DSpace Collection:

Low threshold organic semiconductor lasers and their application as explosive sensors

Wang, Yue — Fri, 30 Nov 2012 00:00:00 GMT

Abstract: This thesis presents studies of organic semiconductor lasers, including their operation when pumped by a light-emitting diode (LED), and their application as explosive sensors. The photophysics and amplified spontaneous emission (ASE) of star-shaped oligofluorene truxene molecules were investigated. These materials exhibit high gain and low optical loss in thin-film waveguides. Low ASE thresholds were achieved with the truxene T3 and T4. Second-order distributed feedback (DFB) lasers were fabricated, with pump threshold intensities below 0.5 kW/cm² and broad tunability of the emission. DFB lasers were demonstrated with a novel polymer BBEHP-PPV, pumped by a pulsed commercial InGaN LED. The laser emission occurred at 533 nm for peak drive current above 15 A. The output beams and pulse-dynamics of the lasers were investigated for the first time, along with a 'double-threshold' phenomenon that was observed in this long-pulse pumping regime. BBEHP-PPV lasers based on various types of diffractive resonators were also fabricated by UV nanoimprint-lithography (NIL). By optimising the resonator design and the fabrication, and the pump-beam geometry, polymer laser thresholds of ~60 W/cm², the lowest recorded for NIL lasers, were demonstrated, enabling them to be pumped by pulsed commercial LEDs and custom micro-LED arrays. One promising application of organic lasers is in explosive sensing. A polymer of intrinsic microporosity (PIM-1) was used to detect nitroaromatic vapours. Rapid detection of dinitrobenzene (DNB) of low vapour pressure was achieved by monitoring the photoluminescence and laser emission during exposure. In addition, a CMOS time-resolved fluorescence lifetime microsystem with a commercial green-emitting copolymer was used as a novel, portable sensor to detect DNB vapour. An InGaN LED pumped BBEHP-PPV laser was also used as a miniature sensor to detect 10 ppb of DNB. These highly sensitive hybrid sensors could be used in humanitarian demining, complementing existing technologies leading to improvement in the detection of hazardous objects.

Slotted photonic crystal biosensors

Scullion, Mark Gerard — Wed, 26 Jun 2013 00:00:00 GMT

Abstract: Optical biosensors are increasingly being considered for lab-on-a-chip applications due to their benefits such as small size, biocompatibility, passive behaviour and lack of the need for fluorescent labels. The light guiding mechanisms used by many of them result in poor overlap of the optical field with the target molecules, reducing the maximum sensitivity achievable. This thesis presents a new platform for optical biosensors, namely slotted photonic crystals, which engender higher sensitivities due to their ability to confine, spatially and temporally, the peak of optical mode within the analyte itself. Loss measurements showed values comparable to standard photonic crystals, confirming their ability to be used in real devices. A novel resonant coupler was designed, simulated, and experimentally tested, and was found to perform better than other solutions within the literature. Combining with cavities, microfluidics and biological functionalization allowed proof-of-principle demonstrations of protein binding to be carried out. High sensitivities were observed in smaller structures than most competing devices in the literature. Initial tests with cellular material for real applications was also performed, and shown to be of promise. In addition, groundwork to make an integrated device that includes the spectrometer function was also carried out showing that slotted photonic crystals themselves can be used for on-chip wavelength specific filtering and spectroscopy, whilst gas-free microvalves for automation were also developed. This body of work presents slotted photonic crystals as a realistic platform for complete on-chip biosensing; addressing key design, performance and application issues, whilst also opening up exciting new ideas for future study.

Microlensing for extrasolar planets : improving the photometry

Bajek, David J. — Sat, 01 Jun 2013 00:00:00 GMT

Abstract: Gravitational Microlensing, as a technique for detecting Extrasolar Planets, is recognised for its potential in discovering small-mass planets similar to Earth, at a distance of a few Astronomical Units from their host stars. However, analysing the data from microlensing events (which statistically rarely reveal planets) is complex and requires continued and intensive use of various networks of telescopes working together in order to observe the phenomenon. As such the techniques are constantly being developed and refined; this project outlines some steps of the careful analysis required to model an event and ensure the best quality data is used in the fitting. A quantitative investigation into increasing the quality of the original photometric data available from any microlensing event demonstrates that 'lucky imaging' can lead to a marked improvement in the signal to noise ratio of images over standard imaging techniques, which could result in more accurate models and thus the calculation of more accurate planetary parameters. In addition, a simulation illustrating the effects of atmospheric turbulence on exposures was created, and expanded upon to give an approximation of the lucky imaging technique. This further demonstrated the advantages of lucky images which are shown to potentially approach the quality of those expected from diffraction limited photometry. The simulation may be further developed for potential future use as a 'theoretical lucky imager' in our research group, capable of producing and analysing synthetic exposures through customisable conditions.

Optical eigenmodes for illumination & imaging

Kosmeier, Sebastian — Wed, 26 Jun 2013 00:00:00 GMT

Abstract: This thesis exploits so called “Optical Eigenmodes” (OEi) in the focal plane of an optical system. The concept of OEi is introduced and the OEi operator approach is outlined, for which quadratic measures of the light field are expressed as real eigenvalues of an Hermitian operator. As an example, the latter is employed to locally minimise the width of a focal spot. The limitations of implementing these spots with state of the art spatial beam shaping technique are explored and a selected spot with a by 40 % decreased core width is used to confocally scan an in focus pair of holes, delivering a two-point resolution enhanced by a factor of 1.3. As a second application, OEi are utilised for fullfield imaging. Therefore they are projected onto an object and for each mode a complex coupling coefficient describing the light-sample interaction is determined. The superposition of the OEi weighted with these coefficients delivers an image of the object. Compared to a point-by-point scan of the sample with the same number of probes, i.e. scanning points, the OEi image features higher spatial resolution and localisation of object features, rendering OEi imaging a compressive imaging modality. With respect to a raster scan a compression by a factor four is achieved. Compared to ghost imaging as another fullfield imaging method, 2-3 orders of magnitude less probes are required to obtain similar images. The application of OEi for imaging in transmission as well as for fluorescence and (surface enhanced) Raman spectroscopy is demonstrated. Finally, the applicability of the OEi concept for the coherent control of nanostructures is shown. For this, OEi are generated with respect to elements on a nanostructure, such as nanoantennas or nanopads. The OEi can be superimposed in order to generate an illumination of choice, for example to address one or multiple nanoelements with a defined intensity. It is shown that, compared to addressing such elements just with a focussed beam, the OEi concept reduces illumination crosstalk in addressing individual nanoelements by up to 70 %. Furthermore, a fullfield aberration correction is inherent to experimentally determined OEi, hence enabling addressing of nanoelements through turbid media.

Active slow light in silicon photonic crystals : tunable delay and Raman gain

Rey, Isabella H. — Fri, 30 Nov 2012 00:00:00 GMT

Abstract: In the past decade, great research effort was inspired by the need to realise active optical functionalities in silicon, in order to develop the full potential of silicon as a photonic platform. In this thesis we explore the possibility of achieving tunable delay and optical gain in silicon, taking advantage of the unique dispersion capabilities of photonic crystals. To achieve tunable optical delay, we adopt a wavelength conversion and group velocity dispersion approach in a miniaturised engineered slow light photonic crystal waveguide. Our scheme is equivalent to a two-step indirect photonic transition, involving an alteration of both the frequency and momentum of an optical pulse, where the former is modiﬁed by the adiabatic tuning possibilities enabled by slow light. We apply this concept in a demonstration of continuous tunability of the delay of pulses, and exploit the ultrafast nature of the tuning process to demonstrate manipulation of a single pulse in a train of two pulses. In order to address the propagation loss intrinsic to slow light structures, with a prospect for improving the performance of the tunable delay device, we also investigate the nonlinear effect of stimulated Raman scattering as a means of introducing optical gain in silicon. We study the influence of slowdown factors and pump-induced losses on the evolution of a signal beam along the waveguide, as well as the role of linear propagation loss and mode profile changes typical of realistic photonic crystal structures. We then describe the work conducted for the experimental demonstration of such effect and its enhancement due to slow light. Finally, as the Raman nonlinearity may become useful also in photonic crystal nanocavities, which confine light in very small volumes, we discuss the design and realisation of structures which satisfy the basic requirements on the resonant modes needed for improving Raman scattering.

Effects of spin-orbit coupling and many-body interactions on the electronic structure of Sr₂RuO₄

Rozbicki, Emil Jerzy — Wed, 30 Nov 2011 00:00:00 GMT

Abstract: The aim of the project is to investigate the effects of spin-orbit coupling and many-body interactions on the band structure of the single-layered strontium ruthenate Sr₂RuO₄. This material belongs to the large family of strongly correlated electron systems in which electron-electron interaction plays a crucial role in determining the macroscopic properties. The experimental method used for this purpose is Angular Resolved Photoemission Spectroscopy (ARPES), which probes the single-particle spectral function and allows direct measurements of the quasi-particle band structure. The analysis is based on comparison of experimental data with electronic structure calculations. Typical methods for the band structure calculations including density functional theory (DFT) in the local density approximation (LDA) and tight-binding calculations (TB) are one-electron approximations and do not give insight into many-body interactions. However, comparing the measured band structures with calculated ones allows estimating the strength of the interactions in the considered system. In Chapter 1 the earlier work on Sr₂RuO₄, which is relevant to this project is presented. This chapter is an introduction to the data analysis and discussion of the results. In Chapter 2 we describe the experimental setup, theoretical principles of the measurement and summarize important improvements made during this project. In Chapter 3 we give a brief introduction into density functional theory and describe methods used within DFT to calculate the band structure. We further give a brief description of a tight binding model for Sr₂RuO₄. The bulk of this chapter is devoted to present the e ects of spin-orbit coupling on the band structure of Sr₂RuO₄. In particular, we use a tight binding model to simulate the anisotropy of the Zeeman splitting found experimentally. In Chapter 4 we present the ARPES results, their analysis and discussion. A particular focus is placed on the discussion of the surface layer Fermi surface topology and on the discovery of strong momentum dependance of the mass renormalization factors of the bulk β and γ bands.

Towards universal quantum computation in continuous-variable systems

Milne, Darran F. — Fri, 30 Nov 2012 00:00:00 GMT

Abstract: In this thesis we explore the possibility of creating continuousvariable quantum systems that are capable of supporting universal quantum computation. We begin by examining the measurement-based model, which employs sequences of measurements on highly entangled resource states, known as a cluster states. We suggest a method for the construction of Gaussian cluster states based on ensembles of atoms and quantum non-demolition interactions. We then go on to expand our model to allow for the inclusion of light modes as part of the cluster. This yields a new class of states, the composite cluster states. This leads us to propose a new architecture for the measurement-based model that uses these composite clusters to increase resource e ciency and reduce computational errors. The second part of this thesis concerns topological quantum computation. In states exhibiting topological degrees of freedom, quantum information can be stored as a non-local property of the physical system and manipulated by braiding quasiparticles known as anyons. Here we show how these ideas can be extended to continuous variables. We establish a continuous variable analogue of the Kitaev toric code, show that excitations correspond to continuous versions of Abelian anyons and investigate their behaviour under the condition of nite squeezing of the resource state. Finally, we expand our continuous variable topological model to include non-abelian excitations by constructing superpositions of CV toric code anyons. We derive the fusion and braiding behaviour of these non-abelian excitations and nd that they correspond to a CV analog of Ising anyons. Using these resources, we go on to suggest a computational scheme that encodes qubits within the fusion spaces of the CV Ising anyons and derive one- and two-qubit quantum gates operations that are implemented in a topological manner.

A compact system for ultracold atoms

Torralbo Campo, Lara — Fri, 30 Nov 2012 00:00:00 GMT

Abstract: This thesis describes the design, construction and optimisation of two compact setups to produce ⁸⁷Rb Bose-Einstein condensates and dual ⁷Li-⁸⁷Rb Magneto- Optical Traps (MOTs). The motivation for compact systems is to have simplified systems to cool the atoms. The first experimental setup is based on a single pyrex glass cell without the need for atom chips. Fast evaporation will be achieved in a hybrid trap comprising of a magnetic quadrupole trap and an optical dipole trap created by a Nd:YVO4 laser and with future plans of using a Spatial Light Modulator (SLM). To enhance an efficient and rapid evaporation, we have investigated Light-Induced Atomic Desorption (LIAD) to modulate the Rb partial pressure during the cooling and trapping stage. With this technique, a ⁸⁷Rb MOT of 7 x 10⁷ atoms was loaded by shining violet light from a LED source into the glass cell, whose walls are coated with rubidium atoms. The atoms were then cooled by optical molasses and then loaded into a magnetic trap where lifetime measurements demonstrated that LIAD improves on magnetically-trapped atoms loaded from constant background pressure by a factor of six. This is quite encouraging and opens the possibility to do a rapid evaporation. In a second experiment, we have designed a compact system based on a stainless steel chamber to trap either ⁷Li or ⁶Li atoms in a MOT loaded from alkali-metal dispensers without the need of conventional oven-Zeeman slower. This setup can also load ⁸⁷Rb atoms, allowing future projects to simultaneously produce degenerate quantum gases of bosonic ⁸⁷Rb and fermionic ⁶Li atoms.

Nanoscale investigation of superconductivity and magnetism using neutrons and muons

Ray, Soumya Jyoti — Fri, 01 Jun 2012 00:00:00 GMT

Abstract: The work presented in this thesis was broadly focussed on the investigation of the magnetic behaviour of different superconducting materials in the form of bulk (singe crystals and pellets) and thin ﬁlms (nanomagnetic devices like superconducting spin valves etc). Neutrons and muons were extensively used to probe the structural and magnetic behaviour of these systems at the nanoscale along with bulk characterisation techniques like high-sensitive magnetic property measurements, scanning probe microscopy and magneto-transport measurements etc. The nanoscale interplay of Superconductivity and Ferromagnetism was studied in the thin ﬁlm structures using a combination of Polarised Neutron Reﬂectivity (PNR) and Low Energy Muon Spin Rotation (LE-µSR) techniques while bulk Muon Spin Rotation (µSR) technique was used for microscopic magnetic investigation in the bulk materials. In the Fe/Pb heterostructure, evidence of the Proximity Effect was observed in the form of an enhancement of the superconducting penetration depth (λs) with an increase in the ferromagnetic layer thickness (dF) in both the bilayered and the trilayered structures. The existence of an Inverted Magnetic Region was also detected at the Ferromagnet-Superconductor (F/S) interface in the normal state possibly originating from the induced spin polarisation within the Pb layer in the presence of the neighbouring Fe layer(s). The spatial size (height and width) of the Inverted Magnetic Region did not change much while cooling the sample below the superconducting transition temperature(Tc)and it also stayed unaffected by an increase in the Fe layer thickness and by a change of the applied magnetic ﬁeld. In the superconducting spin valve structure containing Permalloy (Py) as ferromagnetic layer and Nb as the superconducting layer, LE-µSR measurements revealed the evidence of the decay of magnetic ﬂux density (as a function of thickness) within the Nb layer symmetrically from the Py/Nb interfaces towards the centre of the Nb layer in the normal state. The thickness dependent magnetisation decay occurred over two characteristic length scales in the normal state that stayed of similar values in the superconducting state also. In the superconducting state, an additional contribution towards the magnetisation was found in the vicinity of the Py/Nb interfaces possibly originating from the spin polarisation of the singlet Cooper pairs in these areas. The nanoscale magnetic investigation on a highly engineered F/S/F structure (where each of the F blocks made of multiple Co/Pd layers with magnetic moments aligned perpendicular to the plane of these layers and neighbouring magnetic blocks separated by Ru layers giving rise to antiferromagnetic alignment) using LE-µSR showed an antisymmetric thickness dependent magnetic ﬂux density proﬁle with two characteristic length scales. In the superconducting state, the magnetic ﬂux density proﬁle got modiﬁed within the superconducting Nb₆₇Ti₃₃ layer near the F/S interfaces in a way similar to that of observed in the case of Py/Nb system, most likely because of the spin polarisation of the superconducting electron pairs. The vortex magnetic phase diagram of Bi₂Sr₂Ca₂Cu₃O10-δ was studied using the Muon Spin Rotation (µSR) technique to explore the effects of vortex lattice melting and rearrangements for vortex transitions and crossover as a function of magnetic ﬁeld and temperatures. At low magnetic ﬁelds, the ﬂux vortices undergo a ﬁrst order melting transition from a vortex lattice to a vortex liquid state with increasing temperature while another transition also occurred with increasing ﬁeld at ﬁxed temperature to a vortex glass phase at the lowest temperatures. Evidence of a frozen liquid phase was found in the intermediate ﬁeld region at low temperature in the form of a lagoon in the superconducting vortex state which is in agreement with earlier observations made in BiSCCO-2212. The magnetic behaviour of the unconventional superconductor Sr₂RuO₄ was investigated using µSR to ﬁnd the evidence of normal state magnetism and the nature of the vortex state. In the normal state, a weak hysteretic magnetic signal was detected over a wide temperature and ﬁeld range believed to be supporting the evidence of a chiral order parameter. The nature of the vortex lattice structure was obtained in different parts of the magnetic phase diagram and the evidence of magnetic ﬁeld driven transition in the lattice structure was detected from a Triangular→Square structure while the vortex lattice stayed Triangular over the entire temperature region below Tc at low ﬁelds with a disappearance of pinning at higher temperatures.

The role of the plasmon resonance for enhanced optical forces

Ploschner, Martin — Fri, 30 Nov 2012 00:00:00 GMT

Abstract: Optical manipulation of nanoscale objects is studied with particular emphasis on the role of plasmon resonance for enhancement of optical forces. The thesis provides an introduction to plasmon resonance and its role in confinement of light to a sub-diffraction volume. The strong light confinement and related enhancement of optical forces is then theoretically studied for a special case of nanoantenna supporting plasmon resonances. The calculation of optical forces, based on the Maxwell stress tensor approach, reveals relatively weak optical forces for incident powers that are used in typical realisations of trapping with nanoantenna. The optical forces are so weak that other non-optical effects should be considered to explain the observed trapping. These effects include heating induced convection, thermoporesis and chemical binding. The thesis also studies the optical effects of plasmon resonances for a fundamentally different application - size-based optical sorting of gold nanoparticles. Here, the plasmon resonances are not utilised for sub-diffraction light confinement but rather for their ability to increase the apparent cross-section of the particles for their respective resonant sizes. Exploiting these resonances, we realise sorting in a system of two counter-propagating evanescent waves, each at different wavelength that selectively guide gold nanoparticles of different sizes in opposite directions. The method is experimentally demonstrated for bidirectional sorting of gold nanoparticles of either 150 or 130 nm in diameter from those of 100 nm in diameter within a mixture. We conclude the thesis with a numerical study of the optimal beam-shape for optical sorting applications. The developed theoretical framework, based on the force optical eigenmode method, is able to find an illumination of the back-focal plane of the objective such that the force difference between nanoparticles of various sizes in the sample plane is maximised.

Fluctuation-driven phase reconstruction at itinerant ferromagnetic quantum critical points

Karahasanovic, Una — Fri, 30 Nov 2012 00:00:00 GMT

Abstract: The formation of new phases close to itinerant electron quantum critical points has been observed experimentally in many compounds. We present a unified analytical model that explains the emergence of new types of phases around itinerant ferromagnetic quantum critical points. The central idea of our analysis is that certain deformations of the Fermi surface enhance the phase-space available for low-energy quantum fluctuations and so self-consistently lower the free energy. Using this quantum order-by-disorder mechanism, we find instabilities towards the formation of a spiral ferromagnet and spin-nematic phase close to an itinerant ferromagnetic quantum critical point. Further, we employ the quantum order-by-disorder mechanism to describe the partially ordered phase of MnSi. Using the simplest model of a Stoner-like helimagnetic transition, we show that quantum fluctuations naturally lead to the formation of an unusual phase near to the putative quantum critical point that shares many of the observed features of the partially ordered phase in MnSi. In particular, we predict an angular dependence of neutron scattering that is in good agreement with neutron-scattering data.

Neutrons to probe nanoscale magnetism in perpendicular magnetic recording media

Venkataramana, Vikash — Wed, 20 Jun 2012 00:00:00 GMT

Abstract: Magnetic recording media refers to the disc shaped thin film magnetic medium present inside the hard disk drive of a computer. Magnetic recording is an important function of the hard disk drive by which information such as text, pictures, audio and videos are stored. Information is broken down to a simple binary format and is stored as magnetised bits along the tracks of the disk forming the hard drive. Over the years advancements in research on the type of magnetic materials used has allowed increased data storage capacities by reducing magnetic bit sizes. It is with this advancement in magnetic data storage, that we have today’s hard disk drive technology, which uses a perpendicular magnetic medium to store data. A perpendicular magnetic medium is a multi-layered magnetic thin film structure with the topmost layer comprising nanoscale magnetic grains of high perpendicular anisotropy. The topmost recording layer (RL) is mapped into individual bits of 80-100 nm² area that consist of 5-10 nm diameter CoCrPt grains, embedded in an oxide matrix. A bit area is defined to ensure a significant number of stable grains allowing data to be stored in each bit as a ‘0’ or a ‘1’ depending on its switched magnetic state. The magnetic grains if sputtered below a threshold grain size tend to suffer from thermal fluctuation and instability due to super-paramagnetic effects, hence bringing limitations to grain size. As a result of this, research in recent years has been directed at introducing a softer magnetic exchange coupled composite (ECC) layer above the recording layer. This layer facilitates the delicate balance of switching smaller grains with strong magneto-crystalline anisotropy at lower magnetic fields, by exchange coupling with the CoCrPt grains in the recording layer. However this technique of increasing the efficiency in the perpendicular magnetic medium by introducing ‘facilitating’ layers is an area that is still being widely researched and understood. Although numerous surface and bulk analysis techniques exist to study magnetic and surface properties of these materials, there is limited information on the structural and magnetic properties of these materials at the nanoscale level. The reported work investigates the structural and magnetic properties of the magnetic grains and multi-layers in the perpendicular magnetic medium using polarised neutron scattering and reflectivity techniques. The work investigates the structural and magnetic properties of the CoCrPt grains, apart from understanding the CoCrPt magnetic grain switching. The work also investigates the magnetisation in the layers of the thin film perpendicular media structure using polarised neutron reflectivity (PNR). Using polarised small angle neutron scattering (PolSANS), it has been shown that ferromagnetic ordered core region of the CoCrPt grain in the recording layer is smaller than the physical CoCrPt granular structure. The magnetic switching behaviour of the CoCrPt grain at different magnetic fields is also analysed and the experimental PolSANS data is fitted with non-interacting size-dependent analytical grain switching models. This result provides significant evidence that the magnetic anisotropy increases with grain size, with larger magnetic grains having larger magnetic anisotropy. Polarised neutron scattering experiments are carried out with the magnetically softer exchange coupled composite (ECC) layer included in the thin film magnetic structure. The first experiments investigate if the ECC layer contributes to the nuclear and magnetic interference scattering term in the experimenting scattering data. The experiments clearly show that there is no contribution from the ECC layer in the nuclear and magnetic scattering interference term. The role of the ECC layer in the magnetic switching process is then investigated at different magnetic fields. The ECC layer was found to influence the size-dependent magnetic grain switching of the CoCrPt grains in the recording layer and a detailed investigation is presented in the reported work. Polarised neutron reflectivity (PNR) experiments have also been carried out with the ECC layer on the perpendicular magnetic media samples. These experiments investigate the composition and thickness of the thin film structure, while also providing information on the magnetic state of the thin films under the influence of an in-plane magnetic field.The in-plane magnetisation in the recording and ECC layer is determined at different in-plane magnetic fields. The magnetisation values determined for the ECC layer and the recording layer (RL) at different in-plane magnetic fields help better understand the differences in their magnetic properties.

Tailoring optical fibers for cell transfection

Ma, Nan — Fri, 30 Nov 2012 00:00:00 GMT

Abstract: Optical transfection is a promising technique for the delivery of foreign genetic material into cells by transiently changing the permeability of the cell membrane. Of the different optical light sources that have been used, femtosecond laser based transfection has been one of the most effective methods for optical transfection which is generally implemented using a free-space bulk optical setup. Here in this thesis, a few novel fabrication methods are devised to obtain easy and inexpensive fabrication of microlensed optical fibers, which can be used to replace traditional optical setup and perform femtosecond optical transfection. These fabrication methods offer the flexibility to fabricate a microlens which can focus femtosecond laser pulses at 800 nm to a small focal spot whilst keeping a relatively large working distance. In conventional optical transfection methods the foreign genetic material to be transfected is homogenously mixed in the medium. This thesis reports the first realization of an integrated optical transfection system which can achieve transfection along with localized drug delivery by combining lensed fiber based optical transfection system with a micro-capillary based microfluidic system. Finally, based on an imaging fiber (coherent optical fiber bundle), the first endoscope-like integrated system for optical transfection with subcellular resolution epifluorescence imaging was built. The transfection efficiency of these fiber based systems is comparable to that of a standard free-space transfection system. Also the use of integrated system for localized gene delivery resulted in a reduction of the required amount of genetic material for transfection. The miniaturized, integrated design opens a range of exciting experimental possibilities, such as the dosing of tissue slices to study neuron activities, targeted drug delivery, and in particular for using endoscope-like integrated systems for targeted in vivo optical microsurgery.

Optoelectronic modulation of mm-wave beams using a photo-injected semiconductor substrate

Gallacher, Tom F. — Wed, 20 Jun 2012 00:00:00 GMT

Abstract: This thesis discusses optoelectronic devices at mm-wave frequencies, focusing on optoelectronic beamforming and non-mechanical beam steering based on an optically excited Fresnel zone plate plasma. The optically controlled zone plate, termed the photo-injected Fresnel zone plate antenna (piFZPA) within this work, is introduced and a comprehensive theoretical framework developed. The design and optimisation of Fresnel zone plates are detailed, which determine the inherent performance of the piFZPA. A range of zone plates were designed, fabricated, and characterised at 94 GHz with up to 46 dBi gain, -26 dB sidelobe levels, and 67% aperture efficiency being measured for a quarter-wave design. The control of (sub) mm-wave beams by optical modulation of the complex permittivity of a semiconductor substrate is discussed. The significance of the free-carrier plasma dynamics, the effective lifetime, surface recombination, and the limits of the substrate which are imposed by the spatial resolution of the free-carrier plasma are highlighted, with the optimisation of these parameters discussed. The passivation quality of high-resistivity silicon wafers were characterised using a mm-wave photoconductance decay method, which yielded lifetime improvements from τ[subscript(eff)] = 60 us up to τ[subscript(eff)] ≈ 4,000 us, resulting in lowered recombination velocities (S = 15 cm/s). W-band characterisations of the passivated wafers illustrate the significance of surface recombination, with measured attenuations of up to 24 dB. Novel theoretical models are developed throughout this thesis, which yield insight into the requirements of optoelectronic devices, and are shown to agree well with measured data. The theoretical framework developed details the requirements, limitations, suitability, and design of piFZPAs at any frequency. A range of transmission-type piFZPAs are demonstrated and characterised at 94 GHz, both on-axis and off-axis, based on a novel architecture, with up to 8% aperture efficiency. Finally, the hybridisation of the piFZPA technique and well established visible display technologies, which has been developed throughout this thesis, enable low-cost, simple, and highly flexible optoelectronic devices, highlighting this method as an attractive solution to adaptive beamforming and non-mechanical steering at mm-wave and submm-wave frequencies.

Low temperature magnetisation properties of the spin ice material Dy₂Ti₂O₇

Slobinsky, Demian G. — Fri, 01 Jun 2012 00:00:00 GMT

Abstract: A way to obtain materials that show novel phenomena is to explore the interplay between geometry and interactions. When it is not geometrically possible to satisfy all the interactions by a given configuration, then to find the ground state becomes very complicated. This interplay between geometry and interactions defines geometrical frustration. One of the most popular examples of geometrical frustration in magnetism is spin ice. In this system, nearest neighbour ferromagnetic interactions between Ising spins in a pyrochlore structure emulate water ice by showing the same degree of frustration. This is manifested by the same ground state residual entropy. Although the clearest example of spin ice among magnets is shown by Dy₂Ti₂O₇, the behaviour of this material is richer than that of pure spin ice. The large magnetic moments of the rare earth Dy form a spin ice that also interacts via dipolar interactions. These long range interactions give rise to monopolar excitations which dramatically affect the dynamics of the system with respect to the pure spin ice case. In this thesis magnetisation experiments and numerical methods are used to explore the properties of the magnetic insulator Dy₂Ti₂O₇. We study its excitations at low temperature and describe the out-of-equilibrium characteristics of the magnetisation processes, below a temperature where the system freezes out. For temperatures above the freezing temperature, we describe and measure a 3D Kasteleyn transition and the concomitant Dirac strings associated to it, for the field in the [100] crystallographic direction. For temperatures below the freezing temperature, we find new out-of-equilibrium phenomena. Magnetic jumps are measured and their sweep rate dependence analysed. A deflagration theory is proposed and supported by simultaneous magnetisation and sample temperature measurements obtained by a new design of a Faraday magnetometer.

Quantum correlations in and beyond quantum entanglement in bipartite continuous variable systems

Tatham, Richard — Fri, 30 Nov 2012 00:00:00 GMT

Abstract: This thesis explores the role of non-classical correlations in bipartite continuous variable quantum systems, and the approach taken is three-fold. We show that given two initially entangled atomic ensembles, it is possible to probabilistically increase the entanglement between them using a beamsplitter-like interaction formed from two quantum non-demolition (QND) interactions with auxiliary polarised light modes. We then develop an elegant method to calculate density matrix elements of non-Gaussian bipartite quantum states and use this to show that the entanglement in a two mode squeezed vacuum can be distilled using QND interactions and non-Gaussian elements. Secondly, we introduce a potential new measure of quantum entanglement in bipartite Gaussian states. This measure has an operational meaning in quantum cryptography and provides an upper bound on the amount of a secret key that can be distilled from a Gaussian probability distribution shared by two conspirators, Alice and Bob, given the presence of an eavesdropper, Eve. Finally, we go beyond the realm of quantum entanglement to explore other non-classical correlations in continuous variable systems. We provide solutions for a number of these measures on two mode Gaussian states and introduce the Gaussian Ameliorated Measurement Induced Disturbance (GAMID). The interplay between these different measures and quantum entanglement is examined. We then attempt to take small steps into the non-Gaussian regime by computing these non-classicality measures on the three-parameter continuous variable Werner states.

The application of spontaneous parametric downconversion to develop tools for validating photonic quantum information technologies

Thomas, Peter James — Tue, 30 Nov 2010 00:00:00 GMT

Abstract: This portfolio of work contributes to the remit of the National Physical Laboratory (NPL) to develop the underpinning expertise and tools for validating nascent and future optical quantum technologies based on the discrete and quantum properties of photons. This requirement overlaps with the requirement to provide validation for devices operating in the photon-counting regime. A common theme running through the portfolio is photon pairs generated through spontaneous parametric downconversion (SPDC). A Hong-Ou-Mandel (HOM) interferometer sourced with visible wavelength photon pairs from an SPDC process in beta-barium borate (BBO) was designed, built and characterised. The visibility of the HOM interference is dependent on the indistinguishability of the interfering photons, but is also influenced by imperfections of the interferometer; therefore an investigation was carried out to quantify the effects of the interferometer imperfections on the measured visibility so that the true photon indistinguishability could be measured with a quantified uncertainty. A bright source of correlated pair photons in the telecoms band based upon a pump enhanced SPDC process in periodically-poled potassium titanyl phosphate (PPKTP) was designed, built and characterised. From the characterisation measurements the source brightness was estimated to be 6.2×10⁴ pairs/ s/ mw pump. The photon pairs were further characterised through their incorporation as a source in a HOM interference experiment. The developed correlated photon pair source was at the heart of a novel scheme for the generation of polarisation entangled photon pairs, for which the design, build and characterisation work is presented. The source was demonstrated to produce two of the four maximally entangled Bell states with quantum interference visibilities of around 0.95. The generated states were also shown to break a form of Bell’s inequality by around six standard deviations. The polarisation entangled photon pair source was originally built at the University of St Andrews and was later transferred to the NPL where it will extend NPL’s capabilities to this key spectral region. Finally a study was carried out to investigate the possibility of a wavelength tuneable device for the absolute measurement of single photon detector quantum efficiencies based upon an established SPDC technique.

Study of phase-matching geometries in bulk and periodically-poled lithium niobate and their use in intracavity terahertz optical parametric oscillators

Thomson, Caroline L. — Wed, 20 Jun 2012 00:00:00 GMT

Abstract: This thesis describes the experimental implementation of novel intersecting cavity terahertz optical parametric oscillators based on bulk and periodically-poled magnesium oxide-doped lithium niobate. Both collinear and non-collinear phase-matching geometries have been demonstrated and injection-seeding has been implemented in devices using periodically-poled material to reduce threshold and increase the down-conversion efficiency. A comprehensive characterisation of the original intracavity terahertz OPO was undertaken, which revealed the parameters having the greatest impact on OPO efficiency (idler mirror reflectivity and cavity length) and led to a better understanding of the losses in the system. During the characterisation process, generation of further terahertz radiation at the same frequency as that generated by the parametric process was observed and identified as being a result of difference frequency generation (DFG) between the parametrically-generated idler and terahertz waves. This phenomenon had previously only been observed when periodically-poled materials were employed in the system. The effect of this additional DFG process has been analysed in terms of the enhancement of the terahertz field on the basis of the coupled wave equations and physically measured quantities. The use of periodically-poled lithium niobate has been a major part of the research presented in this thesis. A comprehensive study of the modified phase-matching conditions was carried out and both collinear and novel hybrid non-collinear phase-matching geometries were identified. Several computer models were developed to assess the performance of any given grating design in these different geometries and the effects of temperature tuning and pump wavelength variation were also investigated using the models. Experimental studies confirmed the viability of the modelling approach but material limitations (particularly the early onset of crystal damage) limited the outcomes of the experiments. A detailed comparison of the poled and bulk materials was made to highlight the present drawbacks of the poled material. Finally, injection seeding was used to improve the efficiency of the collinear phase-matched PPLN OPOs. When seeding was used the depletion of the pump pulse was increased to the point of being measurable, reaching an upper level of 10%. Coupling constraints placed on the seed laser limited the amount of depletion attained. The potential for injection seeding to be used in the hybrid non-collinear phase-matching scheme was also identified but not realised during the course of this work. Were this technique successful, the tuning range of the intersecting cavity terahertz OPO could be extended to encompass the sub-1THz region, something that has previously been limited by the available idler cavity angles.

Propagation loss in slow light photonic crystal waveguides

Schulz, Sebastian Andreas — Wed, 20 Jun 2012 00:00:00 GMT

Abstract: The ﬁeld of nanophotonics is a major research topic, as it offers potential solutions to important challenges, such as the creation of low power, high bandwidth interconnects or optical sensors. Within this ﬁeld, resonant structures and slow light waveguides are used to improve device performance further. Photonic crystals are of particular interest, as they allow the fabrication of a wide variety of structures, including high Q-factor cavities and slow light waveguides. The high scattering loss of photonic crystal waveguides, caused by fabrication disorder, however, has so far proven to be the limiting factor for device applications. In this thesis, I present a detailed study of propagation loss in slow light photonic crystal waveguides. I examine the dependence of propagation loss on the group index, and on disorder, in more depth than previous work by other authors. I present a detailed study of the relative importance of different components of the propagation loss, as well as a calculation method for the average device properties. A new calculation method is introduced to study different device designs and to show that photonic crystal waveguide propagation loss can be reduced by device design alone. These “loss engineered” waveguides have been used to demonstrate the lowest loss photonic crystal based delay line (35 dB/ns) with further improvements being predicted (< 20 dB/ns). Novel fabrication techniques were investigated, with the aim of reducing fabrication disorder. Initial results showed the feasibility of a silicon anneal in a nitrogen atmosphere, however poor process control led to repeatability issues. The use of a slow-fast-slow light interface allowed for the fabrication of waveguides spanning multiple writeﬁelds of the electron-beam lithography tool, overcoming the problem of stitching errors. The slow-fast-slow light interfaces were combined with loss engineering waveguide designs, to achieve an order of magnitude reduction in the propagation loss compared to a W1 waveguide, with values as low as 130 dB/cm being achieved for a group index around 60.

Millimetre wave quasi-optical signal processing systems

Webb, M. R. — Fri, 01 Jan 1993 00:00:00 GMT

Abstract: The development of spatial signal processing techniques at millimetre wavelengths represents an area of science and technology that is new. At optical wavelengths, spatial signal processing techniques are well developed and are being applied to a variety of situations. In particular they are being used in pattern recognition systems with a great deal of success. At millimetre wavelengths, the kind of technology used for signal transport and processing is typically either waveguide based or quasi-optically based, or some hybrid of the two. It is the use of quasi-optical methods that opens up the possibility of applying some of the spatial signal processing techiques that up to the present time have almost exclusively been used at optical wavelengths. A generic device that opens up this dimension of spatial signal processing to millimetre wave quasi-optical systems is at the heart of the work described within this thesis. The device could be suitably called a millimetre wave quasi-optical spatial light modulator (8LM), and is identical in operation to the spatial light modulators used in many optical signal processing systems. Within this thesis both a theoretical and an experimental analysis of a specific millimetre wave quasi-optical spatial light modulator is undertaken. This thesis thus represents an attempt to open up this new area of research and development, and to establish for it, a helpful theoretical and experimental foundation. It is an area that involves a heterogeneous mix of various technologies, and it is an area that is full of potential. The development of the experimental method for measuring the beam patterns produced by millimetre wave quasi-optical spatial light modulators involved the separate development of two other components. Firstly, a sensitive, low-cost millimetre wave pyroelectric detector has been developed and characterised. And secondly, a high performance quasi-optical Faraday rotator (a polarisation rotator) has been developed and characterised. The polarisation state of a quasi-optical beam is the parameter most often exploited for signal processing applications in millimetre wave quasi-optical systems, and thus a high performance polarisation rotator has readily found many opportunities for use.

The application of quasi-optical techniques to millimetre wave radar

Leeson, Michael. J. — Fri, 01 Jan 1993 00:00:00 GMT

Abstract: The application of Quasi Optical techniques has been of great benefit to the field of instrumentation for frequencies between 750Hz and several hundred OHz. The application of Quasi Optical techniques to millimetre wave radar, described in this thesis, has produced an FMCW Doppler radar capable of operation at 940Hz and 1400Hz. Total polarization agility and a capability to operate over a very wide bandwidth is demonstrated. Quasi Optical circuits are proposed as solutions for many of the system requirements, and these are fully analyzed. Significant benefits of these techniques are demonstrated, and future improvements are suggested. A new design tool, in the form of a program, for Quasi Optical circuit analysis is presented and is used for the analysis of all the optical circuits in this thesis. The program has speeded up the design process for optical circuits. A new type of feedhorn is described and characterized. Its performance compares well with existing feedhorns, and it provides a low cost alternative to existing antenna requirements.

An acoustical investigation of the concert harp

Bell, Alexander J. — Fri, 01 Jan 1988 00:00:00 GMT

Abstract: This thesis is a report of acoustical research on the concert harp. The harp has an established place in the symphony orchestra and is reacquiring its role as a solo chamber instrument that it had before the development of the modern piano. As far as can be determined, this is the first doctoral thesis on the concert harp and serves as an introduction to the science of the instrument, The experimental methods employed- holographic interferonietry, input admittance measurements, Chiadni glitter pattern methods, sound pressure level measurements- have all been successfully used with work on other musical instruments. Theoretical calculations are used to underpin the experimental results for several of the subjects reported. The experimental results are also compared with the results of similar tests on different musical instruments. Analyses of the violin, guitar and piano are particularly used in discussions. This work is specifically on the "Orchestra" concert harp, manufactured and sold by the Salvi Harp organisation, though reference Is made in Chapter 3 to the "Electra" concert harp, which is also a Salvi harp. The "Orchestra" harp has a similar design to many other concert harps built by different luthiers around the world. This thesis is structured as follows. The first chapter is a review of historical and contemporary research an stringed musical instruments. The next chapter is a detailed description of the Salvi "Orchestra" harps the dimensions of all the inportant features are given, the tensions and materials of the strings are reported and there is also a short description on the playing of the instrument. The next five chapters form the kernal of the research report and deal with the vibrations of the constituent part of the "Orchestra" and finally the completed, strung harp itself. In Chapter 3, the vibrations of the free soundboard are reported in some detail. Analysis is made at a number of stages of the construction of the soundboard itself. The position of the neutral axis on the soundboard is also given. There is also reference to the soundboard of the Salvi "Electra" harp. Chapter 4 deals with the air resonances in the enclosed air volume of the "Orchestra" soundbox. Both a Helmholtzian air mode and higher order air modes are discussed. Theoretical models are used for both forms of air modes, Chapter 5 is a report of the vibrational modes of the "Orchestra" soundbox using both Chladni glitter patterns and holographic interferonietry. The results of Chapter 5 are confirmed and expanded by the work in Chapter 6, where input admittance measurements are made on the soundbox.Chapter 7 investigates the vibrational modes of the soundbox, both in the isolated state and as part of a completed, strung harp. This is followed by a chapter on the directivity of the "Orchestra" harp in which the principal areas of radiation from the harp are reported. The next chapter deals with attempts to relate objective measurements with subjective opinions of six concert harps. The last chapter summarises the principal results of the various analyses reported in this thesis. Suggestions for further research on the harp are made. There are also suggestions for the improvement of the Salvi "Orchestra" harp. There are three appendices at the end of this work. The first deals with the testing of spruce samples intended for the soundboards of the harps. The effect of the veneer is also discussed. The second appendix deals with the production and physical properties of gut harp strings. The third appendix describes the changes to the resonant modes of an isolated soundbox produced by changing the shape of the straining and cover bars of the soundboard.

Magnetohydrodynamic waves in structured atmospheres

Edwin, Patricia Mary — Tue, 01 Jan 1985 00:00:00 GMT

Abstract: The effect of structuring, in the form of magnetic or density inhomogeneities, on the magnetohydrodynamic (mhd) waves of an infinite plasma is investigated. The appropriate dispersion formulae, in both Cartesian and cylindrical polar coordinate geometries, are derived. The main properties of the allowable modes in structured plasmas are described, particularly those featuring in a slender inhomogeneity. The inclusion of non-adiabatic effects is examined, specifically for a thermally dissipative, unstratified, finite structure and for a slender inhomogeneity in a stratified medium. The dissipative time scales of slender structures are shown to have a dependence on the Peclet number. Growth factors appropriate to these time scales for the overstable motions of a thermally dissipative, Boussinesq fluid are derived. For the linear analysis of a slender structure it is shown that the dispersive nature of the waves is deducible from the simplified one-dimensional equations. The analysis is extended, for slender structures, to nonlinear motions and the governing equation representing an effective balance between nonlinear, dispersive and dissipative effects, the Benjamin-Ono-Burgers equation, is established. The solutions of this equation are considered and, for weakly-dissipative systems, are shown to be slowly decaying solitons. The importance, in the context of group velocity, of the dispersive nature of waves in ducted structures is discussed and analogies are made with other ducted waves, for example, the Love waves of seismology. It is suggested that the behaviour of such waves, following an impulse, may account for the range of oscillatory behaviour, the quasi-periodic and short time scales, observed in both the solar corona and Earth's magnetosphere. Density variations across a structure and the structure's curvature, with possible applications to coronal loops, are also considered. Further suggestions for possibly identifying some of the theoretical results with observed behaviour in sunspots, chromospheric fibrils and spicules are also made.

On microdosimetry of neutrons of selectable energy in mixed (n,y) fields

Saion, Elias bin. — Sun, 01 Jan 1989 00:00:00 GMT

Abstract: Biological damage of tissue due to intermediate energy neutrons is generally known to be very important in radiobiology and radiation protection. However, there is no suitable method to determine the quality of these neutrons in particular in the working environment of mixed (n,y) radiation fields. In this thesis, an attempt is made to develop a dosimeter based on microdosimetric principles which has the capability for such a purpose. With this object the basic concepts of microdosimetry are reviewed and discussed with emphasis on their application for radiation protection and in designing of the dosimeter. Microdosimetry based on low pressure tissue-equivalent proportional counters (TEPCs) is a powerful technique for determining microscopic distributions of energy deposition and quality of ionizing radiations. However the energy deposition spectra of intermediate energy neutrons in mixed fields of fast neutrons can only be measured using TEPC in co-axial double cylindrical form by an appropriate choice for the thickness of the common tissue-equivalent (TE) dividing wall separating the inner and outer counters and by appropriate use of coincidence/anti-coincidence pulse arrangements. An analytical calculation for the response of the inner counter operating in coincidence/anti-coincidence modes with the outer counter was developed. However there will be some events, due to fast neutrons, which will contribute to the signals from intermediate energy neutrons and which cannot be removed by anti-coincidence. For these analytical corrections must be made. Also, the events associated with the dividing wall inherent in the system can contribute to the response of the inner counter and must be corrected by calculation. The calculation was possible due to the fact that recoil particles from intermediate energy neutron interactions have effective stopping powers and projected ranges which differ significantly from the continuous slowing down approximation (CSDA) values. By incorporating these the basic CSDA formulae for energy deposition spectra of neutrons could be extended down to intermediate energy neutrons of about 1 keV. A prototype co-axial double cylindrical TEPC capable of separating the component of neutrons (≤ 850 keV) in mixed (n,y) radiation fields was manufactured and tested. The thin wall dividing the inner and outer counters was fabricated from the standard A-150 TE plastic with the thickness equivalent to the range of 850 keV protons. The operational characteristics of the dosimeter were studied to determine its applicability for use in microdosimetry. The gas gain of the inner and outer TEPCs was measured at various simulated mean chord lengths and applied voltages. The results can be expressed according to Campion's equation within a given range of the electric field strength. The resolution of the inner TEPC measured at the operating voltages is in agreement with the theoretical prediction. A series of microdosimetric experiments were performed with mixed fields of 60Co gamma-rays and neutrons from the UTR-300 nuclear reactor and from 252Cf and 241Am-Be radioactive sources. Discrimination against fast neutrons of energy > 850 keV was achieved using an anti-coincidence unit specially designed for better efficiency of data acquisition. Discrimination against fast electrons due to photon interactions was also achieved. Spectra with anti-coincidence are dominated by slow protons and electrons. Their mean lineal energies are higher than those of spectra without anti-coincidence. The quality factor and dose equivalent for spectra with anti-coincidence are higher than the spectra without anticoincidence indicating the importance of intermediate energy neutrons in mixed fields. The quality factor and the corresponding dose equivalent corrected for saturation of lineal energy corresponding to 2 nm of ionization spacing is consistently higher than those derived from the absorbed dose based formulae, the biophysical implications of which are discussed. Suggestion for future developments for microdosimetry of intermediate energy neutrons in mixed fields are made and discussed.

Alternative techniques for the production and manipulation of ultracold atoms

Bruce, Graham D. — Wed, 20 Jun 2012 00:00:00 GMT

Abstract: This Thesis contains details of the construction and characterisation of a compact apparatus for the cooling of ultracold atoms to quantum degeneracy, and their manipulation in flexible holographic optical traps. We have designed and built two iterations of this apparatus. The first version consists of a stainless steel single-cell vacuum chamber, in which we confine ⁸⁷Rb and ⁶Li or ⁷Li in a Magneto-Optical Trap. We characterise the alternative methods of pulsed atomic dispenser and Light Induced Atomic Desorption (LIAD) to rapidly vary the background pressure in the vacuum chamber with the view to enabling efficient evaporative cooling in the single chamber, loading MOTs of up to 10⁸ atoms using pulsed dispensers. The LIAD is found to be ineffective in loading large MOTs in this setup, while the pulsed dispensers method gradually increases the background pressure in the chamber over time. Based on the results of this first iteration, we designed and built a second single-chamber apparatus for cooling of ⁸⁷Rb to quantum degeneracy. The LIAD technique was used to successfully load MOTs containing 8x10⁷ atoms in this single pyrex cell with a rapidly-varying background pressure. The lifetime of an atomic cloud loaded from the MOT into a magnetic trap increased by a factor of 6 when LIAD was used. The holographic optical traps for cold atoms are generated using a Spatial Light Modulator, and we present our novel method for improving the quality of holographic light patterns to the point where they are suitable for trapping ultracold atoms using a feedback algorithm. As demonstrations of this new capability, we show power-law optical traps which provide an efficient, reversible route to Bose-Einstein Condensation and a dynamic ring trap for the investigation of superfluidity in cold atoms.

The electronic structure of the nematic materials Sr₃Ru₂O₇ and Ca(Co[subscript(x)]Fe[subscript(1-x)])₂As₂

Allan, Milan P. — Mon, 22 Nov 2010 00:00:00 GMT

Abstract: We investigated the electronic structure of the two nematic materials Sr₃Ru₂O₇ and Ca(Fe₀.₉₇Co₀.₀₃As)₂ using spectroscopic – imaging scanning tunneling microscopy (SI-STM) and angle resolved photoemission spectroscopy (ARPES). – – – Sr₃Ru₂O₇ is an itinerant metamagnet that shows a putative quantum critical endpoint at 8 Tesla, submersed by the formation of a nematic electronic phase. Using ARPES, we identified at least 5 Fermi pockets in agreement with quantum oscillation measurements. Surprisingly, we found Fermi velocities up to an order of magnitude lower than in single layer Sr₂RuO₄ and up to 35 times lower than predicted by ab initio calculations. Many bands are confined in an energy range of only ∼10 meV below the Fermi level. This, as well as distinct peak-dip-hump shapes of the spectra with a characteristic energy of around ∼5 meV indicate strong correlations and a possible nontrivial mechanism that is absent in single layer Sr₂RuO₄ and connected to the nematicity. The quasiparticle interference of one of the bands was detected by SI-STM, which was also used to measure subatomic features with the symmetries of the relevant Ru d orbitals. – – – In the second mate- rial, the iron-based high-temperature superconductor Ca(Fe[subscript(1-x)]Co[subscript(x)]As)₂, we discovered electronic nematic nano-pattern in its under-doped ‘parent’ state. We spectroscopically imaged this state in real space over large areas and across domain boundaries that change the directionality of the nano-pattern by 90°. We propose that oriented, dimer-shaped electronic nematogens are responsible for this pattern, in striking contrast to what has been expected and observed in electronic nematic materials. The dimers consist of two Gaussian conductance peaks separated by about 8 a[subscript(FeFe)]. Unidirectionality also shows in the quasiparticle interference pattern of the delocalized electrons. The dispersion is in agreement with scattering from the α₂ band discovered by ARPES but has distinct C₂ symmetry, not inconsistent with a C₄-symmetric band scattered by the proposed dimers.

Organic semiconductor lasers : compact hybrid light sources and development of applications

Yang, Ying — Tue, 01 Jun 2010 00:00:00 GMT

Abstract: This thesis describes a number of studies on organic semiconductors as laser gain media with the aim of simplifying the excitation scheme and exploring potential applications. A hybrid device taking the advantage of high power inorganic light emitting diodes (LEDs) and low threshold organic distributed feedback lasers is demonstrated to realize a LED pumped organic laser. When the drive current is higher than 152 A, a sharp peak is clearly observed in the laser output spectrum, implying the LED successfully pumps the polymer laser above threshold. This is the first time an incoherent LED has been used as the excitation source for an organic semiconductor laser. A strategy for further improving the performance of the hybrid device is explored with the use of a luminescent concentrator made of a dye doped SU8 film, to intensify the power density from the inorganic LED. The luminescent concentrator is capable of increasing the incident power density by a factor of 9 and reducing the lasing threshold density by 4.5 times. As a preliminary investigation towards mode-locked polymer lasers, the impact of a solid state saturable absorber on a solution based organic semiconductor laser is explored. The dye doped polystyrene thin film saturable absorber exhibits a saturation intensity of a few MW/cm². When it is placed into the laser cavity, a train of short pulses is generated and the underlying mechanism is discussed. Finally, the potential of using organic semiconductor lasers in the detection of nitro-aromatic explosive vapours is studied in distributed feedback polyfluorene lasers. A high sensing efficiency and fast response from the laser prove polyfluorene lasers can be used as disposal and low cost devices in explosive chemosensing.

Supermassive black holes : the local supermassive black hole mass function

Vika, Marina — Fri, 01 Jun 2012 00:00:00 GMT

Abstract: Over recent years there has been an increase of the number of secure supermassive black hole (SMBH) detections. These SMBH measurements have lead astronomers to establish well defined empirical relationships between the SMBH mass and some of the properties of the host galaxy. The number of galaxies with SMBH mass measurements is currently limited to about 100. One approach of expanding the study of the SMBH is to use the empirical relations for estimating M[subscript(bh)] for larger samples of galaxies. The investigation of the SMBH population (or SMBH mass function) for large sample of galaxies in the nearby universe has helped to constrain the SMBH and the galaxy evolution. Previous estimates of the SMBH mass function at low redshift were produced mainly by combining the measurements of the galaxy luminosity or velocity function with one of the SMBH scaling relations. In the first part of the thesis I will present an independent construction of the nearby supermassive black hole mass function by applying the optical M[subscript(bh)]–L relation onto the Millennium Galaxy Catalogue (MGC). Additionally, in the second part I will provide photometric analysis of all UKIDSS galaxies for which SMBH masses have been measured. I will derive composite profiles of brightness, ellipticity and position angles of each galaxy. I will show that the Sérsic function fits the brightness profile of the majority of the elliptical galaxies and the bulge of disk galaxies and I will provide alternative multi-component fits when necessary. Then these photometric parameters will be used for constructing the M[subscript(bh)]–L relation in the near-IR and to investigate the M[subscript(bh)]–n relation. In the third part I will construct the near-IR SMBH mass function for the Galaxy and Mass Assembly (GAMA) survey. For this purpose I will apply the newly derived M[subscript(bh)]–L relation onto an elliptical subsample of K-band images. The advantage of this SMBH mass function is that during the M[subscript(bh)]–L construction I used the same quality images and techniques used on the GAMA survey. Apart from the M[subscript(bh)]–L relation, the M[subscript(bh)]–sigma relation was used as an alternative approach for a subsample of galaxies for which the velocity dispersions were available. Furthermore, I employed both local SMBH mass functions (MGC & GAMA) for estimating the SMBH mass density at redshift zero and accounted for the dependence of the total SMBH density on the look-back time by comparing with semi-analytic SMBH mass functions. Finally, from the SMBH mass density I estimated the baryon fraction that is locked into SMBHs.

Optical transfection and injection techniques applied to mammalian and embryonic cells

Torres, Maria Leilani — Wed, 30 Nov 2011 00:00:00 GMT

Abstract: The delivery of biomolecules into living cells is an important methodology in cell and molecular biology. Optical methods using lasers are attractive tools for such application. However, the interaction of the laser with the cell depends on the laser type and the parameters used. Hence, in this thesis, optical transfection and injection of both mammalian and embryonic cells is demonstrated using a variety of laser sources. Furthermore, some key issues are addressed by demonstrating alternative configurations of optoinjection and transfection systems to develop a robust, user-friendly device with potential for commercialisation. Most optical methods for the delivery of molecules rely on complex and expensive laser systems that occupy a large footprint. In order for the system to be accessible to end-users, transient transfection of plasmid DNA into mammalian cells using an inexpensive continuous wave 405 nm diode laser is demonstrated. In this work, the laser parameters are varied in order to optimise the transfection efficiency. By calculating the temperature change upon irradiation of the focused violet light, the mechanism of violet diode laser transfection is elucidated. Furthermore, the system is used to deliver small interfering RNA molecules to specifically knock down a particular protein within the cell. This work is a major step towards an inexpensive and portable optical transfection system. The critical issue of accurate targeting of the cell membrane is also addressed in conventional near-infrared femtosecond optical transfection systems. A near-infrared femtosecond holographic system is built utilising a spatial light modulator in order to provide fast three dimensional beam translation. Computer control of dosage and targeting allows us to explore the potential of different targeting modalities. An enhanced optoinjection and transfection on mammalian cells is demonstrated. Furthermore, the system is applied to optically manipulate a developing Pomatoceros lamarckii embryo. The holographic system can be employed to optoinject a variety of macromolecules into the embryo, as well as orient and position the embryo by switching to the continuous wave mode of the laser. Such development of optical techniques to deliver biomolecules and orient embryos will benefit the field of developmental biology. Lastly, to achieve controlled cavitation, limiting the mechanical effects of a nanosecond laser source, an optically trapped microsphere undergoes laser induced breakdown in the presence of a cell monolayer. Laser induced breakdown of a trapped microsphere allows control over several parameters, such as the microsphere material, position of the breakdown from the monolayer and the size of the microsphere. Optimising these parameters provide limited mechanical effects, particularly suited for cell transfection. This technique is an excellent tool for plasmid-DNA transfection of multiples of cells with both reduced energy requirements and cell lysis compared to previously reported approaches. Demonstrating optimised and successful delivery of macromolecules with the variety of laser sources used in this thesis will advance the applicability of optical injection and transfection and allow more potential users to access the technique. This thesis advances optical injection and transfection for optimised delivery of macromolecules to both mammalian cells and a developing embryo.

Integration methods for enhanced trapping and spectroscopy in optofluidics

Ashok, Praveen Cheriyan — Thu, 01 Dec 2011 00:00:00 GMT

Abstract: “Lab on a Chip” technologies have revolutionized the field of bio-chemical analytics. The crucial role of optical techniques in this revolution resulted in the emergence of a field by itself, which is popularly termed as “optofluidics”. The miniaturization and integration of the optical parts in the majority of optofluidic devices however still remains a technical challenge. The works described in this thesis focuses on developing integration methods to combine various optical techniques with microfluidics in an alignment-free geometry, which could lead to the development of portable analytical devices, suitable for field applications. The integration approach was applied to implement an alignment-free optofluidic chip for optical chromatography; a passive optical fractionation technique fractionation for cells or colloids. This system was realized by embedding large mode area photonic crystal fiber into a microfluidic chip to achieve on-chip laser beam delivery. Another study on passive sorting envisages an optofluidic device for passive sorting of cells using an optical potential energy landscape, generated using an acousto-optic deflector based optical trapping system. On the analytical side, an optofluidic chip with fiber based microfluidic Raman spectroscopy was realized for bio-chemical analysis. A completely alignment-free optofluidic device was realized for rapid bio-chemical analysis in the first generation by embedding a novel split Raman probe into a microfluidic chip. The second generation development of this approach enabled further miniaturization into true microfluidic dimensions through a technique, termed Waveguide Confined Raman Spectroscopy (WCRS). The abilities of WCRS for online process monitoring in a microreactor and for probing microdroplets were explored. Further enhanced detection sensitivity of WCRS with the implementation of wavelength modulation based fluorescent suppression technique was demonstrated. WCRS based microfluidic devices can be an optofluidic analogue to fiber Raman probes when it comes to bio-chemical analysis. This allows faster chemical analysis with reduced required sample volume, without any special sample preparation stage which was demonstrated by analyzing and classifying various brands of Scotch whiskies using this device. The results from this study also show that, along with Raman spectroscopic information, WCRS picks up the fluorescence information as well, which might enhance the classification efficiency. A novel microfabrication method for fabricating polymer microlensed fibers is also discussed. The microlensed fiber, fabricated with this technique, was combined with a microfluidic gene delivery system to achieve an integrated system for optical transfection with localized gene delivery.

Silicon electro-optic modulator

Dong, Fengqiao — Thu, 27 Oct 2011 00:00:00 GMT

Abstract: In recent years, as on-chip data transmission has increased dramatically, much time and effort has been devoted to the development of compact electro-optic modulators with large bandwidth and low power consumption, which is the key component for on-chip data links. Silicon which has been widely used in electronic industry has been considered as a promising material for electro-optic modulators, due to its mature manufacturing technology and low cost. In this work, a silicon electro-optic modulator based on a new type of phase shifter is proposed. The phase shifter is in one arm of an asymmetric Mach-Zehnder interferometer (MZI) structure and operates very similar to a MOS capacitor. Indium tin oxide (ITO) is used as an electrode and flowable oxide (FOx, spin-on-glass) is used as a gate oxide. ITO is being widely used in many electro-optic applications as a transparent conductor, as it offers both electrical conductivity and optical transparency, although it has seen less use in optical waveguide devices. Electrical simulations have been completed in order to study the electrical performance of the phase shifter and also to improve the design. SiO₂ has been used as a gate oxide in the simulation. The depletion region width and capacitance-voltage (C-V) characterization have been modelled. Based on the theoretical analysis and simulation results, n-type silicon with the doping concentration of 1×10¹⁷ cm⁻³ has been chosen as the active material. ITO fabrication and its electrical and optical properties have been studied. The effect of ITO annealing on sheet resistance and transmittance has been investigated. ITO (140 nm thick) annealed at 400˚C for 30 minutes in air shows the best result. The sheet resistance is around 750 Ω/□ and the optical transmittance is about 87%. Aluminium (Al) electrical contacts to silicon have been fabricated and tested. The HF cleaning and post thermal annealing effect on the contact resistance has been investigated. The transmission line method (TLM) has been used to determine the contact resistance. The Al contact resistance is about 335 Ω on n-type silicon substrate with a doping concentration of 1×10¹⁷ cm⁻³. ITO-FOx phase shifters and modulators have been fabricated and tested. The MZI structure of the modulator shows the typical interference pattern. This is important for realising phase-intensity modulation. Al-FOx phase shifters have also been fabricated and tested. The transmission depends on the Voltage, both in terms of phase and the optical loss, clearly indicating a change in carrier density. Although ITO-FOx phase shifters and modulators did not work successfully due to high optical losses caused by waveguides sidewall roughness and fabrication process, ITO showed promise to use in electro-optic modulators as a transparent conducting layer. The ITO layer separates silicon waveguides from Al contacts and lowers optical losses due to metal absorption. Overall, successful operation of a MOS-capacitor type optical phase shifter has been achieved, but the modulation efficiency is low (1 dB at 50 V) and the insertion loss is high (over 10 dB). Description: Electronic version excludes material for which permission has not been granted by the rights holder

Electrically injected photonic-crystal nanocavities

Welna, Karl P. — Wed, 30 Nov 2011 00:00:00 GMT

Abstract: Nano-emitters are the new generation of laser devices. A photonic-crystal cavity, which highly confines light in small volumes, in combination with quantum-dots can enhance the efficiency and lower the threshold of this device. The practical realisation of a reliable, electrically pumped photonic-crystal laser at room-temperature is, however, challenging. In this project, a design for such a laser was established. Its properties are split up into electrical, optical and thermal tasks that are individually investigated via various device simulations. The resulting device performance showed that with our design the quantum-dots can be pumped in order to provide gain and to overcome the loss of the system. Threshold currents can be as low as 10’s of μA and Q-factors in the range of 1000’s. Gallium arsenide wafers were grown according to our specifications and their diode behaviour confirmed. Photonic-crystal cavities were fabricated through a newly developed process based on a TiOₓ hard-mask. Beside membraned cavities, also cavities on oxidised AlGaAs were fabricated with help to a unique hard-mask removal method. The cavities were measured with a self-made micro-photoluminescence setup with the highest Q-factor of 4000 for the membrane cavity and a remarkable 2200 for the oxide cavity. The fabrication steps, regarding the electrically pumped photonic-crystal laser, were developed and it was shown that this device can be fabricated. During this project, a novel type of gentle confinement cavity was developed, based on the adaption of the dispersion curve (DA cavity) of a photonic-crystal waveguide. Q-factors of as high as 600.000 were measured for these cavities made in Silicon.

Biophysical aspects of photodynamic therapy

Valentine, Ronan — Wed, 30 Nov 2011 00:00:00 GMT

Abstract: Photodynamic therapy (PDT) is a multimodality cancer treatment available for the palliation or eradication of systemic and cutaneous malignancies. In this thesis, the application of PDT is for the treatment of non-melanoma skin cancer (NMSC). While PDT has a well-documented track record, there are, at this time no significant indicators to suggest the superiority of one treatment regime over the next. The motivation for this work is to provide additional evidence pertaining to PDT treatment variables, and to assist in optimising PDT treatment regimes. One such variable is the treatment light dose. Determining the light dose more accurately would assist in optimising treatment schedules. Furthermore, choice of photosensitiser pro-drug type and application times still lack an evidence base. To address issues concerning treatment parameters, fluorescence spectroscopy – a valuable optical diagnostic technique – was used. Monitoring the in vivo PpIX fluorescence and photobleaching during PDT was employed to provide information pertaining to the progression of treatment. This was demonstrated by performing a clinical study at the Photobiology Unit, Ninewells Hospital and Medical School, Dundee. Two different photosensitiser pro-drugs – either 5-aminolaevulinic acid (ALA) or its methyl ester (MAL) – were investigated and based on the fluorescence and pain data recorded both may be equally suitable for topical PDT. During PDT, surface fluorescence is observed to diminish with time – due to photobleaching – although cancerous cells may continue to be destroyed deep down in the tissue. Therefore, it is difficult to ascertain what is happening at depth in the tumour. This raised the questions; How long after surface PpIX fluorescence has diminished is the PDT treatment still effective and to what depths below the surface is effective treatment provided? In order to address these important questions, a three-dimensional (3D) Monte Carlo radiation transfer (MCRT) model was used to compute the light dose and the ¹O₂ production within a tumour, and the PpIX fluorescence emission from the tumour. An implicit dosimetry approach based on a single parameter – fluorescence photobleaching – was used in order to determine the ¹O₂ generation, which is assumed to be related to tissue damage. Findings from our model recommended administering a larger treatment light dose, advocating an increase in the treatment time after surface PpIX fluorescence has diminished. This increase may ultimately assist in optimising PDT treatment regimes, particularly at depth within tumours.

FePt magnetic nanoparticles : syntheses, functionalisation and characterisation for biomedical applications

Chen, Shu — Mon, 21 Feb 2011 00:00:00 GMT

Abstract: Iron platinum (FePt) has attracted growing interest because of its high Curie temperature, magneto-crystalline anisotropy and chemical stability. Nanoparticles (NPs) made of this alloy are promising candidates for a wide range of biomedical applications including magnetic separation, magnetic targeted drug delivery, hyperthermia for cancer therapy and also as magnetic resonance imaging (MRI) contrast agents. This thesis presents the synthesis, functionalization and characterization of FePt NPs along with a toxicity study and an investigation into their application as MRI contrast agents. Regarding their synthesis, different approaches have been explored including the co-reduction of Fe and Pt precursors in an aqueous media, the thermal decomposition in a conventional high-boiling solvent such as benzyl ether, and in low-melting organic salts (ionic liquids). The data revealed an inhomogeneous composition distribution of Fe and Pt between particles obtained in aqueous media, due to the iron salts hydrolysis, and a mismatch in the co-reduction kinetic of the two metal precursors. While the iron content in the NPs could be increased by using more hydrolytically stable iron precursors or stronger reducing agents, there are remaining limiting parameters which prevent further Fe content increase in NPs. In contrast, by excluding the water from the reaction system and using a Fe²⁻ iron precursor, homogenous 1:1 Fe to Pt ratio NPs can be obtained through a modified thermal decomposition pathway in benzyl ether. Based on the study of synthesis in this conventional chemical, the potential of ionic liquids (ILs) to be used as novel solvents for FePt NPs synthesis was further explored. It was then demonstrated that ionic liquids (ILs) can not only be used as a solvent for synthesis of FePt NPs, but also can provide an exciting alternative pathway to direct synthesis fct-FePt NPs. In the context of the bioapplication of FePt NPs, a family of FePt NPs was specifically designed to enhance their MRI contrast agents properties. In contrast with previous reports, this thesis demonstrates that FePt NPs can be made non-toxic and provides the first data on their cellular uptake mechanisms. A six times increase in the FePt based T₂ contrast properties compared to clinical iron oxide NPs is reported. The relationship between the MRI contrast properties and the NPs architecture is explored and rationalised as the basis for the design of NPs as enhanced MRI contrast agents. Finally, the first observations of cellular and in vivo MR imaging with FePt NPs is also reported. This study opens the way for several applications of FePt NPs such as regenerative medicine and stem cell therapy, thus providing a bio-platform to develop novel diagnostic and therapeutic agents.

Photonic crystal waveguides in chalcogenide glasses

Spurny, Marcel — Wed, 30 Nov 2011 00:00:00 GMT

Abstract: The growing speed and bandwidth requirements of telecommunication systems demand all-optical on-chip solutions. Microphotonic devices can deliver low power nonlinear signal processing solutions. This thesis looks at the slow light photonic crystals in chalcogenide glasses to enhance low power nonlinear operation. I demonstrate the development of new fabrication techniques for this delicate class of materials. Both, reactive ion etching and chemically assisted ion beam etching are investigated for high quality photonic crystal fabrication. A new resist-removal technique was developed for the chemical, mechanical and light sensitive thin films. I have developed a membraning method based on vapor phase etching in combination with the development of a save and economical etching tool that can be used for a variety of vapour phase processes. Dispersion engineered slow light photonic crystals in Ge₃₃As₁₂Se₅₅ are designed and fabricated. The demonstration of low losses down to 21±8dB/cm is a prerequisite for the successful demonstration of dispersion engineered slow light waveguides up to a group index of around n[subscript(g)] ≈ 40. The slow light waveguides are used to demonstrate highly efficient third harmonic generation and the first advantages of a pure chalcogenide system over the commonly used silicon. Ge₁₁.₅As₂₄24Se₆₄.₅ is used for the fabrication of photonic crystal cavities. Quality factors of up to 13000 are demonstrated. The low nonlinear losses have enabled the demonstration of second and third harmonic generation in those cavities with powers up to twice as high as possible in silicon. A computationally efficient model for designing coupled resonator bandpass filters is used to design bandpass filters. Single ring resonators are fabricated using a novel method to define the circular shape of the rings to improve the fabrication quality. The spectral responses of the ring resonators are used to determine the coupling coefficient needed for the design and fabrication of the bandpass filters. A flat top bandpass filter is fabricated and characterized as demonstration of this method. A passive all-optical regenerator is proposed, by integrating a slow-light photonic crystal waveguide with a band-pass filter based on coupled ring resonators. A route of designing the regenerator is proposed by first using the dispersion engineering results for nonlinear pulse propagation and then using the filter responses to calculate the nonlinear transfer function.

Material and device design for organic optoelectronics

Levell, Jack William — Wed, 30 Nov 2011 00:00:00 GMT

Abstract: This thesis describes investigations into the photophysical properties of luminescent materials and their application in optoelectronic devices such as light emitting diodes and photodetectors. The materials used were all solution processable because of the interest in low cost processing of organics. I have investigated the photophysics of 1,4,5,8,9,12-hexamethyltriphenylene, a triphenylene derivative which has its luminescence enhanced by the addition of methyl groups. These groups change the planar shape of the triphenylene molecule into a twisted one, changing the symmetry of the molecule and increasing its dipole moment in absorption and emission by ~4 fold. This increased its rate of radiative deexcitation by ~20 times. In addition, the twisted shape of the molecule prevents intermolecular interactions and concentration effects from affecting the luminescence. This results in an efficient solid-state photoluminescence quantum yield of 31%. This thesis also includes an investigation into phosphorescent polymer dendrimers, designed to have suitable viscosities in solution for inkjet printed OLED applications. A photophysical study of the intra-chain aggregation effects on the luminescence was undertaken in both homopolymers and copolymers with high energy gap spacer units. Using double dendrons to increase the steric protection of the luminescent cores, the best homopolymers achieved 12.1% external quantum efficiency (39.3 cd/A) at 100 cd/m² brightness and the best co-polymer achieved 14.7% EQE (48.3 cd/A) at 100 cd/m². This compares favourably with 11.8% EQE for the best phosphorescent polymer and 16% for the best solution processed dendrimer OLED previously reported. Finally I have applied a solution processed enhancement layer to silicon photodiodes to enhance their ultraviolet response. Using a blend of materials to give favourable absorption and emission properties, 61% external quantum efficiency was achieved at 200 nm, which is better than the 20-30% typical for vacuum deposited lumogen enhancement layers used commercially.

Ultrafast photophysics of iridium complexes

Hedley, Gordon J. — Tue, 30 Nov 2010 00:00:00 GMT

Abstract: This thesis presents ultrafast photophysical measurements on a number of phosphorescent iridium complexes and establishes relationships between the relaxation rates and the vibrational properties of the material. When ultrafast luminescence is measured on the peak of the phosphorescence spectrum and on its red-side, 230 fs and 3 ps decay time constants were observed in all materials studied, and this was attributed to population redistribution amongst the three electronic substates of the lowest triplet metal-ligand charge transfer (MLCT) state. The observation of luminescence at higher values of energy embodied ultrafast dissipation of excess energy by intramolecular vibrational redistribution (IVR) and it was found that the dissipation channels and rate of IVR could be modified by chemical modification of the emitting molecule. This was tested in two ways. Firstly by adding electronically inactive dendrons to the core, an increase in the preference for dissipation of excess energy by IVR rather than by picosecond cooling to the solvent molecules was found, but this did not change the rate of IVR. The second method of testing was by fusing a phenyl moiety directly onto the ligand, this both increased the rate of IVR and also the preference for dissipation by it rather than by picosecond cooling. Fluorescence was recorded in an iridium complex for the first time and a decay time constant of 65 fs was found, thus allowing a direct observation of intersystem crossing (ISC) to be made. In a deep red emitting iridium complex internal conversion (IC) and ISC were observed and the factors controlling their time constants deduced. IC was found to occur by dissipation of excess energy by IVR. The rate of IC was found to be dependent on the amount of vibrational energy stored in the molecule, with IC fast (< 45 fs) when < 0.6 eV of energy is stored and slower (~ 70 fs) when the value is > 0.6 eV. The rate of ISC agreed with these findings, indicating that the very process of ISC may be thought of as closely analogous to that of IC given the strongly spin-mixed nature of the singlet and triplet MLCT states.

Extragalactic and cosmological tests of gravity theories with additional scalar or vector fields

Feix, Martin — Fri, 24 Jun 2011 00:00:00 GMT

Abstract: Despite the many successes of the current standard model of cosmology on the largest physical scales, it relies on two phenomenologically motivated constituents, cold dark matter and dark energy, which account for approximately 95% of the energy-matter content of the universe. From a more fundamental point of view, however, the introduction of a dark energy (DE) component is theoretically challenging and extremely fine-tuned, despite the many proposals for its dynamics. On the other hand, the concept of cold dark matter (CDM) also suffers from several issues such as the lack of direct experimental detection, the question of its cosmological abundance and problems related to the formation of structure on small scales. A perhaps more natural solution might be that the gravitational interaction genuinely differs from that of general relativity, which expresses itself as either one or even both of the above dark components. Here we consider different possibilities on how to constrain hypothetical modifications to the gravitational sector, focusing on the subset of tensor-vector-scalar (TeVeS) theory as an alternative to CDM on galactic scales and a particular class of chameleon models which aim at explaining the coincidences of DE. Developing an analytic model for nonspherical lenses, we begin our analysis with testing TeVeS against observations of multiple-image systems. We then approach the role of low-density objects such as cosmic filaments in this framework and discuss potentially observable signatures. Along these lines, we also consider the possibility of massive neutrinos in TeVeS theory and outline a general approach for constraining this hypothesis with the help of cluster lenses. This approach is then demonstrated using the cluster lens A2390 with its remarkable straight arc. Presenting a general framework to explore the nonlinear clustering of density perturbations in coupled scalar field models, we then consider a particular chameleon model and highlight the possibility of measurable effects on intermediate scales, i.e. those relevant for galaxy clusters. Finally, we discuss the prospects of applying similar methods in the context of TeVeS and present an ansatz which allows to cast the linear perturbation equations into a more convenient form.

Hawking radiation in dispersive media

Robertson, Scott James — Fri, 24 Jun 2011 00:00:00 GMT

Abstract: Hawking radiation, despite its presence in theoretical physics for over thirty years, remains elusive and undetected. It also suffers, in its original context of gravitational black holes, from conceptual difficulties. Of particular note is the trans-Planckian problem, which is concerned with the apparent origin of the radiation in absurdly high frequencies. In order to gain better theoretical understanding and, it is hoped, experimental verification of Hawking radiation, much study is being devoted to systems which model the spacetime geometry of black holes, and which, by analogy, are also thought to emit Hawking radiation. These analogue systems typically exhibit dispersion, which regularizes the wave behaviour at the horizon but does not lend itself well to analytic treatment, thus rendering Hawking’s prediction less secure. A general analytic method for dealing with Hawking radiation in dispersive systems has proved difficult to find. This thesis presents new numerical and analytic results for Hawking emission spectra in dispersive systems. It examines two black-hole analogue systems: it begins by introducing the well-known acoustic model, presenting some original results in that context; then, through analogy with the acoustic model, goes on to develop the lesser-known fibre-optical model. The following original results are presented in the context of both of these models: • an analytic expression for the low-frequency temperature is found for a hyperbolic tangent background profile, valid in the entire parameter space; it is well-known that the spectrum is approximately thermal at low frequencies, but a universally valid expression for the corresponding temperature is an original development; • an analytic expression for the spectrum, valid over almost the entire frequency range, when the velocity profile parameters lie in the regime where the low-frequency temperature is given by the Hawking prediction; previous work has focused on the low-frequency thermal spectrum and the characterization of the deviations from thermality, rather than a single analytic expression; and • a new unexplored regime where no group-velocity horizon exists is examined; the Hawking spectra are found to be non-zero here, but also highly non-thermal, and are found, in the limit of small deviations, to vary with the square of the maximum deviation; the analytic expression for the case with a horizon is found to carry over to this new regime, with appropriate modifications. Furthermore, the thesis examines the results of a classical frequency-shifting experiment in the context of fibre-optical horizons. The theory of this process is presented for both a constant-velocity and a constantly-decelerating pulse, the latter case taking account of the Raman effect. The resulting spectra are at least qualititively explained, but there is a discrepancy between theory and experiment that has not yet been accounted for.

Observational signatures of massive star formation : an investigation of the environments in which they form, and the applicability of the paradigm of low-mass star formation

Johnston, Katharine G. — Fri, 24 Jun 2011 00:00:00 GMT

Abstract: This thesis presents both a study of the cluster-scale environments in which massive stars form, investigating in particular how the ionized gas in these regions relates to the molecular star-forming material, as well as detailed studies of two luminous forming stars, AFGL 2591 and IRAS 20126+4104, to determine whether they are forming similarly to their low-mass counterparts. The results of this work include the identification of 35 HII regions (20 newly discovered) via a radio continuum survey of ionized gas towards 31 molecular cluster-forming clumps. The observed ionized gas was found to be preferentially associated with the clumps, which were shown to have a range of evolutionary stages. The massive star formation efficiency was determined for the clumps with associated ionized gas, and a relationship was found between the mass of the clumps and the mass of their embedded massive stars. By modelling the SEDs and images of AFGL 2591 and IRAS 20126+4104, it was found that the geometry of their circumstellar material was generally consistent with an envelope plus disk, similar to that expected for low-mass protostars. However, within the central ~1800 AU, the mid-IR images of IRAS 20126+4104 were better described by only a flattened envelope, suggesting that the radiation from IRAS 20126+4104 may be affecting the regions closest to the star. Observations of the ionized and molecular gas towards AFGL 2591 were carried out, and a photoionization code was developed to interpret these observations. The results showed that the observed 3.6 cm emission is likely to be produced by both a shock-ionized jet and a hypercompact HII region that does not appear to have disrupted the jet or the large-scale circumstellar environment. In addition, the C¹⁸O(1-0) emission observed towards AFGL2591 traces the densest parts of the outflow, with the blue-shifted emission exhibiting many of the properties of the outflows from low-mass protostars.

Advanced photonic methodologies for the 'in vitro' manipulation of cellular systems

McDougall, Craig — Sat, 01 Jan 2011 00:00:00 GMT

Abstract: This thesis investigates the application of a variety of optical techniques for the manipulation of single cells and their local micro-environment. The methodologies developed provide enhanced control over a single cell under study affording exquisite spatial and temporal control over biological processes of interest. The work presented within the thesis can be split into three distinct categories. The first of these provides an investigation in light activated “caged” molecular probes. This work generated several new compounds which were then applied to providing control over processes involved in pain, mitochondrial intracellular signalling and memory processes in the central nervous system. Application of caged neurotransmitters then demonstrates the first in vitro wavelength orthogonal photolysis of biologically relevant substances. Such a technique has great potential in the study of fundamental interactions within the processes underpinning memory and cognitive function. Secondly the application of optical injection techniques for the introduction of membrane impermeable species of interest is presented. An exploration of laser sources and optical systems has yielded two new strategies for optical injection. The targeted introduction of fluorescent stains, nucleic acids and gold nanoparticles to the interior of live mammalian cells demonstrates the power of these techniques. Thirdly, an investigation in optical trapping and optical injection provides simplified micromanipulation techniqes for application to biological studies. The use of capillaries as reservoirs for reagents of interest has realised a procedure for the reduction of large-scale chemical assays to a single cell level in static flow. When this technique is combined with intelligent control over the trapping laser source’s temporal behaviour, the interaction with the sample under study can be tailored for biological amiability or sample ablation. In this way a single laser source can be employed for the optical trapping and nanosurgery of a biological sample. A final study is presented demonstrating initial results for the targeted optical injection of caged compounds into mammalian cells. This methodology draws on the strengths of optical injection and caging technologies and presents a significant step forward in the level of control afforded over a biological system under study by optical techniques. The studies presented highlight the level of control and flexibility afforded by the application of optical manipulation and excitation strategies. Such optical methodologies extend the photonic tools available for enhanced studies in the life sciences.

Optically guided neuronal growth

Carnegie, David John — Sat, 01 Jan 2011 00:00:00 GMT

Abstract: In this thesis, experiments into artificially guiding neuronal growth cones using tightly focused laser beams were performed and evaluated. The experiments are performed by focusing a laser beam to the leading edge of a developing growth cone and attempting to change the direction of growth cone. These experiments were carried out using Gaussian, line and asymmetric line beam profiles. There was no noticeable change in the success rate with different beam profiles. Following this, I assisted my colleague Dr Michael Mazilu in the construction of a mathematical model of filopedia in an optical field in order to help explain the mechanism for optically guided neuronal growth which suggests that optical trapping forces on filopedia are responsible. Next, I set about implementing a system to automate the process of laser guided neuron growth by employing a spatial light modulator and a custom-built computer program. This allowed the computer to track a developing growth cone and automatically adjust the position of the laser beam as the growth cone developed. This program was successfully employed to artificially grow neuronal growth cones towards a user-inputted target point. The use of the spatial light modulator to beam shape was also demonstrated with the use of a Bessel beam being used to guide neurons for the first time. I also used a transgenic cell line of neurons to show for the first time that HSP70 is not involved in this phenomenon. This was accomplished by transfecting NG108’s with a plasmid containing HSP70 promoter tagged GFP. Under enough thermal or mechanical stress, the cells would express HSP70 which would produce a detectable GFP signal. No GFP was detected in cells after being exposed to laser irradiation of a power higher than would normally be used to guide neurons. Combined, these experiments show that the beam profile of the operating laser does not significantly affect the success of artificial growth and that the optical force on filopedia near the laser beam is likely to be the mechanism for this phenomenon. A possible heating effect of the laser has also been shown to not be strong enough to elicit a heat shock stress response from the cell. The demonstration of an automatic system which incorporates beam shaping has also been shown and such a system shows the potential to advance the investigation of artificial neuron growth using lasers.

Techniques for homodyne dechirp-on-receive linearly frequency modulated radar

Middleton, Robert — Wed, 22 Jun 2011 00:00:00 GMT

Abstract: This thesis presents work done to extend and improve the operation of homodyne dechirp-on-receive linearly frequency modulated radars. First, an investigation of the effect of common phase errors on the point response function of the radar is described. The dependence on the window function of the degradation due to phase errors is investigated, and a simple, precise, and general approach for calculating the degraded Point Spread Function (PSF) is described and demonstrated. This method is shown to be particularly useful when investigating the effect of chirp nonlinearity on the PSF. Next, a method for focussing range profiles that are degraded by chirp nonlinearity is described. This method is based on two established methods, the Phase Gradient Algorithm (PGA) and a time-domain re-sampling technique. The technique is entirely hardware independent, allowing any homodyne dechirp-on-receive linearly frequency modulated radar to be focussed. Where suitable archive signal data exists, focussed imagery can even be produced from radars that no longer exist. The complete algorithm and details of the implementation are described, and the technique is demonstrated on three representative radar cases: extreme chirp nonlinearity, typical chirp nonlinearity, and a retrospective case. In all of the cases, it was shown that the PSF was dramatically improved. A technique based on down conversion by aliasing for reducing the required sampling rate is described, and a simple technique for calculating suitable sampling rates is presented. This method is demonstrated for a typical application in which sampling rate reduction might be required, namely Moving Target Indication (MTI). The MTI application is described and quantified, including a simple technique for choosing suitable radar operation parameters. The MTI technique with subsampling was demonstrated in software simulations and in a simple radar experiment. A Synthetic Aperture Radar (SAR) test bench for researching component performance and scatterer properties in the context of SAR was developed. An appropriate image formation processing algorithm was found and modified to better suit the task of a short data collection baseline and drifting centre frequencies, both of which are present in the test bench situation. Software was written to collect data, to control the hardware, and to process the signals into SAR images. A data simulator was written to test the image formation algorithm implementation; it also served as a useful tool for investigating the effect of signal errors on the quality of the resultant SAR imagery. A suitable oscillator was chosen for the task, based on phase noise and centre frequency stability considerations, both of which are quantified and discussed. Preliminary SAR imagery was produced, indicating that the system operates correctly and in agreement with comparable systems.

Intracavity terahertz optical parametric oscillators

Walsh, David A. — Sat, 01 Jan 2011 00:00:00 GMT

Abstract: This thesis describes the design and implementation of several novel, nanosecond pulsed, intracavity optical parametric oscillators for the generation of terahertz radiation. The application of the intracavity approach in the context of terahertz optical parametric oscillators has been demonstrated for the first time, and the pump wave energy required was thereby reduced by an order of magnitude. The terahertz wave was tunable from under 1THz up to 3THz with a free running linewidth of ~50GHz and pulse energies up to ~20nJ (pulses were a few nanoseconds in duration). The terahertz beam profile was of Gaussian shape and could be focussed down to 2.3 times the diffraction limited spot size (M² values of 2.3 and 6.7 in the components of the beam parallel and perpendicular to the silicon prism array output coupler respectively). Developments of this intracavity source with regard to the linewidth are also reported. Implementation of etalons in the optical (laser and OPO) cavities was shown to be a promising technique that brings the terahertz linewidth down below 1GHz (close to the transform limit of nanosecond pulses) while retaining the tuning range and beam characteristics of the free running system. Close to Fourier transform limited pulses were obtained (<100MHz linewidth) via an injection seeding technique, although with significantly increased system complexity. A deleterious effect caused by the mode beating of a multimode host laser was also discovered, in that sidebands were induced on the seeded downconverted wave. This has wider implications in the field of intracavity OPOs. Finally, quasi-phasematching techniques implementing periodically poled lithium niobate were investigated as a way to lower the downconversion threshold energy requirement (by collinear propagation of the optical waves), and also to extract the terahertz wave rapidly from the (highly absorbing in the terahertz region) lithium niobate crystal. The existence of two phasematching solutions arising from the bidirectionality of the grating vector was identified as a serious design constraint in the context of an OPO where either solution can build up from noise photons, and so prefers the solution with the lowest walkoff of the downconverted waves - possibly resulting in unextractable terahertz radiation. Quasi-phasematching with an orthogonal grating vector (with identical but opposite phasematching solutions) was demonstrated and cascaded downconversion processes observed and characterised. These cascaded processes are permitted by the collinearality of the optical waves and may allow efficiency improvements through overcoming the quantum defect limit. This research has resulted in four peer reviewed papers in respected journals, and the intracavity terahertz OPO has been licensed to a company who have commercialised the technology (M Squared Lasers, Glasgow).

Numerical modeling of modified Newtonian dynamics in galaxies : testing the external field effects

Xufen, Wu — Tue, 30 Nov 2010 00:00:00 GMT

Abstract: Galaxies are natural laboratories for testing fundamental physics on the nature of the dark matter. MOdified Newtonian Dynamics (MOND) has been tested for over 20 years on small and large scales. While there are several versions of how MOND extrapolates to the large scales, and these versions are not yet fully successful, the original Bekenstein-Milgrom version of MOND is fully predictive and works very well on galaxy scales. However, little work has been done to explore this theory beyond fitting the rotation curves and Tully-Fisher relation of isolated disc galaxies. So far little is known of MONDian elliptical galaxies accelerating in any galaxy cluster. A defining feature of MOND is that internal dynamics of the galaxy depends on the overall acceleration of the galaxy. The existence of cuspy triaxial equilibria for elliptical galaxies is the minimal requirement to MOND. With the PhD project here, I constructed and then further studied the evolution and stability of gravitationally bound systems resembling like cuspy elliptical galaxies, both in isolation and when embedded in a uniform external field. I also studied the escape speeds from spiral galaxies, in particular by comparing the potentials of the Milky Way Galaxy in the Cold Dark Matter (CDM) and MOND frameworks.

Studies of novel beam shapes and applications to optical manipulation

Morris, Jill E. — Tue, 30 Nov 2010 00:00:00 GMT

Abstract: In this thesis an investigation into novel beams and optical manipulation is presented. Sculpting the phase profile of a Gaussian beam can result in the generation of a beam with unusual properties. Described in this thesis are optical vortices, Bessel beams and Airy beams. Additionally, optical manipulation was investigated using both novel beams and Gaussian beams with an emphasis on the use of a broad bandwidth laser source. The generation of multiple broadband optical trap sites was explored, and the transfer of orbital angular momentum from a broadband optical vortex to trapped microspheres was demonstrated. An introduction to the thesis and an overview of laser sources used for optical manipulation is presented in Chapters 1 and 2. Chapters 3 and 4 detail the background of optical manipulation and novel beam shaping. In Chapter 5, an investigation into the generation of multiple broadband optical trap sites is presented. Chapter 6 details the use of a ‘white light’ optical vortex to transfer orbital angular momentum to trapped microspheres. Chapter 7 presents the results of an investigation carried out using a supercontinuum source to characterise the wavelength and spatial coherence dependence of the properties of an optical Airy beam. The use of a monochromatic laser to generate Bessel beams that propagate along curved trajectories is detailed in Chapter 8. Chapter 9 summarises the thesis and suggests future work. Description: Electronic version excludes material for which permission has not been granted by the rights holder

Yb:tungstate waveguide lasers

Bain, Fiona Mair — Tue, 30 Nov 2010 00:00:00 GMT

Abstract: Lasers find a wide range of applications in many areas including photo-biology, photo-chemistry, materials processing, imaging and telecommunications. However, the practical use of such sources is often limited by the bulky nature of existing systems. By fabricating channel waveguides in solid-state laser-gain materials more compact laser systems can be designed and fabricated, providing user-friendly sources. Other advantages inherent in the use of waveguide gain media include the maintenance of high intensities over extended interaction lengths, reducing laser thresholds. This thesis presents the development of Yb:tungstate lasers operating around 1μm in waveguide geometries. An Yb:KY(WO₄)₂ planar waveguide laser grown by liquid phase epitaxy is demonstrated with output powers up to 190 mW and 76 % slope efficiency. This is similar to the performance from bulk lasers but in a very compact design. Excellent thresholds of only 40 mW absorbed pump power are realised. The propagation loss is found to be less than 0.1 dBcm⁻¹ and Q-switched operation is also demonstrated. Channel waveguides are fabricated in Yb:KGd(WO₄)₂ and Yb:KY(WO₄)₂ using ultrafast laser inscription. Several of these waveguides lase in compact monolithic cavities. A maximum output power of 18.6 mW is observed, with a propagation loss of ~2 dBcm⁻¹. By using a variety of writing conditions the optimum writing pulse energy is identified. Micro-spectroscopy experiments are performed to enable a fuller understanding of the induced crystal modification. Observations include frequency shifts of Raman lines which are attributed to densification of WO₂W bonds in the crystal. Yb:tungstate lasers can generate ultrashort pulses and some preliminary work is done to investigate the use of quantum dot devices as saturable absorbers. These are shown to have reduced saturation fluence compared to quantum well devices, making them particularly suitable for future integration with Yb:tungstate waveguides for the creation of ultrafast, compact and high repetition rate lasers.

The optical and NIR luminous energy output of the Universe : the creation and utilisation of a 9 waveband consistent sample of galaxies using UKIDSS and SDSS observations with the GAMA and MGC spectroscopic datasets

Hill, David T. — Fri, 24 Jun 2011 00:00:00 GMT

Abstract: Theories of how galaxies form and evolve depend greatly on constraints provided by observations. However, when those observations come from different datasets, systematic offsets may occur. This causes difficulties measuring variations in parameters between filters. In this thesis I present the variation in total luminosity density with wavelength in the nearby Universe (z<0.1), produced from a consistent reanalysis of NIR and optical observations, taken from the MGC, UKIDSS and SDSS surveys. I derive luminosity distributions, best-fitting Schechter function parameterisations and total luminosity densities in ugrizYJHK, and compare the variation in luminosity density with cosmic star formation history (CSFH) and initial mass function (IMF) models. I examine the r band luminosity distribution produced using different aperture definitions, the joint luminosity- surface brightness (bivariate brightness) distribution in ugrizYJHK, comparing them to previously derived distributions, and how the total luminosity density varies with wavelength when surface brightness incompleteness is accounted for. I find the following results. (1) The total luminosity density calculated using a non-Sersic (e.g. Kron or Petrosian) aperture is underestimated by at least 15%, (2) Changing the detection threshold has a minor effect on the best-fitting Schecter parameters, but the choice of Kron or Petrosian apertures causes an offset between datasets, regardless of the filter used to define the source list, (3) The decision to use circular or elliptical apertures causes an offset in M* of 0.20 mag, and best-fitting Schechter parameters from total magnitude photometric systems have a flatter faint-end slope than Kron or Petrosian photometry, (4) There is no surface brightness distribution evolution with luminosity for luminous galaxies, but at fainter magnitudes the distribution broadens and the peak surface brightness dims. A Choloniewski function that is modified to account for this surface brightness evolution fits the bivariate-brightness distribution better than an unmodified Choloniewski function, (5) The energy density per unit interval, vf(v) derived using MGC and GAMA samples agrees within 90% confidence intervals, but does not agree with predictions using standard CSFH and IMF models. Possible improvements to the data and alterations to the theory are suggested.

Continuous wave and modelocked femtosecond novel bulk glass lasers operating around 2000 nm

Fusari, Flavio — Fri, 01 Jan 2010 00:00:00 GMT

Abstract: This thesis reports on the development of glass-based femtosecond laser sources around 2 µm wavelength. In order to be able to produce 2 µm radiation the dopants used were trivalent Thulium (Tm³⁺) and trivalent Holmium (Ho³⁺) that could be optically pumped with Ti:Sapphire radiation at 0.8 µm and semiconductor disk lasers (SDL) at 1.2 µm. The samples were produced at Leeds University and polished in-house in bulk form and deployed in free space laser cavities. Tellurite compounds doped with Tm³⁺ produced stable continuous wave 1.94 µm radiation when pumped at 800 nm with a maximum efficiency of 28.4% with respect to the absorbed power and maximum output power around 120 mW when pumped using a Ti:Sapphire operating around 0.8 µm. The radiation was broadly tunable across 130 nm. Tm³⁺-Ho³⁺ doubly doped tellurite samples lased around 2.02 µm with maximum efficiency of 25.9% and with P[subscript(OUT)]=75 mW and a smooth tunability of 125 nm. The fluorogermanate glass doped with Tm³⁺ gave an absorbed to output power efficiency of 50%. The maximum continuous wave output powers obtained were around 190 mW and limited by the available pump power at 0.8 µm. These results together with a very low threshold of 60 mW of incident power were comparable to the crystalline counterparts to this gain medium. The Tm3+ tellurite and the Tm³⁺-Ho³⁺ tellurite compounds were also pumped by an SDL operating at 1215 nm to obtain an indication of the viability of such a pump scheme. The results were a maximum internal slope efficiency of 22.4% with a highest output power of 60 mW. The comparison demonstrated that 1.2 µm pumping was competitive with using 0.8 µm wavelength. The use of semiconductor saturable absorbing mirror (SESAM) technology was used for the modelocking of these lasers. The SESAM was produced in Canada and implanted with As⁺ ions in order to reduce the relaxation time. Trains of transform-limited laser pulses at 222 MHz as short as 410 fs centred at 1.99 µm were produced for the first time with a bulk Tm³⁺:Fluorogermanate glass. The maximum average output power obtained was of 84 mW. The same SESAM deployed on the Tm³⁺-Ho³⁺ Tellurite compounds gave trains of transform-limited pulses as short as 630 fs at 2.01 µm with a repetition rate of 143 MHz and a maximum averaged output power of 43 mW. The regime of propagation obtained was soliton-like and the modelocking was self-starting. The results obtained with bulk glass were very promising and open interesting research pathways within the realm of amorphous bulk gain media.

Plasmonic effects upon optical trapping of metal nanoparticles

Dienerowitz, Maria — Tue, 30 Nov 2010 00:00:00 GMT

Abstract: Optical trapping of metal nanoparticles investigates phenomena at the interface of plasmonics and optical micromanipulation. This thesis combines ideas of optical properties of metals originating from solid state physics with force mechanism resulting from optical trapping. We explore the influence of the particle plasmon resonance of gold and silver nanospheres on their trapping properties. We aspire to predict the force mechanisms of resonant metal particles with sizes in the Mie regime, beyond the Rayleigh limit. Optical trapping of metal nanoparticles is still considered difficult, yet it provides an excellent tool to investigate their plasmonic properties away from any interface and offers opportunities to investigate interaction processes between light and nanoparticles. Due to their intrinsic plasmon resonance, metal nanoparticles show intriguing optical responses upon interaction with laser light. These differ greatly from the well-known bulk properties of the same material. A given metal nanoparticle may either be attracted or repelled by laser light, only depending on the wavelength of the latter. The optical forces acting on the particle depend directly on its polarisability and scattering cross section. These parameters vary drastically around the plasmon resonance and thus not only change the magnitude but also the direction and entire nature of the acting forces. We distinguish between red-detuned and blue-detuned trapping, that is using a trapping wavelength shorter or longer than the plasmon resonance of the particle. So far optical trapping of metal nanoparticles has focussed on a wavelength regime far from the particle’s resonance in the infrared. We experiment with laser wavelengths close to the plasmon resonance and expand the knowledge of metal nanoparticle trapping available to date. Existing theoretical models are put to the test when we compare these with our real experimental situations.

Applications of microfluidic chips in optical manipulation & photoporation

Marchington, Robert F. — Fri, 01 Oct 2010 00:00:00 GMT

Abstract: Integration and miniaturisation in electronics has undoubtedly revolutionised the modern world. In biotechnology, emerging lab-on-a-chip (LOC) methodologies promise all-integrated laboratory processes, to perform complete biochemical or medical synthesis and analysis encapsulated on small microchips. The integration of electrical, optical and physical sensors, and control devices, with fluid handling, is creating a new class of functional chip-based systems. Scaled down onto a chip, reagent and sample consumption is reduced, point-of-care or in-the-field usage is enabled through portability, costs are reduced, automation increases the ease of use, and favourable scaling laws can be exploited, such as improved fluid control. The capacity to manipulate single cells on-chip has applications across the life sciences, in biotechnology, pharmacology, medical diagnostics and drug discovery. This thesis explores multiple applications of optical manipulation within microfluidic chips. Used in combination with microfluidic systems, optics adds powerful functionalities to emerging LOC technologies. These include particle management such as immobilising, sorting, concentrating, and transportation of cell-sized objects, along with sensing, spectroscopic interrogation, and cell treatment. The work in this thesis brings several key applications of optical techniques for manipulating and porating cell-sized microscopic particles to within microfluidic chips. The fields of optical trapping, optical tweezers and optical sorting are reviewed in the context of lab-on-a-chip application, and the physics of the laminar fluid flow exhibited at this size scale is detailed. Microfluidic chip fabrication methods are presented, including a robust method for the introduction of optical fibres for laser beam delivery, which is demonstrated in a dual-beam optical trap chip and in optical chromatography using photonic crystal fibre. The use of a total internal reflection microscope objective lens is utilised in a novel demonstration of propelling particles within fluid flow. The size and refractive index dependency is modelled and experimentally characterised, before presenting continuous passive optical sorting of microparticles based on these intrinsic optical properties, in a microfluidic chip. Finally, a microfluidic system is utilised in the delivery of mammalian cells to a focused femtosecond laser beam for continuous, high throughput photoporation. The optical injection efficiency of inserting a fluorescent dye is determined and the cell viability is evaluated. This could form the basis for ultra-high throughput, efficient transfection of cells, with the advantages of single cell treatment and unrivalled viability using this optical technique.

Optical sorting and photo-transfection of mammalian cells

Mthunzi, Patience — Tue, 30 Nov 2010 00:00:00 GMT

Abstract: Recently, laser light sources of different regimes have emerged as an essential tool in the biophotonics research area. Classic applications include, for example: manipulating single cells and their subcellular organelles, sorting cells in microfluidic channels and the cytoplasmic delivery of both genetic and non-genetic matter of varying sizes into mammalian cells. In this thesis several new findings specifically in the optical cell sorting as well as in the photo-transfection study fields are presented. In my optical cell sorting and guiding investigations, a new technique for enhancing the dielectric contrast of mammalian cells, which is a result of cells naturally engulfing polymer microspheres from their environment, is introduced. I explore how these intracellular dielectric tags influence the scattering and gradient forces upon these cells from an externally applied optical field. I show that intracellular polymer microspheres can serve as highly directional optical scatterers and that the scattering force can enable sorting through axial guiding onto laminin coated glass coverslips upon which the selected cells adhere. Following this, I report on transient photo-transfection of mammalian cells including neuroblastomas (rat/mouse and human), embryonic kidney, Chinese hamster ovary as well as pluripotent stem cells using a tightly focused titanium sapphire femtosecond pulsed laser beam spot. These investigations permitted advanced biological studies in femtosecond laser transfection: firstly, the influence of cell passage number on the transfection efficiency; secondly, the possibility to enhance the transfection efficiency via whole culture treatments of cells thereby, synchronizing them at the mitotic (M phase) as well as the synthesis phases (S phase) of the cell cycle; thirdly, this methodology can activate the up-regulation of the protective heat shock protein 70 (hsp70). Finally, I show that this novel technology can also be used to transfect mouse embryonic stem (mES) cell colonies and the ability of differentiating these cells into the extraembryonic endoderm.

The Solar System in perspective : from debris discs to extrasolar planets

Kains, Noé — Tue, 30 Nov 2010 00:00:00 GMT

Abstract: The last twenty-five years have seen our understanding of the formation and abundance of planets revolutionised, thanks to the first detections of debris discs, and, a decade later, of the first extrasolar planets. Hardly a week now goes by without a planet discovery, and the range of methods used to search for planets has expanded to include techniques that are efficient at detecting different types of planets. By combining the discoveries of the various methods, we therefore have the opportunity to build a picture of planet populations across the Galaxy. In this thesis, I am presenting work done as a basis towards such an effort: first I present work carried out to improve modelling methods for gravitational microlensing events. Since the first microlensing observing campaigns, the amount of data of anomalous events has been increasing ever faster, meaning that the time required to model all observed anomalous events is putting a strain on available human and computational resources. I present work to develop a method to fit anomalous microlensing events automatically and show that it is possible to conduct a thorough and unbiased search of the parameter space, illustrating this by analysing an event from the 2007 observing season. I then discuss the possible models found with this method for this event, and their implication (Kains et al. 2009), and find that this algorithm locates good-fit models in regions of parameters that would have been very unlikely to be found using standard modelling methods. Results indicate that it is necessary to use a full Bayesian approach, in order to include prior information on the parameters. I discuss the analytical priors calculated by Cassan et al. (2009) and suggest a possible form of an automatic fitting algorithm by incorporating these priors in the algorithm used by Kains et al. (2009). Another topic with which this thesis is concerned is the evolution of debris discs around solar-type stars. Late-type stars are expected to be the most numerous host stars of planets detected with the microlensing technique. Understanding how their debris discs evolve equates to understanding the earliest stages of planet formation around these stars, allowing us to truly put our Solar System in perspective. Using the analytical model of Wyatt et al. (2007a), I modelled the evolution of infrared excess flux at 24 and 70 microns using published data of debris discs around solar-type (spectral types F, G and K) stars from the Spitzer Space Telescope. By comparing the results of this study to an analogous study carried out by for A stars by Wyatt et al. (2007b), I find that although best-fit parameters are significantly different for solar-type stars, this may be due to the varying number of inefficient emitters around stars of different spectral types. I suggest that although effective properties are different by an order of magnitude or more, intrinsic properties, while still different, are so by a much smaller factor. These differences may be due to the longer timescales over which solar-type stars evolve, which allow for the formation of larger and stronger planetesimals.

The earliest fragmentation in molecular clouds : and its connection to star formation

Smith, Rowan Johnston — Mon, 21 Jun 2010 00:00:00 GMT

Abstract: Stars are born from dense cores of gas within molecular clouds. The exact nature of the connection between these gas cores and the stars they form is an important issue in the field of star formation. In this thesis I use numerical simulations of molecular clouds to trace the evolution of cores into stars. The CLUMPFIND method, commonly used to identify gas structures is tested. I find that the core boundaries it yields are unreliable, but in spite of this, the same profile is universally found for the mass function. To facilitate a more robust definition of a core, a modified clumpfind algorithm which uses gravitational potential instead of density is introduced. This allows the earliest fragmentation in a simulated molecular cloud to be identified. The first bound cores have a mass function that closely resembles the stellar IMF, but there is a poor correspondence between individual core masses and the stellar masses formed from them. From this, it is postulated that environmental factors play a significant part in a core’s evolution. This is particularly true for massive stars, as massive cores are prone to further fragmentation. In these simulations, massive stars are formed simultaneously with stellar clusters, and thus the evolution of one can affect the other. In particular, the global collapse of the forming cluster aids accretion by the precursors of the massive stars. By tracing the evolution of the massive stars, I find that most of the material accreted by them comes from diffuse gas, rather than from a well-defined stellar core.

One- and two-photon pumped organic semiconductor lasers

Tsiminis, Georgios — Fri, 01 Jan 2010 00:00:00 GMT

Abstract: This thesis describes a number of studies on organic semiconductors focused around using them as gain media for lasers. The photophysical properties of organic semiconductors are studied using a wide range of experimental techniques, allowing the evaluation of new materials and novel excitation schemes for use in organic semiconductor lasers. Polyfluorene is a well-established conjugated polymer laser gain medium and in this thesis its excellent lasing properties are combined with its two photon absorption properties to demonstrate a tunable two-photon pumped solid-state laser based on a commercially available organic semiconductor. A family of bisfluorene dendrimers was studied using a number of photophysical techniques to evaluate their potential as laser materials. Distributed feedback lasers based on one of the dendrimers are demonstrated with lasing thresholds comparable to polyfluorene. The same materials were found to have enhanced two-photon absorption properties in comparison to polyfluorene, leading to the fabrication of tunable two-photon pumped dendrimer lasers. A member of a novel family of star-shaped oligofluorene truxenes was evaluated as a laser gain material and the distributed feedback lasers made from them show some of the lowest lasing thresholds reported for organic semiconductors, partly as a consequence of exceptionally low waveguide losses in comparison to other single-material thin films. Finally, an organic laser dye is blended with a conjugated polymer, where the dye molecules harvest the excitation light of a GaN laser diode and transfer its energy to the polymer molecules. This is the first time such a scheme is used in an organic laser and in combination with a novel surface-emitting distributed Bragg reflector resonator allows the demonstration of a diode-pumped organic laser, a significant step towards simplifying organic lasers.

Thin-film photonic crystal LEDs with enhanced directionality

Bergenek, Krister — Mon, 30 Nov 2009 00:00:00 GMT

Femtosecond cellular transfection using novel laser beam geometries

Tsampoula, Xanthi — Mon, 30 Nov 2009 00:00:00 GMT

Abstract: In this thesis, femtosecond (fs) cellular transfection of Chinese Hamster Ovary (CHO) cells was performed using a tightly focused Gaussian beam. The beam focus was positioned on the cell membrane and three laser doses, each of 40 ms duration, were delivered allowing for the formation of a highly localized pore on the cell membrane. The membrane pore, induced as a result of a multiphoton process known as photoporation, permitted the surrounding DNA to diffuse into the cell cytoplasm. 48 hours after laser irradiation, the viable photoporated cells expressed a red fluorescent protein. The topography of a photoporated cell, targeted with tightly focused fs pulses, was also monitored as a function of the input power using Atomic Force Microscopy. Following this, I generated and implemented a “non-diffracting” quasi-Bessel beam (BB) by means of a conical shaped lens, the axicon, which successfully provided an alternative route for photoporation to the highly divergent Gaussian beam. A comparison was given between the two beam approaches for photoporation. The “non-diffracting” character of the BB resulted in the first successful attempt towards automating optical transfection. This was achieved by using an axicon and a spatial light modulator (SLM) to provide phase modulation on the annular spatial spectrum field of the BB. This approach provided control over the lateral and axial position of the beam with respect to the cell membrane, allowing for point and click photoporation. Successful photoporation of CHO cells was also demonstrated using for the first time an axicon tipped optical fibre. The applicability prospects of this method are significant, ranging from potential endoscopic embodiments of the technique to advanced studies of tissue properties in vitro and in vivo.

Optical trapping: optical interferometric metrology and nanophotonics

Lee, Woei Ming — Fri, 25 Jun 2010 00:00:00 GMT

Abstract: The two main themes in this thesis are the implementation of interference methods with optically trapped particles for measurements of position and optical phase (optical interferometric metrology) and the optical manipulation of nanoparticles for studies in the assembly of nanostructures, nanoscale heating and nonlinear optics (nanophotonics). The first part of the thesis (chapter 1, 2) provides an introductory overview to optical trapping and describes the basic experimental instrument used in the thesis respectively. The second part of the thesis (chapters 3 to 5) investigates the use of optical interferometric patterns of the diffracting light fields from optically trapped microparticles for three types of measurements: calibrating particle positions in an optical trap, determining the stiffness of an optical trap and measuring the change in phase or coherence of a given light field. The third part of the thesis (chapters 6 to 8) studies the interactions between optical traps and nanoparticles in three separate experiments: the optical manipulation of dielectric enhanced semiconductor nanoparticles, heating of optically trapped gold nanoparticles and collective optical response from an ensemble of optically trapped dielectric nanoparticles.

Searching for transiting extra-solar planets at optical and radio wavelengths

Smith, Alexis Michael Sheridan — Mon, 30 Nov 2009 00:00:00 GMT

Abstract: This thesis is concerned with various aspects of the detection and characterisation of transiting extra-solar planets. The noise properties of photometric data from SuperWASP, a wide-field survey instrument designed to detect exoplanets, are investigated. There has been a large shortfall in the number of planets such transit surveys have detected, compared to previous predictions of the planet catch. It has been suggested that correlated, or red, noise in the photometry is responsible for this; here it is confirmed that red noise is present in the SuperWASP photometry, and its effects on planet discovery are quantified. Examples are given of follow-up photometry of candidate transiting planets, confirming that modestly-sized telescopes can rule out some candidates photometrically. A Markov-chain Monte Carlo code is developed to fit transit lightcurves and determine the depth of such lightcurves in different passbands. Tests of this code with transit data of WASP-3 b are reported. The results of a search for additional transiting planets in known transiting planetary systems are presented. SuperWASP photometry of 24 such systems is searched for additional transits. No further planets are discovered, but a strong periodic signal is detected in the photometry of WASP-10. This is ascribed to stellar rotational variation, the period of which is determined to be 11.91 ± 0.05 days. Monte Carlo modelling is performed to quantify the ability of SuperWASP to detect additional transiting planets; it is determined that there is a good (> 50 per cent) chance of detecting additional, Saturn-sized planets in P ~ 10 day orbits. Finally, the first-ever attempt to detect the secondary eclipse of a transiting extra-solar planet at radio wavelengths is made. Although no eclipse is conclusively detected, upper limits to the flux density from HD 189733 b are established, and compared to theoretical predictions of the flux due to electron-cyclotron maser emission.

Magnetothermal properties near quantum criticality in the itinerant metamagnet Sr₃Ru₂O₇

Rost, Andreas W. — Fri, 26 Jun 2009 00:00:00 GMT

Abstract: The search for novel quantum states is a fundamental theme in condensed matter physics. The almost boundless number of possible materials and complexity of the theory of electrons in solids make this both an experimentally and theoretically exciting and challenging research field. Particularly, the concept of quantum criticality resulted in a range of discoveries of novel quantum phases, which can become thermodynamically stable in the vicinity of a second order phase transition at zero temperature due to the existence of quantum critical fluctuations. One of the materials in which a novel quantum phase is believed to form close to a proposed quantum critical point is Sr₃Ru₂O₇. In this quasi-two-dimensional metal, the critical end point of a line of metamagnetic first order phase transitions can be suppressed towards zero temperature, theoretically leading to a quantum critical end point. Before reaching absolute zero, one experimentally observes the formation of an anomalous phase region, which has unusual ‘nematic-like’ transport properties. In this thesis magnetocaloric effect and specific heat measurements are used to systematically study the entropy of Sr₃Ru₂O₇ as a function of both magnetic field and temperature. It is shown that the boundaries of the anomalous phase region are consistent with true thermodynamic equilibrium phase transitions, separating the novel quantum phase from the surrounding ‘normal’ states. The anomalous phase is found to have a higher entropy than the low and high field states as well as a temperature dependence of the specific heat which deviates from standard Fermi liquid predictions. Furthermore, it is shown that the entropy in the surrounding ‘normal’ states increases significantly towards the metamagnetic region. In combination with data from other experiments it is concluded that these changes in entropy are most likely caused by many body effects related to the underlying quantum phase transition.

Measurements of exciton diffusion in conjugated polymers

Shaw, Paul E. — Mon, 30 Nov 2009 00:00:00 GMT

Abstract: The exciton diffusion length, which is the distance an exciton can diffuse in its lifetime, is an important parameter that has a critical impact on the operation of many organic optoelectronic devices, including organic solar cells, light emitting diodes and lasers. Knowledge of the exciton diffusion length can be a powerful aid for the design and optimisation of these devices. This thesis details the development of techniques based on time-resolved fluorescence for measuring the exciton diffusion in organic semiconductors. Two main methods were used to investigate exciton diffusion in the conjugated polymers P3HT, MEH-PPV and F8BT: the surface quenching technique and exciton-exciton annihilation. In particular, the surface quenching technique was adapted to avoid some of the potential pitfalls that have plagued earlier measurements. Using a titania quencher, measurements were performed using the surface quenching technique and fitted with an exciton diffusion model, allowing the calculation of the exciton diffusion length. Results from measurements of the exciton-exciton annihilation rate, which is a diffusion controlled process, where in good agreement with those from surface quenching, confirming the robustness of this twofold approach. A novel method for the control of the β-phase conformation in PFO films was used to produce films containing varying concentrations of β-phase. Exciton-exciton annihilation was used to investigate exciton diffusion in these films, revealing a gradual rise with increasing β-phase fraction due to improved interconnectivity. This work demonstrates how simple processing techniques can be used to control both film morphology and the exciton diffusion. The thickness dependence of the photoluminescence lifetime in conjugated polymers is a phenomenon that has so far received little attention and, thus, remained unexplained. This study demonstrates that it is not due to exciton quenching by external factors, but can be explained by a change in the morphology with decreasing film thickness.

Itinerant metamagnetism and magnetic inhomogeneity: a magnetic analogue of the superconducting Fulde-Ferrell-Larkin-Ovchinnikov phase in Sr₃Ru₂O₇

Berridge, Andrew McConnell — Mon, 30 Nov 2009 00:00:00 GMT

Abstract: The formation of magnetic order in solids is a complex and subtle issue. There are a wide range of different types of magnetisation, all of which may be favoured under different circumstances. In this thesis we consider a novel combination of ideas where the formation of spatially modulated magnetisation is linked to a metamagnetic transition. In this we are inspired by a general principle of modulated phases intervening as intermediate states in phase transitions. In particular we draw analogies with the Fulde-Ferrell-Larkin-Ovchinnikov state of spatially modulated superconductivity. We study a mean-field theory for itinerant magnetism where the crystal lattice drives the formation of a rich phase diagram. A peak in the electronic density of states due to a van Hove singularity creates ferromagnetism and a metamagnetic transition. Furthermore we find that a modulated magnetic phase - a spin-spiral, becomes favoured along the metamagnetic transition line. The appearance of this phase causes the metamagnetic transition to bifurcate to enclose the modulated region. The topology of this reconstructed phase diagram shows remarkable similarity to that observed in experiments on Sr₃Ru₂O₇. This material shows a metamagnetic transition which can be tuned by field angle towards zero temperature. Before this point is reached a new phase with high and anisotropic resistivity appears. We believe that this anomalous phase can be explained by the formation of a phase of modulated magnetisation caused by a peak in the electronic density of states. This mechanism may also apply in a range of other materials as it is driven by rather generic features of the bandstructure.

Warping, dust settling and dynamics of protoplanetary disks

O'Sullivan, Mark George — Tue, 01 Jan 2008 00:00:00 GMT

Abstract: The research presented in this thesis investigates several aspects of the evolutionary processes of T Tauri stars and their accompanying circumstellar disks. The versatile Monte Carlo radiation transfer technique, with several modifications and extensions, is used throughout to study the structure and constitution of both the circumstellar disk at large and the changeable and dynamic inner disk regions. The photopolarimetric variability of AA Tau in the Taurus star forming region is modelled in a fully 3D manner. I find that a magnetospherically induced warp in the accretion disk at roughly the stellar co-rotation radius occults the star and reproduces both the observed period and duration and the required brightness and polarisation variations. The model SEDs allow estimates of the disk mass, radial extent and large- scale density structure. Using a modified SPH code we find the interaction of a 5.2kG stellar magnetic field inclined at 30° to the rotation axis with the disk, is capable of generating a warp of the size and shape needed to reproduce the observed variations. Modified Monte Carlo models capable of incorporating any number of dust particle grain sizes distributed throughout the disk in vertical and radial distributions, in a fully 3D manner are presented. This versatile tool allows the investigation of evolutionary processes such as dust settling and grain growth predicted to occur in T Tauri sources as they age. A Mie Scattering code was also adapted and incorporated into the models allowing us to determine optical properties for dust grains and distributions of any size. I present model SEDs fitting the latest publicly available IR data for a number of T Tauri sources and reproduce the observational effects of dust grain growth and settling with a high degree of success. The fits are by no means unique and the structural parameters required to produce them are quite uncertain but it is possible to determine useful information on the larger scale structure and bulk constituents of these disks. A fully 3D non-LTE radiative transfer code using CO line emissions as a tracer of the disk dynamics and able to simulate any disk structure or geometry, either analytical or imported from a hydrodynamic simulation, is presented. Signatures attributed to the disk dynamics and spiral density structure derived from hydrodynamic simulations of massive disks are investigated and resolved. Line profiles and contour maps of the velocity of the emitting material are generated and compared with observations.

Yb-doped femtosecond lasers and their frequency doubling

Sarmani, Abdul Rahman — Tue, 01 Jan 2008 00:00:00 GMT

Abstract: Ultralow threshold, compact and highly efficient femtosecond lasers based on Yb³⁺ -doped potassium yttrium tungstate (Yb:KYW) and Yb³⁺ -doped vanadium yttrium oxide (Yb:YVO 4 ) have been demonstrated within this PhD-research project. For a continuous wave unmode-locked Yb:KYW laser a threshold as low as 101 mW was obtained with a slope efficiency of 74 %. By employing a single prism for dispersion control, the laser was tunable between 1012 nm to 1069 nm. When operated in the mode-locked regime, this laser produced transform-limited pulses having durations of 210 fs at a central wavelength of 1044 nm. Stable mode locking was observed for an optimised incident pulse fluence on the SESAM between 140 μJ/cm² to 160 μJ/cm² which was 2-3 times higher than the designed energy pulse fluence of the SESAM (70 μJ/cm² ). The employment of several combinations of chirped mirror designs for control of intracavity group velocity dispersion led to excellent results. The threshold for mode locking was satisfied for a pump power of 255 mW where the slope efficiency was measured to be 62 %. This is the most efficient SESAM-assisted femtosecond laser yet reported and the highest optical-to-optical efficiency of 37 % is exceptional. Transform- limited pulses with durations as short as 90 fs were produced in a spectral region centred on 1052 nm. The success of this research thus represents a good foundation on which to design and build more compact configurations that will incorporate just one chirped mirror for dispersion compensation. A relatively high nonlinear refractive index, n₂ , of 15 x 10⁻¹⁶ cm² /W was measured in Yb:YVO 4 and this affords particular potential for this candidate material in Kerr-lens mode locking. In fact, for operation in the femtosecond domain, the threshold power was 190 mW with a slope efficiency of 26 % and near-transform-limited pulses as short as 61 fs were generated at a centre wavelength of 1050 nm. The main objectives in developing this type of laser relate to a demonstration of high peak power operation in thin disc laser configurations. The deployment of a diode-pumped Yb:KYW femtosecond laser as a pump source for frequency doubling in a periodically-poled LiTaO₃ crystal was realised. The maximum realized output power of 150 mW corresponded to an impressive second harmonic conversion efficiency of 43 %. 225-fs duration green pulses (centred at 525 nm) were generated under the condition of strong focusing in the nonlinear crystal.

Optical micromanipulation of aerosols

Summers, Michael David — Thu, 01 Jan 2009 00:00:00 GMT

Abstract: This thesis describes my work on the development of optical trapping techniques for manipulating airborne particles. Although many of the basic principles are similar to those used in more conventional colloidal experiments, there are many differences which have been described and investigated in detail in this work. Basic characterisation measurements are made, such as axial Q and sample size selectivity, for a number of sample liquids in a basic optical tweezers setup. Performance at 532nm and 1064nm were compared and shown to be very similar, despite increased absorption in the infrared. A successful method was developed for the optical trapping of solid aerosol particles, allowing a direct comparison between similar particles suspended in both the gas and liquid phase. A single beam levitation trap was developed for transporting liquid aerosols to allow multiple chemical measurements to be made on a single droplet. Performance between Gaussian and Bessel beams was compared for various liquids, with guiding distances of several millimetres being achieved with the Bessel beam geometry. An experiment to demonstrate lasing within an optically tweezed droplet was also performed and spectra were taken. Although strong resonance modes were evident, the data was not conclusive. However, it is likely that a redesign of the experiment would be successful. These techniques have extended research capabilities in the areas of both optical trapping and atmospheric chemistry, allowing the detailed study of single aerosol particles in the 1-10 μm range.

A study of superconductivity in single crystals and thin films using muon-spin rotation and neutron scattering

Heron, David Owen Goudie — Thu, 01 Jan 2009 00:00:00 GMT

Abstract: The archetypal high temperature superconductor Bi₂Sr₂CaCu₂O[subscript[8+δ]] has been extensively investigated. However, until now, little has been known about the behaviour of the magnetic vortices inside the Vortex Glass and liquid state. µSR measurements have shown a negative skewness for the field probability distributions in these regimes. Such a negative skewness has only recently been explained as being a direct consequence of three-body correlations between vortices in a similar layered superconductor. With a new understanding and knowledge of the physics of these systems, it is instructive to re-visit the superconductor Bi₂Sr₂CaCu₂O[subscript[8+δ]] to explain the evolution of these three-body correlations occurring here. Comparing this with the ion-irradiated superconductors (of the same Bi₂Sr₂CaCu₂O[subscript[8+δ]] material), allows one to observe how three-body correlations between vortices evolve differently to that in the pristine material. Moreover, in the region of the macroscopic irreversibility line, entropically driven disorder exists below the matching field B[subscript[ϕ]] , whilst there is the appearance of relatively straight vortex lines at fields above B[subscript[ϕ]] . Such phenomena suggest a significant di fference in the evolution of three-body correlations compared with the unirradiated material. There has been much work conducted on the interplay between superconductivity and magnetism in materials of reduced dimensions. Work presented here on the ferromagnet/superconductor trilayer system (Permalloy/Nb/Permalloy) has shown a novel magnetic profile at the interface between the ferromagnetic and superconducting boundary, where, contrary to what is expected, the magnetism appears to be significantly suppressed at the interface before increasing towards the centre of the Nb layer.

Procrustean entanglement concentration, weak measurements and optimized state preparation for continuous-variable quantum optics

Menzies, David — Fri, 26 Jun 2009 00:00:00 GMT

Abstract: In this thesis, we are concerned with continuous-variable quantum optical state engineering protocols. Such protocols are designed to repair or enhance the nonclassical features of a given state. In particular, we build a weak measurement model of Gaussian entanglement concentration of the two mode squeezed vacuum state. This model allows the simultaneous description of all possible ancilla system variations. In addition, it provides an explanation of the Gaussian-preserving property of these protocols while providing a success criterion which links all of the degrees of freedom on the ancilla. Following this, we demonstrate the wider application of weak measurements to quantum optical state engineering by showing that they allow probabilistic noiseless amplifi cation of photon number. We then establish a connection between weak measurements and entanglement concentration as a fundamental result of weak measurements on entangled probes. After this, we explore the trade-off between Gaussian and non-Gaussian operations in the preparation of non-Gaussian pure states. In particular, we suggest that an operational cost for an arbitrary non-Gaussian pure state is the largest Fock state required for its approximate preparation. We consider the extent to which this non-Gaussian operational cost can be reduced by applying unitary Gaussian operations. This method relies on the identification of a minimal core state for any target non-Gaussian pure state.

Cross-phase modulation in rubidium-87

Sinclair, Gary F. — Fri, 26 Jun 2009 00:00:00 GMT

Abstract: This thesis explores the theoretical foundations of cross-phase modulation (XPM) between optical fields in the N-configuration atom. This is the process by which the refractive index experienced by one field can be modulated by controlling the intensity of another. The electro-optical version of this effect was first discovered by John Kerr in 1875 and found applications in photonics as a means of very rapidly modulating the phase and intensity of electromagnetic fields. Due to recent advances in experimental techniques there has been growing interest in generating nonlinear optical interactions in coherently prepared atomic ensembles. The use of coherently prepared media brings the possibility of achieving a much larger cross-phase modulation than is possible using classical materials. This is particularly useful when trying to create large optical nonlinearities between low-intensity electromagnetic fields. Much of the current research into cross-phase modulation is directed towards realising potential applications in the emerging field of quantum information processing. Above all, the possibility of constructing an all-optical quantum computer has been at the heart of much research and controversy in the field. In this thesis the theory of steady-state, transient and pulsed cross-phase modulation is developed. Moreover, care has been taken to relate all research back to experimentally feasible situations. As such, the relevance of the theory is justified by consideration of the situation present in rubidium-87. Due to the close relationship between XPM in the N-configuration atom and electromagnetically induced transparency in the Lambda-atom, many similarities and insights act as link between these two fields. Indeed, it is frequently demonstrated that the key to understanding the various properties of XPM in the N-configuration atom is by comparison with the situation in the corresponding Lambda-atom equivalent.

Star formation across the galaxy : observations and modelling of the spectral energy distributions of young stars

Robitaille, Thomas P. — Fri, 26 Jun 2009 00:00:00 GMT

Abstract: In the last few decades, the emergence of large-scale infrared surveys has led to a revolution in the study of star formation. In particular, NASA’s Spitzer Space Telescope has recently carried out mid- and far-infrared observations of numerous star formation regions with unprecedented resolution and sensitivity, and has uncovered thousands of forming stars. In combination with present and future large-scale near-infrared and sub-mm surveys, spectral energy distributions from near-infrared to mm wavelengths will be available for these thousands of young stars. Never before has there been such a wealth of multi-wavelength data for so many young stars. Traditional techniques for studying the physical properties of young stars through their spectral energy distributions have usually focused either on the analysis of many sources using simple observational diagnostics such as colours or spectral indices, or on the analysis of a few sources through the detailed modelling of their full spectral energy distributions. The work presented in the first part of this thesis aims to bridge these two techniques through the efficient modelling of the spectral energy distributions of many young stars. In particular, the technique developed for this work makes it straightforward to find out how well different physical parameters are constrained, whether any parameters are degenerate, and whether additional data would resolve the degeneracies. In the second part of this thesis, a census of intrinsically red sources observed by Spitzer in the Galactic plane is presented, including a catalogue of over 11,000 likely young stellar objects. This sample of sources is the largest uniformly selected sample of young stars to date, and effectively provides a map of the sites of star formation in the mid-plane of the Milky-Way. In parallel, this census has uncovered over 7,000 candidate asymptotic giant branch stars, of which over 1,000 are variable at 4.5 or 8.0 microns.

An embedded control and display system for a laser-based mid-infrared hyperspectral imager

Ross, Mark — Mon, 01 Jun 2009 00:00:00 GMT

Abstract: Back-scatter absorption gas imaging (BAGI) is a powerful laser-based detection technique whereby the strong spectroscopic absorption features in the gaseous species of interest are exploited in order to provide an image of the otherwise invisible (to the naked eye) gas. Such a device had been under development at the University of St. Andrews for the past three years. This thesis is concerned with the work carried out in the design, construction and testing of an electronic supervisory system for such a device to both control the electro-mechanical image acquisition hardware and display the image data upon an LCD module via an on-board video driver. Two different LCD display technologies, super twisted nematic (STN) and thin film transistor (TFT), have been demonstrated and their suitability for use in this system is assessed. It was found that the refresh rate and contrast ratio of the TFT display was greatly superior to that of the STN. Frame rates in excess of 10 fps have been demonstrated with this module. In addition to the scanner, a laser management system (LMS) was designed, constructed and tested to control the laser illumination system, which is based on an intracavity optical parametric oscillator (ICOPO). This involved the development of a dual-channel PID temperature controller to stabilise various optical components located within the ICOPO illumination source, a digitally-controlled constant current source to drive the pump diode laser and a digitally controlled system for an associated Q-switch driver module. The LMS was developed as part of the miniaturisation process and resulted in one dedicated instrument replacing six individual devices required in the laboratory demonstrator. The BAGI device has now been commercialised with elements of this research program being part of the overall instrument.

Optical micromanipulation using dispersion-compensated and phase-shaped ultrashort pulsed lasers

Shane, Janelle — Mon, 30 Nov 2009 00:00:00 GMT

Abstract: Ultrashort pulsed lasers offer high peak powers at low average powers, making them ideal for maximising the efficiency of nonlinear excitation. Their broad bandwidths make it possible to tailor the pulse's temporal profile for advanced control of multiphoton excitation, techniques known as pulse shaping. This thesis represents the first combination of ultrashort pulse shaping with optical trapping and axicon dispersion compensation. We construct an optical trapping system which incorporates a 12fs duration pulsed laser, the shortest duration used to date in optical trapping. To achieve 12fs pulse durations at the sample, we must first eliminate temporal dispersion, which stretches and distorts pulses as they travel through microscope systems. We use the Multiphoton Intrapulse Interference Phase Scan (MIIPS) method to measure and compensate all orders of dispersion in our optical trapping system, verifying 12-13fs pulses at the sample. We use the dispersion-compensated optical trapping system to investigate the effects of pulse duration on optical trapping. Our theoretical arguments show that trap stiffness is independent of pulse duration. For experimental verification, we measure the trap stiffness of trapped 780nm silica spheres with back focal plane interferometry as we change pulse duration by more than an order of magnitude using quadratic pulse shaping. We find the trap stiffness unchanged within 9%. We also use quadratic pulse shaping to control two-photon fluorescence in optically trapped fluorescent polymer spheres. Next, we demonstrate two methods for producing selective two-photon excitation in trapped particles: amplitude shaping and 3rd order pulse shaping. Finally, we compensate dispersion in an axicon system, producing a non-diffracting ultrashort Bessel beam with controllable dispersion. This forms the basis for ongoing experiments exploring ultrashort Bessel beams in cellular transfection (photoporation), and examining the spatial profile of the Bessel beam as a function of the pulse's temporal profile.

Measurement and application of optical nonlinearities in indium phosphide, cadmium mercury telluride and photonic crystal fibres

Sloanes, Trefor J. — Mon, 30 Nov 2009 00:00:00 GMT

Abstract: The two-photon absorption (TPA) coefficient is measured in indium phosphide (InP) using femtosecond pulses to be 45cm/GW at 1.32μm. Nanosecond pulses are subsequently used to find the free-carrier refractive index cross-section, σ_r, and the free-carrier absorption coefficient, σ_fca. The quantity βσ_r is measured to be -113x10⁻²ºcm⁴/GW at 1.064μm and -84x10⁻²ºcm⁴/GW at 1.534μm. At 1.064μm, with β assumed to be 22cm/GW, the value suggested by theory, σ_r is -5.1x10⁻²ºcm³. Similarly, at 1.534μm, assuming β to be 20cm/GW gives a σ_r value of -4.1x10⁻²ºcm³. Due to refraction affecting the measurements of σ_fca, only an upper limit of 1x10⁻¹⁵cm² can be put on its value. The free-carrier experiments are repeated on two samples of cadmium mercury telluride (CMT) having bandgaps of 0.89eV and 0.82eV. For the first sample, β_σr is measured to be -148x10⁻²ºcm⁴/GW. Assuming β to be 89cm/GW gives a σ_r value of -1.7x10⁻²ºcm³ whilst σ_fca is found to be at most 3x10⁻¹⁵cm². Significant linear absorption occurs in the second sample which generates a large free-carrier population. It is shown that this significantly enhances the nonlinearities. Finally, the results of the work are tested by modelling a nonlinear transmission experiment, and the results found in this work give a closer fit to experimental results than the result of theory. Four-wave mixing (FWM) in a photonic crystal fibre is exploited to create a high output power optical parametric amplifier (OPA). To optimise the OPA conversion efficiency, the fibre length has to be increased to 150m, well beyond the walk-off distance between the pump and signal/idler. In this regime, the Raman process can take over from the FWM process and lead to supercontinuum generation. The OPA exhibits up to 40% conversion efficiency, with the idler (0.9μm) and the signal (1.3μm) having a combined output power of over 1.5W.

Studies of particle and atom manipulation using free space light beams and photonic crystal fibres

Gherardi, David Mark — Fri, 26 Jun 2009 00:00:00 GMT

Abstract: Light can exert optical forces on matter. In the macroscopic world these forces are minuscule, but on the microscopic or atomic scale, these forces are large enough to trap and manipulate particles. They may even be used to cool atoms to a fraction of a degree above absolute zero. This thesis details a number of experiments concerned with the optical manipulation of atoms and micron-size particles using free space light beams and photonic crystal fibres. Two atom guiding experiments are described. In the first experiment, a spatial light modulator is used to generate higher blue-detuned azimuthal Laguerre-Gaussian LG) beams, which are annular beams with a hollow core. These LG beams are then used to guide laser cooled rubidium-85 atoms within the dark core over a distance of 30 mm. The second atom guiding experiment involves attempting to guide laser cooled and thermal rubidium atoms through a hollow-core photonic crystal fibre using red-detuned light. Hollow-core photonic crystal fibres are fibres that are able to guide light with low attenuation within a hollow core. For this experiment a hot wire detection system was designed, along with a number of complex vacuum systems. The first dual-beam fibre trap for micron-size particles constructed using endlessly single-mode photonic crystal fibre (ESM-PCF) is described. The characteristics of dual-beam fibre traps are governed by the fibres used. As ESM-PCF has considerably different properties in comparison to conventional single- or multimode fibres, this dual beam ESM-PCF trap exhibits some novel characteristics. I show that the dual beam ESM-PCF trap can form trapping, repulsive and line potentials; an interference-free ‘white light’ trap; and a dual-wavelength optical conveyor belt.

The environments in which stars and circumstellar discs form

Poulton, Christopher John — Tue, 01 Jan 2008 00:00:00 GMT

Abstract: In this thesis, images of a debris disc are used to examine the evidence for the presence of a Neptune-like planet around ε Eridani and detections of protoplanetary discs are used to investigate the evidence for star and future planet formation. A χ² analysis of the movement of clumps in the ε Eridani debris disc is presented using 850 μm SCUBA data taken over a 4 year period and compared with results from simulated data. A rotation is detected at the 2σ level and is faster than the Keplerian rate, consistent with theoretical models in which dust trapped in mean motion resonances tracks a planet orbiting the star at ≈26 AU. Future observations that could be taken with SCUBA-2 are also simulated and demonstrate that the true rotation rate cannot be recovered without the identification of the background sources aligned with the clumpy debris disc. Near and mid infrared observations are used to perform a survey of YSOs in the Rosette Molecular Cloud. Although triggering by compression of the molecular cloud by the expanding HII region at the centre of the Rosette Nebula is a possible origin for some of the recent star formation, the majority of the active star formation is occurring in already dense regions of the cloud not compressed by the expansion of the HII region. Mid-infrared data for W4 and SCUBA data for the star forming region AFGL 333 are also presented. A survey of YSOs reveals that whilst some young sources are coincident with the W4 loop, consistent with a scenario of triggered star formation in a swept-up shell, several young sources are found to be forming outside of this ring. The dust temperature and mass of AFGL 333 are estimated and the result implies a star formation efficiency of ~4% in the W4 loop.

Microscopic applications of holographic beam shaping and studies of optically trapped aerosols

Burnham, Daniel R. — Wed, 24 Jun 2009 00:00:00 GMT

Abstract: This thesis has two themes. Firstly, it concerns the original application of holographic beam shaping, employed through the methods associated with optical manipulation, to three microscopic fields of research. Secondly, it studies the optical trapping of aerosol droplets through experimentation and computational modelling. The aims are to not only provide an account of the work carried out but also a base for future researchers and students. Chapter 1 provides an introduction to the field of optical manipulation and the relevance of my studies. Chapter 2 outlines the construction of an optical tweezers which is the basis of advanced experimental work described in later chapters. It also overviews how optical tweezers operate and are quantified. In chapter 3 I describe how beam shaping is implemented for my investigations with a spatial light modulator and phase-only holograms. I detail the algorithms and software written before discussing their performance and finally the optimisation of the apparatus. Chapter 4 describes three original applications of beam shaping, including the trapping and coagulation of multiple aerosols, the manipulation of filamentous fungi hyphal tips and novel digital microfluidic operations using thermocapillary forces. I also lay down preliminary results for observing orbital angular acceleration using beams carrying orbital angular momentum. To study single optically trapped aerosols I use two methods. Firstly, their Brownian motion is investigated through sub diffraction limit position detection. Unique results in optical tweezers are shown with liquid droplets behaving as under-damped Brownian oscillators. Through these studies I demonstrate a new technique for sizing trapped aerosols, with significant advantages over current methods. I also show that the droplets can be be parametrically excited which can result in trap failure. Secondly, in chapter 6, I use a theoretical model to describe the forces imparted to a trapped droplet. I extend current theories to include the effects of a three medium focal region to accurately describe airborne optical traps. The work qualitatively explains the phenomena observed experimentally. The work contained here leaves much scope for future investigations, for which I provide an overview in chapter 7.

Free space optical interconnects for speckled computing

Reardon, Christopher P. — Fri, 26 Jun 2009 00:00:00 GMT

Abstract: The aim of this project was to produce an integrate-able free space optical transceiver for Specks. Specks are tiny computing units that together can form a powerful network called a SpeckNet. The SpeckNet platform is developed by the SpeckNet consortium, which consists of five Scottish Universities and combines computer science, electrical engineering and digital signal processing groups. The principal goal of creating an optical transceiver was achieved by integrating in-house fabricated VCSELs (with lasing thresholds below 400 uA) and custom designed detectors on the SpeckNet platform. The transceiver has a very low power consumption (approximately 100 uW), which removes the need for synchronous communication through the SpeckNet thus making the network more efficient. I describe both static and dynamic beam control techniques. For static control, I used micro-lenses. I fabricated the lenses by greyscale electron beam lithography and integrated them directly on VCSEL arrays. I achieved a steering angle of 10 degrees with this design. I also looked at integrated gratings etched straight into a VCSEL and observed beam steering with an efficiency of 60% For dynamic control, I implemented a liquid crystal (LC) design. I built a LC cell with 30 individually controlled pixels, but I only achieved a steering angle of 1 degree. Furthermore, I investigated two different techniques for achieving beam steering by interference, using coupled VCSELs (a phased array approach). Firstly, using photonic crystals etched into the surface of the VCSEL, I built coupled laser cavities. Secondly, I designed and built bow-tie type VCSELs that were optically coupled but electrically isolated. These designs work by differential current injection causing an interference effect in the VCSELs far field. This technique is the first stepping stone towards realising a phased optical array. Finally, I considered signal detection. Using the same VCSEL material, I built a resonant-cavity detector. This detector had a better background rejection ratio than commercially available silicon devices.

The influence of cation doping on the electronic properties of Sr₃Ru₂O₇

Farrell, Jason — Thu, 27 Nov 2008 00:00:00 GMT

Abstract: Sr₃Ru₂O₇ is a quasi-two-dimensional metal and has a paramagnetic ground state that is heavily renormalised by electron-electron correlations and magnetic exchange interactions. Inextricably linked to this renormalisation is the metamagnetism of Sr₃Ru₂O₇ - a rapid rise in uniform magnetisation over a narrow range of applied magnetic field. Knowledge of the zero-field physics is essential to any description of the metamagnetism. Light may be shed on the enigmatic ground state of Sr₃Ru₂O₇ by doping the crystal lattice with foreign cations: this is the primary purpose of the original research referred to in this thesis, in which studies of some of the electronic properties of crystals of cation-doped Sr₃Ru₂O₇ are reported. Single crystals of Sr₃(Ru[subscript(1-x)]Ti[subscript(x)])₂O₇ and Sr₃(Ru[subscript(1-x)]Cr[subscript(x)])₂O₇ have been synthesised in an image furnace and some of the properties of these crystals have been measured. Evidence that indicates the emergence of a spin density wave as a function of Ti-doping in Sr₃(Ru[subscript(1-x)]Ti[subscript(x)])₂O₇ is presented. Time-dependent magnetic irreversibility has been observed in samples of Sr₃(Ru[subscript(1-x)]Cr[subscript(x)])₂O₇, thus hinting at the involvement of the RKKY mechanism in these materials. Regarding cation doping out of the conducting RuO₂ planes, samples of (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ have been grown and investigated. Both the Sommerfeld coefficient and the Fermi liquid A coefficient of (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ are found to decrease as a function of y (0 ≤ y ≤ 0.02); these observations point towards a reduction in the thermodynamic mass of the Landau quasiparticles. Results from magnetoresistance and magnetisation measurements indicate that the metamagnetism of the (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ series probably cannot be explained by a rigid band-shift model. Also, some aspects of these data imply that the metamagnetism cannot be fully accounted for by a spin fluctuation extension to the Ginzburg-Landau theory of uniform magnetisation.

The de Haas van Alphen effect near a quantum critical end point in Sr₃Ru₂O₇

Mercure, Jean-Francois — Thu, 27 Nov 2008 00:00:00 GMT

Abstract: Highly correlated electron materials are systems in which many new states of matter can emerge. A particular situation which favours the formation of exotic phases of the electron liquid in complex materials is that where a quantum critical point (QCP) is present in the phase diagram. Neighbouring regions in parameter space reveal unusual physical properties, described as non-Fermi liquid behaviour. One of the important problems in quantum criticality is to find out how the Fermi surface (FS) of a material evolves near a QCP. The traditional method for studying the FS of materials is the de Haas van Alphen effect (dHvA). A quantum critical end point (QCEP) has been reported in the highly correlated metal Sr₃Ru₂O₇, which is tuned using a magnetic field high enough to perform the dHvA experiment. It moreover features a new emergent phase in the vicinity of the QCEP, a nematic type of electron ordering. The subject of this thesis is the study of the FS of Sr₃Ru₂O₇ using the dHvA effect. Three aspects were explored. The first was the determination of the FS at fields both above and below that where the QCEP arises. The second was the search for quantum oscillations inside the nematic phase. The third was a reinvestigation of the behaviour of the quasiparticle effective masses near the FS. In collaboration with angle resolved photoemission spectroscopy experimentalists, a complete robust model for the FS of Sr₃Ru₂O₇ at zero fields was determined. Moreover, the new measurements of the quasiparticle masses revealed that no mass enhancements exist anywhere around the QCEP, in contradiction with previous specific heat data and measurements of the A coefficient of the power law of the resistivity. Finally, we report dHvA oscillations inside the nematic phase, and the temperature dependence of their amplitude suggests strongly that the carriers consist of Landau quasiparticles.

Dendrimer light-emitting diodes

Stevenson, Stuart G. — Fri, 28 Nov 2008 00:00:00 GMT

Abstract: The electronics industry today is one that stands as a multi-billion dollar industry that is increasingly incorporating more and more products that have ever escalating applications in our everyday life. One of the main sectors of this industry, and one that is likely to continue expanding for a considerable number of years are flat-panel displays. Traditionally, the displays market has been dominated by cathode ray tube (CRT) and liquid crystal displays (LCDs) display types. The drawback of such display displays is that they can be bulky, heavy and/or expensive and so there is considerable room for an alternative and superior technology. One possibility is organic semiconductor displays where light-emitting molecules can be dissolved in common solvents before being inkjet printed, spin-coated or even painted onto any surface giving the benefits of simple and cost effective processing. Organic light-emitting diodes (OLEDs) have recently become ever more evident as a major display type. This thesis focuses on the advancement of light-emitting dendrimers towards flat-panel display applications. The particular interest in dendrimers arises because it has been found they are capable of giving solution-processed phosphorescent devices with high efficiency. Throughout the thesis the benefits of the dendrimer concept are repeatedly shown revealing why this could become the ideal organic material for display applications. The thesis introduces various techniques of electroluminescence and photoluminescence measurements before applying such methods to study a large number of light-emitting dendrimers in order to explore the role of intermolecular interactions, how they are related to molecular structure, and how this determines photophysical and charge transporting properties of the dendrimers. By such studies a number of highly efficient solution-processed phosphorescent light-emitting dendrimers have been identified while the efficiency of devices made from these dendrimers has been improved. This has been demonstrated in each of the three primary display colours of red, green and blue. The work detailed thus brings closer the prospect of dendrimer light-emitting diodes being the future flat-panel display type of choice.

Novel semiconductor based light sources

McRobbie, Andrew Douglas — Mon, 01 Jun 2009 00:00:00 GMT

Abstract: The research described in this thesis relates to the design, fabrication and testing of novel semiconductor-based light sources that have been designed for the generation of infra-red light. The thesis is formatted to account for two distinct components of my work, where the first part concerns sources producing coherent light by direct laser emission, notably, ultrashort-pulse quantum-dot lasers. These types of lasers continue to show considerable promise as efficient, compact sources of ultrashort pulses with durations of hundreds of femtoseconds, while giving rise to unique and interesting electronic properties such as low lasing thresholds through the quantum nature of their density of states. At the outset a study of the most relevant aspects of the lasing dynamics of an optically pumped quantum-dot laser is outlined. Pumping of the device with intense discrete optical pulses leads to output from multiple electronic states, each having a characteristic wavelength and temporal properties. I show that pulses produced by excited-state emission have shorter durations (24 ps) and arrive earlier in time than those due to transitions from the ground state, which themselves have durations of around 180 ps. Investigations are then made on two different mode-locked quantum-dot laser systems. One is an all-quantum-dot external-cavity laser that is mode locked using a quantum-dot SESAM device at a repetition frequency of 860 MHz with output power approaching 20 mW. This is followed by a study of a monolithic two-section quantum-dot laser that is mode locked stably in a wide temperature range of 20°C to 70°C. The excellent performance characteristics presented serve to demonstrate both the versatility of quantum-dot material as components in mode-locked laser systems and the temperature stability of such laser devices. The second part of the thesis relates to structures that are designed to take advantage of nonlinear frequency conversion in GaAs-based semiconductors. This material system possesses a nonlinear coefficient of ~170 pm/V and is transparent from around 0.9 μm through to 17 μm, making it attractive for the realisation of a new class of efficient, integrable, quasi-phase-matched, optical parametric oscillator devices. Initially, ion implantation is utilised as a vector to create a periodically-switched nonlinear ridge waveguided device. The observation is made that in the course of implantation the transmissive properties of the device are severely degraded. Unfortunately, the high losses incurred, which reached 250 dB/cm, could not be removed without also destroying the modulation in nonlinearity. During the course of this investigation, significant technological advances were made in the production of orientation-patterned GaAs structures. By recognising the elegance and potential of this new orientation-patterned (OP) methodology, a study of its implications and applicability in the context of my project is initiated.

Photonic crystals as functional mirrors for semiconductor lasers

Moore, Stephen A. — Sun, 30 Nov 2008 00:00:00 GMT

Abstract: In recent years, interest has grown in the research fields of semiconductor lasers and photonic crystals. This thesis looks at integrating photonic crystals into existing semiconductor laser technology to act as functional laser mirrors. The majority of the research is conducted on a quantum-dot material system. The surface recombination velocity of a GaAs based quantum-dot material is shown to be a similar value to InP material. This allows the creation of fine photonic crystal structures in the laser design without high threshold current penalties. The spectral reflection properties of a one dimensional photonic crystal is studied and found to be an unsuitable candidate for a stand-alone laser mirror, due to its low reflectivity. A two-dimensional photonic crystal W3 defect waveguide is successfully integrated as a quantum-dot laser mirror. Single fundamental mode output is achieved with a typically multi-mode 20 μm wide laser mesa, highlighting the mode selective property of the mirror. A similar two-dimensional mirror is studied for its potential as a dispersion compensating mirror for mode-locked lasers. Initial theoretical analysis shows pulse compression for a suitably designed mirror. Experimental continuous- wave results for the same mirror structure demonstrate the tuning of mirror reflectivity with photonic crystal hole radius. A hybrid silicon-organic photonic crystal laser is demonstrated with output in the visible spectrum. This design is a new type of silicon emitter.

Fluorescence resonance energy transfer studies of protein interactions

Martin, Sarah Friede — Tue, 24 Jun 2008 00:00:00 GMT

Abstract: This thesis presents an investigation of fluorescence resonance energy transfer (FRET) as a reporting signal for protein-protein interactions. Quantitative optical assays to measure protein binding, conjugation and deconjugation are developed and results validated by conventional biochemical techniques. The optical techniques developed provide fast, cheap, quantitative and accurate alternatives to conventional methods. Fluorescent protein fluorophores ECFP and Venus-EYFP were chosen as they are a non-interfering FRET pair and provide an inexpensive and convenient cloning-based labelling method. The small ubiquitin-like modifier SUMO and the SUMOylation pathway leading to its conjugation to target proteins is investigated as a model system. These assays are hence particularly relevant to research on post-translational modification and ubiquitin systems. In protein-protein binding assays we utilise both steady-state and time-resolved FRET detection to measure the equilibrium binding constant of the well-characterised pair SUMO1 and Ubc9. An assay in multi-well plate format is also presented, which uniquely enables repeat measurements under varying conditions and under the addition of further substances. The multi-protein binding interactions of the SUMOylation pathway including RanBP2 are analysed in binding inhibition assays. Our results clarify the role of RanBP2: a covalent SUMO1-Ubc9 link is required for the formation of a trimeric complex, although mutual binding sites are present on all three proteins. Furthermore, the binding of SUMO1 and Ubc9 is disrupted by RanBP2, which may be an essential step in transferring SUMO1 to its target protein. A FRET-based kinetic study of this conjugation process to RanGAP1 is presented. An assay to monitor the deconjugation of SUMO1 by specific proteases is established using a doubly-tagged SUMO construct. This enables a quantitative analysis of protease and substrate specificity based on real-time kinetic data, a characterisation of crude cell extracts and a high-throughput screen for protease inhibitors using FRET. A screen of the National Cancer Institute (NIC) diversity set for SenP1 inhibition reveals nine suitable compounds, which are potential anti-cancer drugs. The results of two further projects, the study of protein-protein binding by measuring small refractive index changes and the autofluorescence of normal and neoplastic cervical tissue models are also presented. In the latter, principal component analysis was used to systematically identify emission regions of significant variation between samples, enabling discrimination between healthy and pre-cancerous tissue models.

Microchip lasers

Conroy, Richard — Thu, 01 Jan 1998 00:00:00 GMT

Abstract: This thesis is concerned with the characterisation of sub-millimetre sized solid-state lasers. These 'microchip lasers' are examined in two forms; one as monolithic devices where the dielectric mirrors forming the laser cavity are directly deposited onto two near parallel faces of the laser gain crystal, and the second where the microchip gain material is used in combination with a nonlinear crystal to form a composite device. A range of neodymium doped crystals, operating continuous wave and in gain-switched mode at 1064nm, are compared as potential microchip laser gain materials, including Nd:YVO₄, Nd:YOS, Nd:SFAP and Nd:SVAP. With the exception of Nd:SVAP, slope efficiencies exceeding 40% and thresholds of less than 100mW were measured for all these lasers. A comparison of the 1064nm and 1342nm transitions in Nd:YVO₄ is also carried out showing similar performance for both transitions. The formation of the cavity within these monolithic lasers is described in detail, in particular for the thermal and gain guiding effects in Nd:YVO₄. Both analytical and numerical modelling of these effects are compared with experimental measurement of the cavity formation. When used in conjunction with a saturable absorber, these sub-millimetre sized lasers can be used to produce short, high-intensity pulses. This is demonstrated using Cr:YAG as a saturable absorber for Nd:YVO₄ at 1064nm to produce pulses as short as 1.38ns and peak powers of up to 1kW, and V:YAG to Q-switch Nd:YVO₄ at 1342nm to produce pulses with durations as short as 9.5ns and peak powers up to 360W. Active control for generating pulses is also demonstrated using a novel range of deflective Q-switches. These low cost, low loss, compact devices produced pulses of up to 12kW peak power and pulses duration of less than 1.1ns on demand. The continuous wave, intracavity frequency doubling of the three main ND³⁺ transitions, to give red, green and blue light is described. Up to 220mW of green light, with an efficiency approaching 40%, 33mW of blue light and 10mW of single-frequency red light were produced.

Modified Newtonian dynamics at all astrophysical scales

Angus, Garry W. — Thu, 27 Nov 2008 00:00:00 GMT

Abstract: In this thesis I test the modified Newtonian dynamics as an alternative to the cold dark matter hypothesis. In the Milky Way, I show that the dynamics of the dwarf galaxies are well described by the paradigm and I confirm its distant low surface brightness globular clusters provide a strong test, for which I make predictions. Through analysis of a sample of 26 X-ray bright galaxy groups and clusters I demonstrate that the three active neutrinos and their anti-particles are insufficient to reconcile modified Newtonian dynamics with the observed temperatures of the X-ray emitting gas, nor with weak-lensing measurements, in particular for the bullet cluster. To this end, I propose an 11eV sterile neutrino to serendipitously resolve the residual mass problem in X-ray bright groups and clusters, as well as matching the angular power spectrum of the Cosmic Microwave Background. With this in mind, I show that the large collision velocity of the bullet cluster and the high number of colliding clusters is more naturally reproduced in MOND than in standard dynamics.

Wide angle search for extrasolar planets by the transit method

Alsubai, Khalid — Tue, 24 Jun 2008 00:00:00 GMT

Abstract: The transit method is considered to be one of the most promising for discovering extrasolar planets. However, the method requires photometric precision of better than ∼ 1%. If we are able to achieve this kind of accuracy, then we are set to discover extrasolar planets. The uniqueness of my experiment will lead to the discovery of transiting planets around the brightest and most important stars quicker than the competitors in the field. The importance of the transit method stems from being able to supply many more planetary parameters than other methods, which plays a crucial role in testing planet formation theories. This thesis is divided into eight chapters. The first chapter provides a general background about transits and their theory. We discuss other methods of extrasolar planet detection, recent developments, future space missions, and what we have learned so far about properties of hot Jupiters. The second chapter details the theory of signals and noise on CCDs followed by the design of the PASS0 experiment. The third chapter reports on the difference imaging data pipeline that we developed and applied to a set of PASS0 data to search for transiting planets. The fourth chapter shows how we apply the PASS0 pipeline to SuperWASP data and improve on the accuracy obtained with their aperture photometry pipeline. The fifth chapter reports on the search for variable stars from the PASS0 and SuperWASP data sets that we consider in this thesis. In the sixth chapter we perform a transit search on the PASS0 and SuperWASP data sets and report the results. In the seventh chapter we use the PASS0 pipeline to process a full season of observing data from 2007 for two recent planet discoveries, WASP-7b and WASP-8b, that have not yet been announced. We analyse their lightcurves and predict their radii. Finally we conclude in the eighth chapter.

Solid state optical conjugated polymer amplifier; with ultrafast gain switching

Amarasinghe, Dimali C. V. — Sun, 30 Nov 2008 00:00:00 GMT

Abstract: Conjugated polymers are organic materials which are attractive as optoelectronic devices because they have a combination of broad band emission, high gain, versatility in processing, are ductile and can be electrically pumped. This thesis describes work conducted on such conjugated polymers as amplifier devices. The conjugated polymers used in this thesis were MEH-PPV, F8BT, GP1302 and ADS233YE. The amplifier devices used were grating coupled and end coupling waveguides. Amplification of light was demonstrated and characterised on single and multiple pulses using the grating coupled structure. Single pulse measurements obtained gains of 21 and 17 dB in a 1 mm long waveguide using the conjugated polymers MEHPPV and F8BT. Annihilation rate was also analysed in the single pulse method with MEH-PPV, giving a value of γ ≈ (3 ± 0.1) x 10⁻⁹ cm³/s. Amplification of a single pulse led to demonstrate amplification and the capability of the amplifier to function with multiple pulses, which resulted in F8BT being used as the gain medium. An average gain of 18 dB was obtained with F8BT in a 1 mm waveguide channel. Amplification was also investigated with end coupled waveguides. This led into investigating a suitable material or suitable combination of material for amplification with the waveguides. Switching of an amplified pulse was attempted on F8BT and GP1302 in the amplifier device at 5 kHz. Switching of F8BT was problematic which lead to attempt switching in GP1302 which was a co-polymer of PFO and F8BT. A 70 % switching effect was obtained with GP1302. Gain recovery dynamics of F8BT, GP1302 and ADS233YE was also investigated. These measurements established a switching rate of 500 GHz for GP1302 and ADS233YE, and F8BT showed partial gain recovery indicating the presence of long lived species. Switching was also attempted on a polymer laser. This resulted in a 100 % switched pulse with a combination of weak pump and strong switch pulse of 40 nJ and 2 μJ respectively. And a strong pump and weak switch pulse of 200 and 50 nJ respectively. Temporal delay of the switch pulse relative to the pump pulse resulted in re-timing of the laser output. Amplification and switching of light pulses were also attempted at a higher repetition rate of 50 kHz with F8BT, GP1302, ADS233YE and MEH-PPV. This resulted in strong amplification of light in MEH-PPV and F8BT with gains of 21 and 13 dB respectively in a waveguide length of 422 μm. Weak amplification of light in ADS233YE and GP1302 was also obtained with a maximum gain of 8 and 3 dB respectively. Switching was attempted on MEH-PPV and ADS233YE.

Longitudinal optical binding

Metzger, Nikolaus K. — Tue, 24 Jun 2008 00:00:00 GMT

Abstract: Longitudinal optical binding refers to the light induced self organisation of micro particles in one dimension. In this thesis I will present experimental and theoretical studies of the separation between two dielectric spheres in a counter-propagating (CP) geometry. I will explore the bistable nature of the bound sphere separation and its dependency on the refractive index mismatch between the spheres and the host medium, with an emphasis on the fibre separation. The physical under pining principle of longitudinal optical binding in the Mie regime is the refocusing effect of the light field from one sphere to its nearest neighbour. In a second set of experiments I developed means to visualise the field intensity distribution responsible for optical binding using two-photon fluorescence imaging from fluorescein added to the host medium. The experimental intensity distributions are compared to theoretical predictions and provide an in situ method to observe the binding process in real time. This coupling via the refocused light fields between the spheres is in detailed investigated experimentally and theoretically, in particular I present data and analysis on the correlated behaviour of the micro spheres in the presence of noise. The measurement of the decay times of the correlation functions of the modes of the optically bound array provides a methodology for determining the optical restoring forces acting in optical binding. Interestingly micro devices can be initiated by means of the light-matter interaction. Light induced forces and torques are exerted on such micro-objects that are then driven by the optical gradient or scattering force. I have experimentally investigate how the driving light interacts with and diffracts from the motor, utilising two-photon imaging. The micromotor rotation rate dependence on the light field parameters is explored and theoretically modelled. The results presented will show that the model can be used to optimise the system geometry and the micromotor.

Prominences and magnetic activity on young single and binary stars

Dunstone, Nicholas J. — Tue, 24 Jun 2008 00:00:00 GMT

Abstract: In this thesis I study the magnetic activity of young stars via observations of stellar prominences on single stars and by applying the Zeeman Doppler imaging (ZDI) technique to map the magnetic fields and measure differential rotation of a young binary system. Stellar prominences can be observed as absorption transients in the rotationally broadened chromospheric lines of rapidly rotating stars. Observations of Speedy Mic(K3V) reveal a densely packed prominence system at heights far above the stellar co-rotation radius. Further observations were used to estimate prominence column densities and masses. From very high signal-to-noise observations, loops of emission are found that trace the path of prominences seen transiting the stellar disc. I also present what appears to be the first observation of an erupting stellar prominence on AB Doradus (K0V). I modify an existing ZDI code so that it can recover the magnetic maps of a binary system. The new code is applied to observations of the pre-main sequence binary system HD 155555 (G5IV+K0IV). The radial magnetic maps reveal a complex surface magnetic topology with mixed polarities at all latitudes and rings of azimuthal field present on both stars. The evolution of the relative field strengths between observations in 2004 and 2007 could be indicative of a magnetic activity cycle. I adapt the sheared image technique for measuring differential rotation parameters to the binary case. Both stellar components of HD 155555 are found to have rates of differential rotation similar to those of the same spectral type main sequence single stars. This is in apparent conflict with previous work on evolved binary systems where low rates of differential rotation were found, leading to the suggestion of suppression by binary tidal forces. I find that the depth of convection zone alone can likely explain the differential rotation results without invoking tidal forces.

Some aspects of ion motion in liquid helium : the study of mobility discontinuities in superfluid helium (and liquid nitrogen), and the influence of grids on the transmission of an ion beam

Doake, Christopher S. M. — Sat, 01 Jan 1972 00:00:00 GMT

Abstract: We were unable to verify the existence of ion mobility discontinuities in either superfluid helium at 1 K or liquid nitrogen. The velocity-field dependence in helium was described by an increased interaction with the normal fluid, due to an increase in the roton number density close to the ion surface. The mobility results in nitrogen were interpreted as being due to liquid motion, following a theory by Kopylov. The D.C. results showed that the effect of a grid on the transmission of an ion beam could be described by a field dependent grid transmission coefficient, independent of the ion velocity. The vortex ring transmission through a grid was a complex function of vorticity being captured by the grid, the capture and escape probabilities of the bare ions by vorticity, and the onset for vorticity propagating throughout the ion cell.

Small angle neutron scattering studies of magnetic recording media

Wismayer, Matthew P. — Tue, 24 Jun 2008 00:00:00 GMT

Abstract: In the beginning of the twenty-first century, educational and commercial institutions have driven the demand for cheap and efficient data storage. The storage medium known as magnetic recording media has remained the mainstay for most computer systems due to its large storage capacity per dollar. With the recording media's ever-increasing storage density has come reductions in the magnetic grain size per bit. At the recording bit's density threshold, the magnetic grains become more susceptible to thermal activation, which can render the storage medium unusable. An accurate characterisation of the recording layer's sub-granular structure is essential for understanding the magnetic and thermal mechanisms of high-density recording media. Small-Angle Neutron Scattering (SANS) studies have been performed to investigate the magnetic and physical properties of longitudinal and perpendicular recording grains. The SANS studies of longitudinal magnetic recording media have probed the recording layer's magnetic grain size at a sub-nanometer resolution. In conjunction with these studies, SQUID magnetometry was used to characterise the recording grain's bulk magnetism. Measurements showed that the recording grain was composed of a ferromagnetic hard core (Co-enriched) and a weakly magnetic shell (Cr-enriched). These results provided important information on the grain's magnetic anisotropy, which determines the recording media's magnetic stability. The polarised SANS studies were used to characterise the recording layer's physical granular structure. It was shown that the physical grain size was comparable to its magnetic counterpart. These physical measurements provided insight into the recording grain's chemical composition. The magnetic properties of perpendicular magnetic recording media were studied using SANS and VSM measurements. The neutron scattering studies revealed that the recording grain was composed of a hard ferromagnetic centre enriched with cobalt. The VSM studies showed that the magnetic recording grains exhibited a large perpendicular magnetic anisotropy. These combined studies provided information on the recording grain's ferromagnetic composition and magnetic stability. The polarised SANS measurements showed the physical grain size to be slightly smaller than its magnetic counterpart. This size difference was attributed to the non-magnetic grain boundary composed of SiO2. The boundary thickness determined the degree of inter-granular exchange coupling. Further polarised studies investigated the recording layers switching behaviour, which revealed more information on the grain's magnetic stability.

Characterisation of materials for organic photovoltaics

Thomsen, Elizabeth Alice — Sun, 01 Jun 2008 00:00:00 GMT

Abstract: Organic solar cells offer the possibility for lightweight, flexible, and inexpensive photovoltaic devices. This thesis studies the physics of a wide range of materials designed for use in organic solar cells. The materials investigated include conjugated polymers, conjugated dendrimers, and inorganic nanocrystals. The materials studied in this thesis fall into five categories: conjugated polymers blended with a buckminsterfullerene derivative PCBM, nanocrystals synthesised in a conjugated polymer matrix, conjugated polymers designed for intramolecular charge separation, conjugated dendrimers blended with PCBM, and nanocrystals synthesised in a matrix of conjugated small molecules or dendrimers. Conjugated polymers blended with PCBM have been extensively studied for photovoltaic applications, and hence form an ideal test bed for new experiments. In this thesis this blend was used to achieve the first pulsed electrically detected magnetic resonance experiments on organic solar cells. Nanocrystals are attractive for photovoltaics because it is possible to tune their band gap across the solar spectrum. In this thesis a one-pot synthesis is used to grow PbS and CdS nanocrystals in conjugated polymers, soluble small molecules, and dendrimers, and characterisation is performed on these composites. Previous work on dendrimer: nanocrystal composites has been limited to non-conjugated molecules, and the synthesis developed in this thesis extends this work to a conjugated oligomer and a conjugated dendrimer. This synthesis can potentially be extended to a variety of conjugated soluble small molecule: nanocrystal and dendrimer: nanocrystal systems. Conjugated dendrimers have been successfully employed in organic light emitting diodes, and in this thesis they are applied to organic solar cells. Materials based on fluorene and cyanine dye cores show excellent absorption tunability across the solar spectrum. A set of electronically asymetric polymers designed for intramolecular charge separation were investigated. Quenching of the luminescence was observed, and light induced electron paramagnetic resonance measurements revealed that photoexcitation led to approximately equal numbers of positive polarons and nitro centred radical anions. This indicates that charge separation is occurring in these molecules.

Control and measurement of ultrafast pulses for pump/probe-based metrology

Harper, Matthew R. — Mon, 01 Jan 2007 00:00:00 GMT

Abstract: In this thesis the control of ultrafast (10⁻¹³ s) optical pulses used for metrological applications has been investigated. Two different measurement set-ups have been considered, both based around the `pump-probe' technique, where an optical pulse is divided into two parts, one to `pump' or excite a physical system of interest, the other to `probe' or measure the outcome. In both cases the measurement uses electro-optic sampling (EOS), where an electric field is measured by detecting changes in the optical probe pulse polarisation after interaction with the field. In the first study, a method for wavelength metrology in the terahertz (THz) region has been demonstrated by producing an optical pulse shaper and genetic algorithm to control pump pulses and so indirectly influence the THz spectra they generate. In the second study an OPO (optical parametric oscillator) has been developed to provide ultrafast optical pulses for the generation of < 100 fs electrical pulses for metrology using quantum interference control (QUIC). QUIC electrical signals have been demonstrated successfully by charge accumulation measurements and the QUIC electrical pulse temporally measured using EOS, though the low signal levels due to power restrictions mean the QUIC electrical pulse is unsuitable for metrology at this time. Finally, a portable optical pulse measurement device based around frequency-resolved optical gating (FROG) has been designed, built and tested. This has been shown to be capable of retrieving amplitude and phase information in both the temporal and spectral domains for optical pulses as short as 20 fs duration. The ability to characterise shaped pulses also has been demonstrated successfully, with the requirements for full automation identified.

Simulating ultracold matter: horizons and slow light

Farrell, Conor — Thu, 19 Jun 2008 00:00:00 GMT

Abstract: This thesis explores the links between different ways of modelling the physical world. Finite difference numerical simulations may be used to encode the behaviour of physical systems, allowing us to gain insight into their workings and even to predict their behaviour. Similarly, one can investigate the properties of gravitational black holes through the use of analogue black holes, physical systems which share at least some part of the physics of the astronomical objects. Concentrating on black hole analogues using Bose-Einstein condensates, I show how simulations of these systems may be greatly assisted through the use of a proper absorbing boundary condition, the Perfectly Matched Layer. Such a boundary condition allows the effcient truncation of the computational domain, both saving computational time and increasing accuracy. I then apply this technique to the simulation of the supersonic flow of a Bose-Einstein condensate through a Laval nozzle, a black hole analogue, showing that such a flow should be stable and observable in the laboratory. Moving to a related system, I investigate the optical analogue of the Iordanskii force - the friction resulting from interaction between excitations in a superfluid's normal component and a superfluid vortex - through the simulation of such a vortex in a Bose-Einstein condensate illuminated by slow light, which is light whose group velocity is on the order of metres per second. The interaction of the slow light with the vortex should produce a momentum transfer due to the optical Aharonov-Bohm effect, exerting a force on the vortex. The coupled system of equations describing the condensate-slow light system is simulated, giving some surprising results.

Ultrashort-pulse generation from quantum-dot semiconductor diode lasers

Cataluna, Maria Ana — Sun, 01 Jun 2008 00:00:00 GMT

Abstract: In this thesis, novel regimes of mode locking in quantum dot semiconductor laser diodes have been investigated by exploiting the unique features offered by quantum dots. Using an unconventional approach, the role of excited state transitions in the quantum dots was exploited as an additional degree of freedom for the mode locking of experimental quantum dot lasers. For the first time, passive mode locking via ground (1260nm) or excited state (1190nm) was demonstrated in a quantum dot laser. Picosecond pulses were generated at a repetition rate of 21GHz and 20.5GHz, for the ground and excited states respectively, with average powers in excess of 25mW. Switching between these two states in the mode-locking regime was achieved by changing the electrical biasing conditions, thus providing full control of the operating spectral band. A novel regime for mode locking in a quantum-dot laser was also investigated, where the simultaneous presence of cw emission in the excited-state band at high injection current levels, dramatically reduced the duration of the pulses generated via the ground state, whilst simultaneously boosting its peak power. This represents a radically different trend from the one typically observed in mode-locked lasers. From this investigation, it was concluded that the role of the excited state can not be neglected in the generation of ultrashort pulses from quantum-dot lasers. Stable passive mode locking of a quantum-dot laser over an extended temperature range (from 20ºC to 80ºC) was also demonstrated at relatively high output average powers. It was observed that the pulse duration and the spectral width decreased significantly as the temperature was increased up to 70ºC. The process of carrier escape in the absorber was identified as the main contributing factor that led to a decrease in the absorber recovery time as a function of increasing temperature which facilitated a decrease in the pulse durations. These results are shown to open the way for the ultimate deployment of ultra stable and uncooled mode-locked semiconductor diode lasers.

Advanced techniques in Raman tweezers microspectroscopy for applications in biomedicine

Jess, Phillip R.T. — Fri, 30 Nov 2007 00:00:00 GMT

Abstract: This thesis investigates the use of Raman tweezers microspectroscopy to interrogate the biochemistry of single biological cells. Raman tweezers microspectroscopy is a powerful technique, which combines traditional Raman microspectroscopy and optical trapping, allowing the manipulation and environmental isolation of a biological cell of interest whilst simultaneously probing its biochemistry gleaning a wealth of pertinent information. The studies carried out in this thesis can be split into two broad categories: firstly, the exploitation of Raman tweezers microspectroscopy to study biological cells and secondly developments to the Raman tweezers microspectroscopy technique that extend its capabilities and the range of samples that can be studied. In the application of Raman tweezers, the stacking and interrogation of multiple cells is reported allowing a rapid representative Raman signal to be recorded from a small cell population with improved signal to noise. Also demonstrated is the ability of Raman spectroscopy to identify and grade the development of Human Papillomavirus induced cervical neoplasia with sensitivities of up to 96 %. These studies demonstrate the potential of Raman spectroscopy to study biological cells but it was noted that the traditional Raman tweezers system struggled to manipulate large cells thus a decoupled Raman tweezers microspectroscopy system is presented where a dual beam fibre optical trap is used to perform the trapping function and a separate Raman probe is introduced to probe the biochemical nature of the trapped cell. This development allowed the trapping and examination of very large cells whilst opening up the possibility of creating Raman maps of trapped objects. Raman tweezers microspectroscopy could potentially become an important clinical diagnostic and biological monitoring tool but is held back by the long signal integration times required due to the weak nature of Raman scattering. The final study presented in this thesis examines the potential of wavelength modulated Raman spectroscopy to improve signal to noise ratios and reduce integration times. All these studies aim to demonstrate the potential and extend the performance of Raman tweezers microspectroscopy.

Ultrafast dynamics in InAs quantum dot and GaInNAs quantum well semiconductor heterostructures

Malins, David B — Tue, 24 Jun 2008 00:00:00 GMT

Abstract: The quantum confined Stark effect (QCSE) and ultrafast absorption dynamics near the bandedge have been investigated in p-i-n waveguides comprising quantum confined heterostructures grown on GaAs substrates, for emission at 1.3um. The materials are; isolated InAs/InGaAs dot-in-a-well (DWELL) quantum dots (QD), bilayer InAs quantum dots and GaInNAs multiple quantum wells (MQW). The focus was to investigate these dynamics in a planar waveguide geometry, for the purpose of large scale integration in optical systems. Initial measurements of the QCSE using photocurrent measurements showed a small shift for isolated QDs whilst a significant shift of 40nm (at 1340nm) was demonstrated for bilayer dots, comparable to that of GaInNAs MWQ (30nm at 1300nm). These are comparable to InP based quaternary multiple quantum wells used in modulator devices. With the use of a broadband continuum source the isolated quantum dots exhibit both a small QCSE (15nm at 1280nm) and minimal broadening which is desirable for saturable absorbers used in monolithic modelocked semiconductor lasers (MMSL). A robust experimental set-up was developed for characterising waveguide modulators whilst the electroabsorption and electro-refraction was calculated (dn=1.5x10â »Â³) using the Kramers-Kronig dispersion relation. Pump probe measurements were performed at room temperature using 250fs pulses from an optical parametric oscillator (OPO) on the three waveguide samples. For the isolated QDs ultrafast absorption recovery was recorded from 62ps (0V) to 700fs (-10V and the shortest times shown to be due to tunneling. Additionally we have shown good agreement of the temperature dependence of these dots and the pulse width durations from a modelocked semiconductor laser using the same material. Bilayer QDs are shown to exhibit ultrafast absorption recovery from 119ps (0V) to 5ps (-10V) offering potential for applications as modelocking elements. The GaInNAs multiple quantum wells show absorption recovery of 55ps (0V), however under applied reverse bias they exhibit long lived field screening transients. These results are explained qualitatively by the spatial separation of electrons and holes at heterobarrier interfaces.

Spin dynamics of quantum spin-ladders and chains

Notbohm, Susanne — Fri, 23 Nov 2007 00:00:00 GMT

Abstract: This thesis describes the neutron scattering measurements of magnetic excitations in spin-chains and ladders. The first part discusses an experimental investigation of the copper oxide family Srâ â Cuâ â Oâ â composed of edge-sharing chains and spin-ladders. The study of Laâ Srâ â Cuâ â Oâ â comprises a slightly hole-doped chain and an undoped ladder structure where the chain can be modeled by a ferromagnetic nearest and an antiferromagnetic next-nearest neighbor coupling. The hole effects are apparent in gaps in the dispersion relation and can be described by a charge-density wave agreeing with the commensuration of the dispersion. Investigating the undoped ladder establishes the exchange constants including a cyclic exchange manifested by the two-magnon continuum and the suppression of the S = 1 bound mode. An orbital consideration provides an explanation for the exchanges including the different sizes of rung and leg coupling. The excitation spectrum of the doped ladder in Caâ .â Srâ â .â Cuâ â Oâ â can be described by a direct comparison with the undoped ladder and the differences consisting of a higher energy mode and subgap scattering can be successfully modeled by the charge spectrum of the ladder calculated from the free electron model. The second part of the thesis investigates the alternating chain material Cu(NOâ )â Â· 2.5D2O and establishes the gapped one-magnon dispersion, the two-magnon continuum and for the first time the S =1 bound mode. Applying magnetic field drives the system through two critical field transitions, condensation of magnons into the ground state and saturation. The modes beyond saturation can be modeled by spin wave theory and the excitations at the first critical field follow Luttinger Liquid behavior. Additionally investigated are the temperature effects with the excitations being of a different nature but containing the signature of a strong correlated system. For an outlook the measurements including temperature and field are provided with further theoretical descriptions necessary.

The fabrication and lithography of conjugated polymer distributed feedback lasers and development of their applications

Richardson, Scott — Sun, 24 Jun 2007 00:00:00 GMT

Abstract: This thesis presents a study of lasing properties and optical amplification in semiconducting conjugated polymers and dendrimers. Configured as surface-emitting distributed feedback lasers, the effect of incorporating wavelength-scale microstructure on the output of the devices is examined along with the ability to create such structures using simplified fabrication processes such as soft lithography. Conjugated materials have received a great deal of interest due to their broad spectral absorption, emission, ability to exhibit gain and ease of processing from solution. As a result, they show great potential for a variety of applications such as photovoltaics, displays, amplifiers and lasers. To date however, there has only been one demonstration of a polymer optical amplifier. A broadband, solution based polymer amplifier is presented where the gain overlaps with the transmission window of polymer optical fibres. The effect of transitions that reduce the availability of gain in conjugated polymers is also examined by studying saturation of absorption in thin films. Producing wavelength scale microstructure is traditionally a slow, expensive technique. Here, solvent assisted micromoulding is used to pattern polymer films in less than two minutes. The effect of the variations in the pattern transfer on the laser characteristics is examined. The micromoulding technique is then applied to fabricating novel device types such as circular gratings and flexible plastic lasers. Encapsulation of the micromoulded laser is then shown to improve the lifetime of the device by over three orders of magnitude. The degradation effects witnessed during this extended operation are characterised quantitatively, an area of study where little data exists in the literature. A novel class of branched dendrimer materials whose properties can be independently tuned due to their modular architecture are configured as blue-emitting distributed feedback lasers. The ability to tune the emission wavelength by varying the film thickness is demonstrated. By changing the chemical groups contained within the molecule, further tuning of the emission can be obtained along with the demonstration of a highly efficient blue-emitting dendrimer laser. Chemosensing using dendrimer lasers is presented by demonstrating the incredibly sensitive response of the laser device to trace vapours of nitro-benzene compounds. The future application of which could be highly beneficial in the detection of explosives.

Microresonators for organic semiconductor and fluidic lasers

Vasdekis, Andreas E. — Mon, 16 Jul 2007 00:00:00 GMT

Abstract: This thesis describes a number of studies of microstructured optical resonators, designed with the aim of enhancing the performance of organic semiconductor lasers and exploring potential applications. The methodology involves the micro-engineering of the photonic environment in order to modify the pathways of the emitted light and control the feedback mechanism. The research focuses on designing new organic microstructures using established semi-analytical and numerical methods, developing fabrication techniques using electron-beam lithography, and optically characterising the resulting structures. Control of the feedback mechanism in conjugated polymer lasers is first investigated by studying Distributed Feedback or photonic crystal resonators based on a square feedback lattice. This study identified the diffraction to free space radiation as a major source of loss in current microstructured resonator designs. By cancelling the coupling to free space through the use of different feedback symmetries and diffraction orders, a threshold reduction by almost an order of magnitude is demonstrated. The introduction of mid-gap defect photonic states in an otherwise uniformly periodic structure was studied in Distributed Bragg Reflector (DBR) resonators. This enabled GaN diode pumped polymer lasers to be demonstrated, indicating that the transition from complex excitation sources to more compact systems is possible. Devices for potential applications in the field of optical communications are also explored by demonstrating a polymer DBR laser based on silicon. In this way, the potential for integrating conjugated polymers with silicon photonics is confirmed. Photonic crystal fibres, which have a periodic microstructure in the transverse direction, are explored as an alternative means for controlling the optical properties of organic lasers. Fluidic fibre organic lasers were demonstrated as efficient sources with good spectral purity. In these devices, mechanisms to tune the emission wavelength were explored and the origin of the frequency selection mechanism was investigated.

Extrasolar planet search and characterisation

Hood, Ben Andrew Ashcom — Tue, 19 Jun 2007 00:00:00 GMT

Abstract: Over two hundred extrasolar planets have been discovered to date with various methods. This thesis reports on searching for extrasolar planets and characterising them by simulating their atmospheres. We used open clusters as targets for deep transit searches, with specific emphasis on the University of St. Andrews Planet Search at the Isaac Newton Telescope. We reduced CCD photometry and described the algorithm we used to search for transits. We estimated the number of transits we expect from our data. We then reduced photometry for the open cluster NGC 6940. From that data we found 18 low-amplitude, short-duration events, though none are transiting planets. They are all eclipsing binary stars. However, our null result constrains the number of planets around M dwarfs, the most numerous stars in our sample. In order to characterise reflected light from extrasolar planets, we built a three-dimensional Monte Carlo based radiation transfer model of extrasolar planetary atmospheres. We detailed the input parameters of the model, and show results of various models, focusing especially on the fractal nature of the clouds of our models, because these are the first three dimensional radiation transfer models of extrasolar planet atmospheres. We found very low geometric albedos in our simulations. Using data specific to the transiting planet HD 209458b, we built a model atmosphere with Rayleigh-scattering hydrogen gas and clouds of enstatite and iron. We show in several models the rarity of a bright HD 209458b, and conclude with some explanations on why extrasolar planets are likely dark and not detected with reflected light.

Atom guiding in free-space light beams and photonic crystal fibres

Livesey, John Gregor — Mon, 01 Jan 2007 00:00:00 GMT

Abstract: In this thesis I describe experimental work and present data on the guiding of Rubidium atoms along free-space propagating light beams as well as within hollow core glass fibres, namely photonic crystal fibres. I describe experiments, laser systems and vacuum trap assemblies designed to facilitate this guiding. These experiments are intended to aid progression within the field of cold atom guidance wherein narrow diameter, long distance hollow-fibre guides are a current goal. Realisation of these guides could lead to promising applications such as atom interferometers and spatially accurate, multi-source, atom depositors. Herein, guided fluxes are observed in free-space guiding experiments for distances up to 50mm and up to 10GHz red-detuning from resonance. Additionally hollow-core, Kagome structured, quasi- and true-photonic crystal fibres are characterised. Finally a number of detailed fibre-guiding magneto-optic traps are developed. Both cold atomic-beams and cold atomic clouds are reliably positioned above fibre entrance facets in conjunction with a guiding laser beam coupled into the fibre core. Issues regarding optical flux detection outwith fibre confinement appear to have hindered observation of guided atoms. A far more sensitive detection system has been developed for use in current, ongoing fibre-guide experiments.

Versatile high resolution dispersion measurements in semiconductor photonic nanostructures using ultrashort pulses

Bell, Matthew Richard — Tue, 19 Jun 2007 00:00:00 GMT

Abstract: This thesis describes the process of developing a robust phase measurement technique with which to analyse semiconductor based devices intended for use in optoelectronic/all optical networks. The devices measured are prospective dispersion compensators, based either on planar photonic crystal waveguides or coupled microcavities connected by ridge waveguide. The technique was validated by measuring the phase transfer function of a Fabry Perot etalon. This demonstrated that even when detecting low optical powers (sub μW), accurate measurement of phase could quickly be carried out over a significant spectral range (~10nm). Comparison of experimental data taken from the prospective dispersion compensators with theory showed excellent agreement, which provided qualitative (cavity spacing and reflectivity) and quantitative (loss) measures of device performance. The phase measurement technique has been designed to be capable of measuring other classes of device also, including active devices such as semiconductor optical amplifiers. This suggests the phase measurement technique may be valuable in analysing the variation of dispersion as a function of applied bias, peak power or temperature for a variety of devices.

Optical micromanipulation using ultrashort pulsed laser sources

Little, Helen — Tue, 19 Jun 2007 00:00:00 GMT

Abstract: In this thesis two previously separate fields of study are brought together: optical micromanipulation and ultrashort laser research. Here, the benefits of combining the high peak powers of ultrashort pulsed lasers and conventional optical micromanipulation techniques are explored. As optical trapping has been studied extensively, the focus of this research is on optical guiding. Moreover, the emphasis is on the use of Bessel beams as these have been shown to offer greater guiding distances than comparable Gaussian beams. The studies within this thesis show that optical guiding in Bessel and Gaussian beams is governed by the average power of the laser. However, the benefits of guiding with ultrashort pulsed lasers to exploit multi-photon processes become evident as the demonstration of simultaneous optical guiding and second harmonic generation in microscopic nonlinear crystal fragments is detailed. This work is developed by using ultrashort pulses to induce two-photon excitation-induced fluorescence in the guiding medium. This allows direct visualisation of the beam-particle interaction and measurement of the reconstruction of the Bessel beam around an object. Some studies using two-photon excitation to investigate Bessel beam penetration through turbid media are discussed. Finally, the work is concluded by exploring the use of pulsed white-light lasers in optical guiding. The wavelength-dependent propagation and reconstruction properties of the white-light Bessel beam are studied before some preliminary optical guiding experiments are discussed. From this, the broad bandwidth of the supercontinuum source is found to offer extended guiding distances in Gaussian beams thereby negating the need for Bessel beams.

T Tauri stars : mass accretion and X-ray emission

Gregory, Scott G. — Mon, 30 Apr 2007 00:00:00 GMT

Abstract: I develop the first magnetospheric accretion model to take account of the observed complexity of T Tauri magnetic fields, and the influence of stellar coronae. It is now accepted that accretion onto classical T Tauri stars is controlled by the stellar magnetosphere, yet to date the majority of accretion models have assumed that the stellar magnetic field is dipolar. By considering a simple steady state accretion model with both dipolar and complex magnetic fields I find a correlation between mass accretion rate and stellar mass of the form M[dot above] proportional to M[asterisk subscript, alpha superscript], with my results consistent within observed scatter. For any particular stellar mass there can be several orders of magnitude difference in the mass accretion rate, with accretion filling factors of a few percent. I demonstrate that the field geometry has a significant effect in controlling the location and distribution of hot spots, formed on the stellar surface from the high velocity impact of accreting material. I find that hot spots are often at mid to low latitudes, in contrast to what is expected for accretion to dipolar fields, and that particularly for higher mass stars, accreting material is predominantly carried by open field lines. Material accreting onto stars with fields that have a realistic degree of complexity does so with a distribution of in-fall speeds. I have also modelled the rotational modulation of X-ray emission from T Tauri stars assuming that they have isothermal, magnetically confined coronae. By extrapolating from surface magnetograms I find that T Tauri coronae are compact and clumpy, such that rotational modulation arises from X-ray emitting regions being eclipsed as the star rotates. Emitting regions are close to the stellar surface and inhomogeneously distributed about the star. However some regions of the stellar surface, which contain wind bearing open field lines, are dark in X-rays. From simulated X-ray light curves, obtained using stellar parameters from the Chandra Orion Ultradeep Project, I calculate X-ray periods and make comparisons with optically determined rotation periods. I find that X-ray periods are typically equal to, or are half of, the optical periods. Further, I find that X-ray periods are dependent upon the stellar inclination, but that the ratio of X-ray to optical period is independent of stellar mass and radius. I also present some results that show that the largest flares detected on T Tauri stars may occur inside extended magnetic structures arising from the reconnection of open field lines within the disc. I am currently working to establish whether such large field line loops can remain closed for a long enough time to fill with plasma before being torn open by the differential rotation between the star and the disc. Finally I discuss the current limitations of the model and suggest future developments and new avenues of research.

Optical sorting and manipulation of microscopic particles

Milne, Graham — Mon, 25 Jun 2007 00:00:00 GMT

Abstract: Over the last few decades, the use of light to control and manipulate microscopic particles has become widespread. These methods are enabling new areas of research to flourish across the physical and biological sciences. This thesis describes investigations into both optical trapping and the closely related field of optical sorting. It documents the development of a variety of new techniques. The thesis begins with a short review of optical trapping and existing methods for sorting mixtures of microscopic particles. The first half of this chapter highlights some of the reasons behind optical trapping's rapid growth in popularity. By reviewing an array of methods for sorting particles and discussing the relative merits of each, the case for optical sorting is established. The second chapter describes research into using a spatial light modulator to create three-dimensional optically trapped colloidal structures using the time-sharing technique. Limiting factors inherent in the technology are discussed in detail. The third chapter reviews a sophisticated particle-tracking software package that has proved to be a considerable success. It was developed explicitly with colloidal microscopy in mind and experimental plots produced by the software are used throughout the thesis. Experimental studies have been performed into the behaviour of microscopic particles moving under the influence of two classes of propagation-invariant beams: Mathieu beams and Bessel beams. The Bessel beam studies have been complimented by a theoretical model and have led ultimately to a new method for the static optical sorting of both solid particles and biological cells, with particular emphasis on human blood. The fifth and final chapter describes how re-configurable optical devices can be implemented to spatially separate different colloidal species. A new method for creating arbitrary optical landscapes using an acousto-optic modulator is reported. This new technique is then used to optically sort four particle species simultaneously - the first experimental demonstration of polydisperse optical fractionation. Additionally, experiments are reported that demonstrate controlled, static optical sorting using a spatial light modulator.

Ultrafast organic lasers and solid-state amplifiers

Goossens, Mark — Tue, 19 Jun 2007 00:00:00 GMT

Abstract: This thesis presents an investigation of the lasing dynamics and optical amplification devices using conjugated polymers. Spectroscopic studies of conjugated polymers and dendrimers were also performed. Conjugated polymers and dendrimers are materials with great potential as display materials and tuneable lasers due to their broad spectra and high optical gains. The effect of conjugation is studied in MEH-PPV and an anisotropy measurement of two different cored dendrimers has been shown to verify a theoretical prediction on their depolarisation. Singlet emission from a highly efficient phosphorescent dendrimer is also observed and is the first known report of fluorescence from this class of dendrimers. Conjugated polymers exhibit optical gain over broad spectral ranges, which has led to much interest in their potential as novel laser gain media. Investigations into lasing from conjugated polymers has been confined mainly to studying the lasing properties and not the temporal dynamics of the laser pulses. In this work an investigation into the lasing dynamics of a 2D-DFB conjugated polymer laser is demonstrated with the first subpicosecond laser pulses observed for a polymer laser. A novel encapsulated laser fabricated via a soft lithography route was also studied and exhibited laser pulse of 6 ps duration. The high gain observed over broad spectral ranges also means that these materials are suitable for use as optical amplifiers. Broadband gain in a conjugated polymer solution was demonstrated with a gain of 30 dB accessible across a 60 nm wavelength range. In the solid state the limited thickness of films (~ 100 nm) and the uneven nature of the film edges had limited the ability to study the amplification of a probe signal. The first practical solid state conjugated polymer amplifier has been demonstrated. The device uses grating structures to couple a probe signal into and out of the gain region. The gain dynamics of different length amplifiers were studied and an 18 dB gain was observed in a 300 µm device length using a conjugated polymer blend of RedF and F8BT. Further work on a conjugated polymer MEH-PPV led to a 21dB gain in a 1 mm device.

Femtosecond Cr⁴⁺: forsterite laser for applications in telecommunications and biophotonics

McWilliam, Alan — Fri, 01 Jun 2007 00:00:00 GMT

Abstract: In this thesis, the development of a femtosecond Cr⁴⁺:forsterite solid-state laser is described where the mode-locking procedure was initiated using two novel saturable absorbers. One was a GaInNAs quantum-well device and the other a quantum-dot-based saturable absorber. These devices had not previously been exploited for the generation of femtosecond pulses from a solid-state laser but in the course of this project, successful mode-locked laser operation in the femtosecond domain was demonstrated for both devices. When the GaInNAs device was incorporated in the Cr⁴⁺:forsterite laser, transform-limited pulses with durations as short as 62fs were obtained. The performance of this femtosecond laser was significantly superior to that for previous quantum-well based saturable absorbers in the 1300nm spectral region. The dynamics of the device were investigated with the aim of refining subsequent devices and to explore the potential to grow future devices for use at longer wavelengths. At the outset of my research work quantum-dot based saturable absorbers had not be used for the mode locking of solid-state lasers in the femtosecond regime. The work presented in this thesis showed that quantum-dot structures could be exploited very effectively for this purpose. This was initially achieved with the quantum-dot element being inclined at an off-normal incidence within the cavity but experimental assessment together with further development of the device allowed for implementation at normal incidence. Reliable operation of the femtosecond laser was demonstrated very convincingly where transform-limited pulses of 160fs duration were generated. Having developed practical femtosecond Cr⁴⁺:forsterite lasers, the final part of the project research was directed towards exemplar applications for a laser operating in the 1300nm spectral region. These were biophotonics experiments in which assessments of both deep tissue penetration and two-photon chromosome cutting were undertaken. This work confirmed the suitability of the 1300nm laser radiation for propagation through substantial thicknesses of biological tissue (~15cm). The demonstration of highly localised two-photon cutting of Muntjac deer chromosomes also represented a novel result because single-photon absorption could be avoided effectively and the temporal broadening of the femtosecond pulses in the delivery optics arising from group velocity dispersion around 1300nm was minimal.

Monte Carlo radiation transfer studies of protoplanetary environments

Walker, Christina H. — Tue, 19 Jun 2007 00:00:00 GMT

Abstract: Monte Carlo radiation transfer provides an efficient modelling tool for probing the dusty local environment of young stars. Within this thesis, such theoretical models are used to study the disk structure of objects across the mass spectrum - young low mass Brown Dwarfs, solar mass T-Tauri stars, intermediate mass Herbig Ae stars, and candidate B-stars with massive disks. A Monte Carlo radiation transfer code is used to model images and photometric data in the UV - mm wavelength range. These models demonstrate how modelling techniques have been updated in an attempt to reduce the number of unknown parameters and extend the diversity of objects that can be studied.

The formation of molecular clouds in spiral galaxies

Dobbs, Clare L. — Wed, 20 Jun 2007 00:00:00 GMT

Abstract: Molecular clouds are imperative to astronomy as the sites of all known star formation. The problem of how molecular clouds are formed in spiral galaxies is approached numerically, by modelling the response of a gas disk to a spiral potential. The importance of spiral shocks is highlighted as a dominant formation mechanism for molecular clouds in grand design galaxies, where a strong density wave is present. The spiral shock both increases the density of the interstellar gas significantly, and produces structure in the spiral arms. The gas evolves into discrete clumps, which are shown to contain substantial densities of molecular hydrogen, and are therefore identified as molecular clouds. The formation of these clouds requires that the interstellar medium (ISM) is cold and inhomogeneous. The passage of an inhomogeneous gas distribution through a spiral potential further shows that supersonic velocities are induced as the gas shocks. This can explain the velocity dispersion relation observed in molecular clouds. Finally, the shearing of clumps of gas in the spiral arms leads to the formation of inter-arm structures, which are commonly observed in spiral galaxies.

Spin relaxation and carrier recombination in GaInNAs multiple quantum wells

Reith, Charis — Fri, 01 Jun 2007 00:00:00 GMT

Abstract: Electron spin relaxation and carrier recombination were investigated in gallium indium nitride arsenide (GaInNAs) multiple quantum wells, using picosecond optical pulses. Pump-probe experiments were carried out at room temperature, using pulses produced by a Ti:sapphire pumped optical parametric oscillator. The peak wavelengths of the excitonic resonances for the quantum well samples were identified using linear absorption measurements, and were found to be in the range 1.25µm-1.29µm. Carrier recombination times were measured for three samples of varying nitrogen content, and were observed to decrease from 548 to 180ps as nitrogen molar fractions were increased in the range 0.45-1.24%. Carrier recombination times were also measured for samples which had undergone a post-growth annealing process, and were found to be signicantly shorter compared to times measured for as-grown samples. Electron spin relaxation time was investigated for samples with quantum well widths in the range 5.8-8nm, and was found to increase with increasing well width, (i.e. decreasing quantum confinement energy), a trend predicted by both D'Yakonov-Kachorovskii and Elliott-Yafet models of spin relaxation in quantum wells. In a further study, longer spin relaxation times were exhibited by samples containing higher molar fractions of nitrogen, but having nominally constant quantum well width. Spin relaxation times increased from 47ps to 115ps for samples containing nitrogen concentrations in the range 0.45-1.24%. Decreases in spin relaxation time were observed in the case of those samples which had been annealed post-growth, compared to as-grown samples. Finally, all-optical polarisation switching based on spin relaxation of optically generated carriers in GaInNAs multiple quantum wells was demonstrated.

Compact objects in active galactic nuclei and X-ray binaries

Cackett, Edward M. — Mon, 01 Jan 2007 00:00:00 GMT

Abstract: In this thesis I study the inner-most regions of Active Galactic Nuclei (AGN) using the reverberation mapping technique, and neutron star low-mass X-ray binaries in quiescence using X-ray observations. Using the 13-year optical monitoring data for the AGN NGC 5548, the luminosity dependence of the Hβ emitting radius was modelled using a delay map, finding that the radius scales with luminosity as predicted by recent theoretical models. Time-delays between the continuum at different wavelengths in AGN can be used to probe the accretion disc. Here, continuum time-delays in a sample of 14 AGN were used to measure the radial temperature profile of the accretion discs, determine the nuclear extinction, and measure distances to the objects. However, the distances measured correspond to a value for Hubble's constant that is a factor of ~2 lower than the accepted value. The implications of this on the thermal disc reprocessing model are discussed. I present two Chandra observations of the neutron star transient in the globular cluster NGC 6440 in quiescence, where the power-law component to the spectrum is seen to be variable between the observations, suggesting that there is ongoing residual accretion. From a Chandra observation of the globular cluster Terzan 1, I have identifed the likely quiescent counterpart to a transient previously observed in outburst, and discuss the other sources within the cluster. Using Chandra and XMM-Newton monitoring observations of two neutron star transients (KS 1731-260 and MXB 1659-29) in quiescence I have found that the neutron star crusts in both sources have now returned to thermal equilibrium with the core. These observations also indicate that the crusts in both sources may have a high thermal conductivity and that enhanced neutrino emission may be occurring in the core. Finally, the discovery of an X-ray transient with XMM-Newton is presented, and the other sources in this observation discussed.

Optically controlled microfluidics

Neale, Steven Leonard — Mon, 01 Jan 2007 00:00:00 GMT

Abstract: Three projects are described in this thesis that combine microfabrication techniques with optical micromanipulation. The aim of these projects is to use expertise in microlithography and optical tweezing to create new tools for Lab-on-Chip devices. The first project looks at the creation of microgears that can be moved using an optical force. The microgears include one dimensional photonic crystal that creates birefringence. This allows the transfer of angular momentum from a circularly polarised light beam to the microgear, making them spin. The microgears are simulated, fabricated and tested. Possible biological applications are suggested. The second project looks at creating microchannels to perform micromanipulation experiments in. Different methods of fabricating the microfluidic channels are compared, and the resulting chambers are used to find the maximum flow rate an optical sorting experiment can be performed at. The third project involves using a thin photoconductive layer to allow the optical control of an electrical force called dielectrophoresis. This light induced dielectrophoresis (LIDEP) allows similar control to optical tweezing but requires less irradiance than optical tweezing, allowing control over a larger area with the same input optical power. A LIDEP device is created and experiments to measure the electrical trap size that is created with a given optical spot size are performed. These three projects show different microfabrication techniques, and highlight how well suited they are for use in optical manipulation and microfluidic experiments. As the size of objects that can be optically manipulated matches well with the size of objects that can be created with microfabrication, it seems likely that many more interesting applications will develop.

Characterisation of organic materials for photovoltaic devices

Lewis, Andrew J. — Wed, 20 Sep 2006 00:00:00 GMT

Abstract: This thesis presents an investigation into a wide range of potential materials for organic photovoltaic (PV) devices. A variety of optical techniques are used to define physical parameters for each material such as the photoluminescence quantum yield (PLQY), absorption coefficient and exciton diffusion length. Electrical characterisation is used to determine the optimal structure for devices fabricated with these materials. A number of novel materials are presented in this thesis. These include new polymers, both soluble and precursor, and a relatively new class of material, the conjugated dendrimer. These are highly configurable branching molecular structures that enable fine tuning of material properties. Work on polymers presented in this thesis investigates how such materials can be improved by testing the effect of small changes to their molecular structure. One of these changes had significant effects upon the overall material characteristics. The introduction of a dipole across a polymer successfully created a charge separating material without the need for an extra species such as C60 to be present. The introduction of the conjugated dendrimer to PV applications allows significant scope for molecular engineering. Dendrimers enable tight control over certain aspects of the molecular properties. Small changes can be made such as colour tuning or solubility that enable optimisation to be performed on the molecular level, rather than on device structure. Such changes produced significantly higher internal quantum efficiencies (> 90%) than typical polymer devices and offer the prospect of power conversion efficiencies in excess of 10%. Time-resolved luminescence (TRL) spectroscopy was used to characterise the behaviour of photogenerated excitons within organic films. The investigation of exciton diffusion length was performed upon two polymers, each utilising two different time-resolved methods; diffusion to a quencher and exciton-exciton annihilation. It was found that diffusion in polythiophene films is anisotropic and the photoluminescence lifetime is dependent upon film thickness. This is explained by the formation of self-ordered microstructures during the spin coating process. Data modelling was performed which took into account both the thickness variation and the interaction of excitons with a quenching interface producing a much more realistic approach than previously published work.

Photonic crystal interfaces: a design-driven approach

Ayre, Melanie — Thu, 01 Jun 2006 00:00:00 GMT

Abstract: Photonic Crystal structures have been heralded as a disruptive technology for the miniaturization of opto-electronic devices, offering as they do the possibility of guiding and manipulating light in sub-micron scale waveguides. Applications of photonic crystal guiding - the ability to send light around sharp bends or compactly split signals into two or more channels have attracted a great deal of attention. Other effects of this waveguiding mechanism have become apparent, and attracted much interest - the novel dispersion surfaces of photonic crystal structures allow the possibility of “slow light” in a dielectric medium, which as well as the possibility of compact optical delay lines may allow enhanced light-matter interaction, and hence miniaturisation of active optical devices. I also consider a third, more traditional type of photonic crystal, in the form of a grating for surface coupling. In this thesis, I address many of the aspects of passive photonic crystals, from the underlying theory through applied device modelling, fabrication concerns and experimental results and analysis. Further, for the devices studied, I consider both the relative merits of the photonic crystal approach and of my work compared to that of others in the field. Thus, the complete spectrum of photonic crystal devices is covered. With regard to specific results, the highlights of the work contained in this thesis are as follows: Realisation of surface grating couplers in a novel material system demonstrating some of the highest reported fibre coupling efficiencies. Development of a short “injecting” taper for coupling into photonic crystal devices. Optimisation and experimental validation of photonic crystal routing elements (Y-splitter and bend). Exploration of interfaces and coupling for “slow light” photonic crystals.

External cavity diode lasers and non-linear optical frequency conversion in spectroscopic applications

Shah, Anjali — Mon, 01 May 2006 00:00:00 GMT

Abstract: Semiconductor diode lasers are successful tools in atomic spectroscopy. They are routinely used in frequency conversion applications to develop devices that access regions of the spectrum not directly available. This thesis describes the practical application of novel violet diode laser systems and their possible inclusion in spectroscopic systems. The design, assembly and successful operation of a doubly resonant optical parametric oscillator is described. There is discussion of the spectral behaviour of the device and the potential for pumping with a violet diode laser. Methods to adapt the output from the solitary diode devices are demonstrated with the use of microlensed diode lasers and extended cavity configurations. Details of the current tuning, linewidth and smooth tuning characteristics of a number of the lasers used are given. A commercial violet diode laser is used within an extended cavity to measure the hyperfine structure of atomic indium from a hollow cathode galvatron source at room temperature. Stabilisation of the diode laser to a line from the indium spectrum is attempted. The remainder of the thesis is concerned with the development of techniques to deliver clearer and more precise spectral information about trace species. Microlensed red and violet diode lasers are used to generate light at 254nm via sum frequency generation for the direct detection and modulation spectroscopy of mercury vapour, with microlensed lasers with modulation allowing more accurate discrimination between spectral features than direct absorption measurements. In addition Raman tweezers modulation spectroscopy is undertaken to investigate polymer microspheres and biological cell samples where the use of the modulation technique demonstrated improvements in the acquisition time and clarity of spectra through increased signal to noise and rejection of background fluorescence effects. A comparison between the direct and modulation techniques for all the systems indicates the greater sensitivity of the modulation technique.