Publication
Dalton Transactions
Status
Peer reviewed
ISSN
1477-9226Type
Journal article
Collections
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